Posted by
admin 10 May, 2013
Tweet Water quality testing is vital to the design of an efficient, cost-effective RO system, and is one of the best ways to preserve system life and performance. Using an accurate Total Dissolved Solids (TDS) measurement to assess the system load prevents costly mistakes up front. The TDS measurement gives users the information they need [...]

Water quality testing is vital to the design of an efficient, cost-effective RO system, and is one of the best ways to preserve system life and performance.
Using an accurate Total Dissolved Solids (TDS) measurement to assess the system load prevents costly mistakes up front. The TDS measurement gives users the information they need to determine whether or not pretreatment is required and the type of membrane/s to select. Ultrameter™ and ULTRAPEN PT1™ Series TDS instruments feature the unique ability to select from 3 industry standard solution models: 442 Natural Water™ NaCl; and KCl. Choosing the model that most closely matches the characteristics of source water yields measurements accurate enough to check and calibrate TDS monitor/controllers that can help alert to system failures, reducing downtime and increasing productivity. The same instruments provide a fast and accurate test for permeate TDS quality control. Measuring concentrate values and analyzing quality trends lets users accurately determine membrane usage according to the manufacturer’s specifications so they can budget consumption correctly. These daily measurements are invaluable in detecting problems with system performance where changes in the ionic concentration of post-filtration streams can indicate scaling or fouling. System maintenance is generally indicated if there is either a 10-15% drop in performance or permeate quality as measured by TDS.
Thin-film composite membranes degrade when exposed to chlorine. In systems where chlorine is used for microbiological control, the chlorine is usually removed by carbon adsorption or sodium bisulfite addition before membrane filtration. The presence of any chlorine in such systems will at best reduce the life of the membrane, thus, a target of 0 ppm free chlorine in the feedwater is desirable.
ORP gives the operator the total picture of all chemicals in solution that have oxidizing or reducing potential including chlorine, bromine, chloramines, chlorine dioxide, peracetic acid, iodine, ozone, etc. However, ORP can be used to monitor and control free chlorine in systems where chlorine is the only sanitizer used. ORP over +300 mV is generally considered undesirable for membranes. Check manufacturer’s specifications for tolerable ORP levels.
An inline ORP monitor/controller placed ahead of the RO unit to automatically monitor for trends and breakthroughs coupled with spot checks by a portable instrument will prevent equipment damage and failure. Myron L 720 Series II™ ORP monitor/controllers can be configured with bleed and feed switches as well as visible and audible alarms.
Ultrameter and ULTRAPEN portable handhelds are designed for fast field testing and are accurate enough to calibrate monitor/controllers. Our measurement methods are objective and have superior accuracy and convenience when compared to colorimetric methods where determination of equivalence points is subjective and can be skewed by colored or turbid solutions.
Monitoring pH of the source water will allow users to make adjustments that optimize the performance of antiscalants, corrosion inhibitors and anti-foulants. Using a 720 II Series Monitor/controller to maintain pH along with an Ultrameter Series or ULTRAPEN PT2™ handheld to spot check pH values will reduce consumption of costly chemicals and ensure their efficacy.
Most antiscalants used in chemical system maintenance specify a Langelier Saturation Index maximum value. Some chemical manufacturers and control systems develop their own proprietary methods for determining a saturation index based on solubility constants in a defined system. However, LSI is still used as the predominant scaling indicator because calcium carbonate is present in most water. Using a portable Ultrameter III 9PTKA™ provides a simple method for determining LSI to ensure the chemical matches the application.
The Ultrameter III 9PTKA computes LSI from independent titrations of alkalinity and hardness along with electrometric measurements of pH and temperature. Using the 9PTKA LSI calculator, alterations to the water chemistry can be determined to achieve the desired LSI. Usually, pH is the most practical adjustment. If above 7, acid additions are made to achieve the pH value in the target LSI. Injections are made well ahead of the RO unit to ensure proper mixing and avoid pH hotspots. A Myron L 720 Series II pH Monitor/controller will automatically detect and divert solution with pH outside the range of tolerance for the RO unit. ULTRAPEN PT2, TechPro II and Ultrameter Series instruments can be used to spot check and calibrate the monitor/controller as part of routine maintenance and to ensure uniform mixing.
Water hardness values indicate whether or not ion exchange beds are required in pretreatment. Checking hardness values directly after the softening process with the Ultrameter III 9PTKA ensures proper functioning and anticipates the regeneration schedule.
Alkalinity is not only important in its effect on the scaling tendency of solution, but on pH maintenance. Additions of lime are used to buffer pH during acid injection. Use a 9PTKA to measure alkalinity values for fast field analysis where other instrumentation is too cumbersome to be practical.
Though testing and monitoring pressure is a good way to evaluate system requirements and performance over time, measuring other water quality parameters can help pinpoint problems when troubleshooting. For example, if the pressure differential increases over the second stage, the most likely cause is scaling by insoluble salts. This means that any degradation in performance is likely due to the dissolved solids in the feed. Using a 9PTKA to evaluate LSI and calculate parameter adjustments is a simple way to troubleshoot a costly problem.
Myron L Meters saves you 10% on all Ultrameters and Ultrapens when you order online at MyronLMeters.com, where you can find the complete selection of Myron L meters, including the Ultrameter III 9PTKA.
Original story from International Filtration News V 32, no. 2
Posted by
admin 7 May, 2013
TweetSoon Myron L Meters will be adding a Water Industry Resources page to MyronLMeters.com. The page will feature links to water industry events, water industry associations, and related technical resources. Please look over our draft page below and suggest anything we might be missing. Be sure to check back with us periodically for new features [...]
Soon Myron L Meters will be adding a Water Industry Resources page to MyronLMeters.com. The page will feature links to water industry events, water industry associations, and related technical resources. Please look over our draft page below and suggest anything we might be missing. Be sure to check back with us periodically for new features and changes, including our upcoming Myron L Meters Users Forum.
Myron L Meters Water Industry Resources
Blog
http://blog.myronlmeters.com/
Manuals and MSDS
http://www.myronlmeters.com/Articles.asp?ID=263
Video Channel
http://www.youtube.com/myronlmeters
Application Bulletins
https://www.myronlmeters.com/Articles.asp?ID=265
Users Group
Water Industry News
http://waterindustrynews.com/
Pinterest
http://pinterest.com/myronlmeters/boards/
Twitter
https://twitter.com/MyronLMeters
Water Science and Conservation
Water Conservation News - Science Daily
http://www.sciencedaily.com/news/earth_climate/water/
U.S. Department of the Interior | Bureau of Reclamation
http://www.usbr.gov/WaterSMART/
Environmental Protection Agency
http://www2.epa.gov/science-and-technology/water-science
Clean Water Network
http://www.cleanwaternetwork.org/
Soil and Water Conservation Society
http://www.swcs.org/
Partnership for Water Conservation
http://www.partners4water.org/
Nature Conservancy Conservation Gateway
http://www.conservationgateway.org/Pages/default.aspx
Water Products Suppliers
Pumps: PulsafeederPumps
http://www.pulsafeederpumps.com/
Storage Tanks: PeabodyStorageTanks
http://www.peabodystoragetanks.com/Default.asp
Water Industry Events
Apr 14 – Apr 18, 2013
Miscellaneous | Miscellaneous
23th Annual Practical Membrane / Filtration & Separations Technologies Short Course
College Station, TX
Apr 16 – Apr 18, 2013
AWWA Section | Section Conference
New York Section 2013 Annual Conference
Saratoga Springs, NY
Apr 16 – Apr 18, 2013
Miscellaneous | Seminar
HEC-HMS
Chicago, IL
Apr 22 – Apr 24, 2013
AWWA | Seminar
SOLD OUT Financial Management Seminar, San Diego, California
San Diego, CA
Apr 23 – Apr 25, 2013
AWWA Section | Section Conference
Pennsylvania Section 2013 Annual Conference
Hershey, PA
Apr 25 – Apr 25, 2013
Miscellaneous | Miscellaneous
Native Landscape Design for Stormwater
Milwaukee, WI
Apr 29 – May 02, 2013
AWWA Section | Annual Meeting
Alaska Section 2013 Annual Conference
Anchorage, AK
May 01 – May 03, 2013
AWWA Section | Section Conference
Arizona Section 2013 Annual Conference
Glendale, AZ
May 06 – May 07, 2013
Miscellaneous | Miscellaneous
17th Annual Water Reuse & Desalination Research Conference
Phoenix, AZ
May 06 – May 08, 2013
Miscellaneous | Speciality Conferences
2013 ABPA Education Conference & Trade Show
Phoenix, AZ
May 06 – May 10, 2013
Miscellaneous | Miscellaneous
2013 West Regional Conference
Seattle, WA
May 07 – May 09, 2013
AWWA Section | Annual Meeting
Montana Section 2013 Annual Conference
Great Falls, MT
May 07 – May 07, 2013
Miscellaneous | Speciality Conferences
SCMA SWAT Training For Operators Workshop
Granbury, TX
May 08 – May 10, 2013
AWWA Section | Annual Meeting
Hawaii Section 2013 Annual Conference
Honolulu, HI
May 08 – May 10, 2013
AWWA Section | Section Conference
Pacific Northwest Section 2013 Annual Conference
Spokane, WA
May 08 – May 10, 2013
Miscellaneous | Seminar
Inspection and Assessment of Dams
Seattle, WA
May 09 – May 09, 2013
Miscellaneous | Miscellaneous
Watershed Planning – Putting the Pieces Together
Milwaukee, WI
May 09 – May 09, 2013
Miscellaneous | Miscellaneous
Smart Water for Smart Cities – A Workshop
Ellicot City, MD
May 09 – May 09, 2013
Miscellaneous | Speciality Conferences
SCMA I Scream, You Scream, We All Scream For Membranes Workshop
Tuttle, OK
May 16 – May 17, 2013
Miscellaneous | Annual Meeting
Water and Agriculture
Palos Verdes, CA
May 19 – May 22, 2013
AWWA Section | Section Conference
West Virginia Section 2013 Annual Conference
Daniels, WV
May 20 – May 20, 2013
Miscellaneous | Speciality Conferences
AMTA/SEDA Joint Technology Transfer Workshop “Application of Membrane Technologies in the Chesapeake Region”
Chesapeake, VA
May 21 – May 23, 2013
Miscellaneous | Miscellaneous
Appalachian Underground Corrosion Short Course (AUCSC 2013)
Morgantown, WV
May 22 – May 24, 2013
AWWA Section | Annual Meeting
Connecticut Section 2013 Annual Conference
Saratoga Springs, NY
May 30 – May 30, 2013
Miscellaneous | Miscellaneous
Water Law for Sustainable Management
Milwaukee, WI
Jun 09 – Jun 13, 2013
AWWA | Annual Meeting
2013 Annual Conference & Exposition
Denver, CO
Jun 24 – Jun 25, 2013
Miscellaneous | Speciality Conferences
2013 AWRA Summer Specialty Conference Environmental Flows
Hartford, CT
Jul 09 – Jul 10, 2013
AWWA | Speciality Conferences
NWMOA MBR Operator Training Workshop
Pendleton, OR
Aug 04 – Aug 04, 2013
Miscellaneous | Annual Meeting
Association of Clean Water Administrators
Sante Fe, NM
Sep 08 – Sep 12, 2013
Miscellaneous | Speciality Conferences
Dam Safety 2013
Providence, RI
Sep 09 – Sep 12, 2013
AWWA Section | Annual Meeting
Virginia Section 2013 Annual Conference
Richmond, VA
Sep 10 – Sep 13, 2013
AWWA Section | Section Conference
Michigan Section 2013 Annual Conference
Lansing, MI
Sep 11 – Sep 13, 2013
AWWA Section | Section Conference
Intermountain Section AWWA
Sun Valley, Idaho
Sep 15 – Sep 18, 2013
Miscellaneous | Symposium
North American Membrane Society 23rd Annual Meeting
Denver
Sep 15 – Sep 18, 2013
Miscellaneous | Symposium
28th Annual WateReuse Symposium
Denver, Colorado
Sep 15 – Sep 18, 2013
AWWA | Speciality Conferences
2013 DSS/Emergency Preparedness and Security Conf.
Itasca, IL
Sep 22 – Sep 25, 2013
Miscellaneous | Annual Meeting
World Congress 2013
Las Vegas, NV
Sep 23 – Sep 25, 2013
Miscellaneous | Annual Meeting
NWMOA 1st Annual Symposium – “Getting the Best from Your Membrane Treatment Plant”
Vancouver, WA
Sep 29 – Oct 03, 2013
Miscellaneous | Speciality Conferences
84th Annual Education and Business Conference
Kansas City, MO
Oct 01 – Oct 03, 2013
Miscellaneous | Speciality Conferences
NRWA WaterPro Conference
Seattle, WA
Oct 02 – Oct 04, 2013
Miscellaneous | Speciality Conferences
6th WaterSmart Innovations Conference and Exposition
Las Vegas, NV
Oct 13 – Oct 15, 2013
AWWA Section | Section Conference
Alabama-Mississippi Annual Conference
Tunica Resorts, MS
Nov 03 – Nov 07, 2013
AWWA | Speciality Conferences
2013 Water Quality Technology Conference
Long Beach, CA
Nov 04 – Nov 08, 2013
Miscellaneous | Miscellaneous
2013 Irrigation Show & Education Conference
Austin
Water Industry Associations
American Fisheries Society
- The Chlorine Institute
- Conservation International
- Environmental Assessment Association
- Environmental Council of the States
- Environmental Law Institute
- The Groundwater Foundation
- Ground Water Protection Council
- Institute of Professional Environmental Practice
10.Irrigation Association
11.NARUC Committee on Water
12.National Association of Conservation Districts
13.National Association of Counties
14.National Association of Environmental Professionals
15.National Association of Pipe Fabricators
16.National Association of Water Companies
17.National Council for Science and the Environment
18.National Drinking Water Clearinghouse
19.National Drought Mitigation Center
20.National Federation of Municipal Analysts
21.National Fire Protection Association
22.National Ground Water Association
National Institute for the Environment
23.National Institutes for Water Resources
24.National Rural Water Association
25.National Small Flows Clearinghouse
26.National Water Research Institute - Canada.
27.National Water Resources Association
28.Renewable Natural Resources Foundation
29.Soil and Water Conservation Society
30.State Water Resources Research Institutes
31.Water and Wastewater Equipment Manufacturers Association
American Filtration and Separations Society (AFS)
The premier organization in North America dedicated to R&D, problem solutions and technology transfer in fluid-particle separation for the benefit of industrial processes, individual health and a clean environment.
American Ground Water Trust is a nonprofit educational organization dedicated to promoting efficient and effective ground water management and provides educational information about ground water issues that are important to well owners.www.agwt.org
American Institute of Hydrology
American Public Works Association
American Society of Irrigation Consultants
American Water Resources Association
American Water Works Association (AWWA)
Association of Metropolitan Water Agencies
Association of Metropolitan Sewerage Agencies
Association of State Drinking Water Administrators
Association of State and Interstate Water Pollution Control Administrators
Association of Water Technologies
AWWA Research Foundation
California Water Operators Association (CWOA)
A professional association dedicated to helping water and wastewater operators in California thru education, public policy, wages, benefits, training.
Caribbean Water and Wastewater Association (CWWA)
The CWWA encourages the study, research and development in water supply and wastewater disposal, and the publication of the results of such work, so as to provide for appropriate and dynamic technological advances in the Caribbean.
Florida Water and Pollution Control Operators Association, Region 8
One of the leading water and wastewater professional training organizations in Florida for over 5,000 professionals that work in the public, private and government utilities.
Instrument Society of America (ISA)
The international society for measurement, control, instrumentation and automation.
International Bottled Water Association is the authoritative source of information about all types of bottled waters.
www.bottledwater.org
Regional Bottled Water Associations:
NEBWA – Northeastern Bottled Water Association
SEBWA – Southeastern Bottled Water Association
MABWA – Mid-America Bottled Water Association
CSBWA – Central States Bottled Water Association
NWBWA – Northwestern Bottled Water Association
CBWA – Canadian Bottled Water Association
International Private Water Association (IPWA)
Promoting private sector participation in water utilities.
The Irrigation Association (IA)
Formed more than 50 years ago to improve the products and practices used to manage water resources and to help shape the worldwide business environment of the irrigation industry.
Kentucky Water & Wastewater Operators Association (KWWOA)
A not-for-profit association organized in the fall of 1958. The KWWOA was created by a group of operators from the drinking and wastewater industry.
Maine Lagoon Systems
The mission of the Maine Lagoon Systems website is to promote clean water resources through the enhanced communication of wastewater lagoon system operators in the state of Maine and beyond.
Maine Wastewater Control Association (MWCA)
An association of over 650 members consisting of municipal and industrial operators, consultants, students, and regulatory officials. The purpose is to facilitate communication of ideas and the preservation of Maine’s waterways.
Measurement, Control and Automation Association (MCAA)
NAWC (National Association of Water Companies)
http://www.nawc.org/
National Ground Water Association (NGWA) is a trade association for ground water professionals including well drillers, pump installers, geologists and other scientists to promote responsible development, use and management of ground water resources. www.ngwa.org
National Institute for the Environment
National Institutes for Water Resources
National Rural Water Association
National Small Flows Clearinghouse
Helping America’s small communities meet their wastewater needs.
National Water Research Institute - Canada.
National Water Resources Association
Northeast Rural Water Association (NeRWA)
Started in 1982, a nonprofit association of water and wastewater systems in Massachusetts, New Hampshire, and Vermont. Among its many services, We offer training and onsite technical assistance to operators, managers, owners and boards.
South Carolina Rural Water Association (SCRWA)
Providing free training to water and wastewater operators in South Carolina, through cooperative agreements with NRWA and USEPA. Offering vendors opportunities to network with utility companies in our state. Offering utilities assistance with water & wastewater issues from an operational to a managerial level.
Water and Wastewater Equipment Manufacturers Association
http://www.wwema.org/
Water Design-Build Council (WDBC)
The Water Design-Build Council supports the development and rehabilitation of the nation’s municipal water and wastewater systems by using the design-build project delivery method. Our mission is to promote best practices for design-build to facilitate productive and collaborative relationships between service providers and governments.
Water Education Foundation
Water Environment Federation (WEF)
Founded in 1928, the Water Environment Federation (WEF) is a not-for-profit technical and educational organization with members from varied disciplines who work toward the WEF vision of preservation and enhancement of the global water environment.
Water Environment Research Foundation
Water Environment WEB - Water Environment Federation
Water Industry Council
Water Organizations - [UWIN]
Water Quality Association (WQA)
A not-for-profit international trade association representing the residential, commercial, industrial, and small community water treatment industry. WQA maintains a close dialogue with other organizations representing different aspects of the water industry in order to best serve consumers, government officials, and industry members.
Regional Water Quality Associations:
EWQA – Eastern Water Quality Association
FWQA – Florida Water Quality Association
Missouri WQA – Missouri Water Quality Association
PWQA – Pacific Water Quality Association
TWQA – Texas Water Quality Association
Water Utility Benchmarking Association
The Watershed Management Council
Industry Publications:
Water Quality Products
www.wqpmag.com
Water Technology
www.watertechonline.com
Water Conditioning and Purification
www.wcponline.com
Food Processing Magazine
www.foodprocessing.com
ALN Magazine
www.alnmag.com
The Bottled Water Reporter
www.ibwa.org
Journal of Hydroinformatics
Journal of Water and Health
Journal of Water and Climate Change
Journal of Water Reuse and Desalination
Journal of Water Sanitation and Hygiene for Development
Journal of Water Supply: Research and Technology-AQUA
Hydrology Research
Water21
Water Asset Management International
Water Practice and Technology
Water Policy
Water Quality Research Journal of Canada
Water Research
Water Science and Technology
Water Science and Technology: Water Supply
Water Systems Council is a national nonprofit organization focused solely on household wells and small water well systems.
www.watersystemscouncil.org
Water Utility Management International
Water Intelligence Online
Government Information Sources
EPA Safe Drinking Water Act List of Primary and Secondary Contaminants, Health Effects, and Sources:
www.epa.gov/safewater/mcl.html
US Water Partnership: Department of State
http://www.state.gov/e/oes/rls/fs/2012/186581.htm
US Department of the Interior: Water Challenges
http://www.doi.gov/whatwedo/water/index.cfm
US Army Corps of Engineers: Water Resources Development
http://www.usace.army.mil/About/History/BriefHistoryoftheCorps/WaterResourcesDevelopment.aspx
Water Resources of the United States
http://water.usgs.gov
USGS Water Data for the Nation
http://waterdata.usgs.gov/nwis
National Water Quality Assessment Program
http://water.usgs.gov/nawqa/
US Bureau of Reclamation
http://www.usbr.gov
United States Environmental Protection Agency Water Resources
http://water.epa.gov
National Climatic Data Center
http://www.ncdc.noaa.gov/
National Water and Climate Center
http://www.wcc.nrcs.usda.gov/
US Drought Portal
http://www.drought.gov/drought/
CDC Healthy Water Portal
http://www.cdc.gov/healthywater/
Water Industry Training
Water Industry Whitepapers and Information
NAWC
http://www.nawc.org/knowledge-center/documents-and-publications/all-document.aspx
The Water and Wastewater Online Training Center is a virtual campus providing quality and targeted online training to meet the information needs of the water and wastewater treatment professional.
http://www.waterandwastewater.com/online_training/
Texas A&M Engineering Extension Service (Water and Wastewater)
http://www.teex.org/teex.cfm?pageid=EUprog&area=EU&templateid=1268
EPA Small Water Systems Training & Technical Assistance Grant
NO-COST EPA Safe Drinking Water Act Training
http://teexweb.tamu.edu/teex-third.cfm?area=EU&templateid=478
The Office of Water Programs at the California State University, Sacramento, College of Engineering and Computer Science provides distance learning courses for persons interested in the operation and maintenance of drinking water and wastewater facilities.
http://www.owp.csus.edu/courses/catalog.php
Kansas Basics Course for Small Public Drinking Water Systems
http://www.waterhelp.org/ks/kdhe/
WEF offers online education and webcasts here:
http://www.wef.org/onlineeducation/default.aspx
Water Industry Training Specialists are a California Corporation in the business of training and certifying Backflow Technicians and Cross-Connection Control Inspectors.
https://www.backflowschool.com/
Environmental-Expert.com hosts several courses from different companies in industrial wastewater, water treatment, and environmental engineering.
http://www.environmental-expert.com/training/keyword-industrial-wastewater-182
Plumbing Engineer
http://www.plumbingengineer.com/white.php
Bitpipe.com
http://www.bitpipe.com/tlist/Utilities-Industry.html
Water-Technology.net
http://www.water-technology.net/downloads/whitepapers/
Posted by
admin 1 May, 2013
TweetMyronLMeters.com has the most advanced lineup of pool analysis meters for the professional pool maintenance technician from the Ultrapen to the PoolPro PS9. Pool Draining Tips to Protect Water Quality With summer right around the corner, many swimming pool owners will be readying their swimming pools in anticipation of the season’s heat. As part of [...]
MyronLMeters.com has the most advanced lineup of pool analysis meters for the professional pool maintenance technician from the Ultrapen to the PoolPro PS9.
Pool Draining Tips to Protect Water Quality
With summer right around the corner, many swimming pool owners will be readying their swimming pools in anticipation of the season’s heat. As part of this process, some pool owners like to drain old swimming pool water which has been sitting all winter. Though not a necessary task, the following tips are provided for you to properly drain pool water in order to protect the water resources in your community.
Whenever possible, it is best to drain your pool onto your landscape. This recycles your pool water, conserves irrigation water, and avoids the environmental risks associated with draining your pool to the street. Before draining your pool water to the street or to your landscape, be sure to follow the guidelines outlined below.
While draining pool water to the street is a common practice, it can prove harmful to the environment if the pool owner does not properly plan and prepare prior to draining. When pool water is drained to the street, it can carry other pollutants such as oil, grease, sediment, bacteria and trash down the storm drain and into the nearest creek, river, or the ocean. Swimming pool water also often contains harmful additives and chemicals. If the water is not properly treated to remove these pollutants prior to draining, they can cause further damage to the health of our waterways and to the plants and animals that live there.
Also, prior to draining to the street, residents are asked to sweep the curb and gutter between the discharge point from their yard to the storm drain down hill from their home. This will remove any pollutants from the gutter that may be carried up by the drained pool water to the storm drain.
For chlorine pools, chlorine levels must be lowered to less than 1 part per million prior to draining. This can be done naturally, by simply allowing the pool water to sit in the sun for a minimum of three days. Alternatively, de-chlorination kits can be purchased at home supply stores at a very reasonable cost. These kits have the tools you need to reach the appropriate chlorine levels before draining your pool to the curb and gutter.
Some people have salt water pool systems which may be preferred due to the lower amount of chemicals required for their operation. However, these pools must not be drained to the storm drain system due to their high salt content relative to the fresh water systems they drain into. Total dissolved solids (TDS) must be below 500 parts per million in order to drain into the street.
“Green pools,” which are pools in which algae is growing, also must not be drained to the street. In these instances, algae must first be killed and removed. This is usually done by chlorinating the swimming pool until the algae is gone, then lowering chlorine to the allowable discharge level. Cartridge filters or diatomaceous earth (DE) filters should be rinsed onto a pervious surface such as landscaped areas or grass. While DE is actually beneficial in your garden, it can build up in storm drains and clog them. DE residues can be scooped up and simply thrown in the trash or put to use fending off worms in your garden.
For more information on how to reach acceptable chemical and TDS levels, call your pool maintenance specialist.
If you are a pool maintenance specialist, consider the PoolPro PS9TKA from MyronLMeters.com – the most advanced and comprehensive pool water analysis meter on the market.

PS9TK from MyronLMeters.com
Pool Pro PS9TK
Measures 9 Parameters: Conductivity, Mineral/Salts, TDS, Alkalinity, Hardness, LSI, pH, ORP/Free Chlorine, Temperature
LSI Calculator for hypothetical water balance calculations
Wireless data transfer capability with bluDock option
Auto-ranging delivers increased resolution across diverse applications
Adjustable Temperature Compensation and Cond/TDS conversion ratios for user-defined solutions
Nonvolatile memory of up to 100 readings for stored data protection
Date & time stamp makes record-keeping easy
pH calibration prompts alert you when maintenance is required
Auto-off minimizes energy consumption
Low battery indicator
(Includes instrument with case and solutions)
Posted by
admin 21 Mar, 2013
TweetAbstract Access to safe drinking water is important as a health and development issue at national, regional, and local levels. About one billion people do not have healthy drinking water. More than six million people (about two million children) die because of diarrhea which is caused by polluted water. Developing countries pay a high cost [...]
Abstract
Access to safe drinking water is important as a health and development issue at national, regional, and local levels. About one billion people do not have healthy drinking water. More than six million people (about two million children) die because of diarrhea which is caused by polluted water. Developing countries pay a high cost to import chemicals including polyaluminium chloride and alum. This is the reason why these countries need low-cost methods requiring low maintenance and skill. The use of synthetic coagulants is not regarded as suitable due to health and economic considerations. The present study was aimed to investigate the effects of alum as coagulant in conjunction with bean, sago, and chitin as coagulants on the removal of color, turbidity, hardness, and Escherichia coli from water. A conventional jar test apparatus was employed for the tests. The study was taken up in three stages, initially with synthetic waters, followed by testing of the efficiency of coagulants individually on surface waters and, lastly, testing of blended coagulants. The experiment was conducted at three different pH conditions of 6, 7, and 8. The dosages chosen were 0.5, 1, 1.5, and 2 mg/l. The results showed that turbidity decrease provided also a primary E. coli reduction. Hardness removal efficiency was observed to be 93% at pH 7 with 1-mg/l concentration by alum, whereas chitin was stable at all the pH ranges showing the highest removal at 1 and 1.5mg/l with pH 7. In conclusion, using natural coagulants results in considerable savings in chemicals and sludge handling cost may be achieved.
Keywords:
Alum; Chitin; Sago; Bean; Coagulation; Turbidity
Background
The explosive growth of the world’s human population and subsequent water and energy demands have led to an expansion of standing surface water [1]. Nowadays, the concern about contamination of aquatic environments has increased, especially when water is used for human consumption. About one billion people do not have healthy drinking water. More than six million people (about two million children) die because of diarrhea which is caused by polluted water[2,3].
In most of the cases, surface water turbidity is caused by the clay particles, and the color is due to the decayed natural organic matter. Generally, the particles that determine the turbidity are not separated by settling or through traditional filtration. Colloidal suspension stability in surface water is also due to the electric charge of particle surface. Thus, there is great importance in either the development of more sophisticated treatments or the improvement of the current ones [4].
The production of potable water from most raw water sources usually entails the use of a coagulation flocculation stage to remove turbidity in the form of suspended and colloidal material. This process plays a major role in surface water treatment by reducing turbidity, bacteria, algae, color, organic compounds, and clay particles. The presence of suspended particles would clog filters or impair disinfection process, thereby dramatically minimizing the risk of waterborne diseases [5,6].
Many coagulants are widely used in conventional water treatment processes, based on their chemical characteristics. These coagulants are classified into inorganic, synthetic organic polymers, and natural coagulants [4]. Alum has been the most widely used coagulant because of its proven performance, cost effectiveness, relatively easy handling, and availability. Recently, much attention has been drawn on the extensive use of alum. Aluminum is regarded as an important poisoning factor in dialysis encephalopathy. Aluminum is one of the factors which might contribute to Alzheimer’s disease [7-9]. Alum reaction with water alkalinity reduces water pH and its efficiency in cold water [10,11]. However, some synthetic organic polymers such as acrylamide have neurotoxicity and strong carcinogenic effect [8,12].
In addition, the use of alum salts is inappropriate in some developing countries because of the high costs of imported chemicals and low availability of chemical coagulants [3]. This is the reason why these countries need low-cost methods requiring low maintenance and skill.
For these reasons, and also due to other advantages of natural coagulants/flocculants over chemicals, some countries such as Japan, China, India, and the United States have adopted the use of natural polymers in the treatment of surface water for the production of drinking water [13]. A number of studies have pointed out that the introduction of natural coagulants as a substitute for metal salts may ease the problems associated with chemical coagulants.
Natural macromolecular coagulants are promising and have attracted the attention of many researchers because of their abundant source, low price, multi-purposeness, and biodegradation[11,14,15]. Okra, rice, and chitosan are natural compounds which have been used in turbidity removal [16-18]. The extract of the seeds has been mentioned for drastically reducing the amount of sludge and bacteria in sewage [19].
In view of the above discussion, the present work has been taken up to evaluate the efficiency of various natural coagulants on the physico-chemical contaminant removal of water. To date, most of the research has been concentrated on the coagulant efficiencies in synthetic water, but in this study, we move ahead making an attempt to test the efficiency of the natural coagulants on surface water. The efficiencies of the coagulants as stated by [20] might alter depending on many factors: nature of organic matter, structure, dimension, functional groups, chemical species, and others.
Methods
Natural coagulants and their preparation
Sago is a product prepared from the milk of tapioca root. Its botanical name is ‘Manihot esculentaCrantz syn. M. utilissima’. Hyacinth bean with botanical name Dolichos lablab is chosen as another coagulant. Both the coagulants were used in the form of powders (starches). Starch consists mainly of a homopolymer of α-D-glucopyranosyl units that comes in two molecular forms, linear and branched. The former is referred to as amylose and the latter as amylopectin [21]. These have the general structure as per [22] (Figure 1) .
Figure 1. General structure of amylose and amylopectin.
The third coagulant was chitin ([C8H13O5N]n), which is a non-toxic, biodegradable polymer of high molecular weight. Like cellulose, chitin is a fiber, and in addition, it presents exceptional chemical and biological qualities that can be used in many industrial and medical applications. The two plant originated coagulants were taken in the form of powder or starch. Chitin was commercially procured.
Stage I
The first stage included testing the efficiency of the four coagulants on the synthetic waters. Synthetic waters with turbidity of 70 and 100 nephelometric turbidity units (NTU) were prepared with fuller’s earth in the laboratory and were used in this part of the study. The experiment was carried out using a jar test apparatus. The experiments were conducted in duplicates to eliminate any kind of error. Efficiency was evaluated by determination of reduction in turbidity of both the synthetic samples.
Stage II
In the second stage of the experiment, the individual coagulants were evaluated for their efficiency on the surface waters. The water samples for this stage and the preceding stage were collected from the surface reservoir, Mudasarlova, located at a distance of 5 km from the Environmental Monitoring Laboratory, GITAM University, where the experiments were carried out. This is the reservoir which serves as a source of domestic water for the nearby residents.
Care was taken while collecting the samples so that a representative sample is obtained. All samples were collected in sterile plastic containers. The samples were transported to the laboratory, and all the experiments were conducted within a duration of 24 h. The physical parameters like temperature and color were noted at the point of sample collection. The water samples were analyzed for the following parameters pre- and post-treatment with the coagulants (Table 1).
Table 1. Physico-chemical parameters tested (stage II)
The coagulants were tested at various concentrations like 0.5, 1, 1.5, and 2 mg/l at three pH ranges of 6, 7, and 8.
Stage III
The results obtained from the second stage of the study have encouraged us to further extend the study in terms of blended coagulants. The blending of coagulants was taken up from the fact that alum was the most widely used coagulant, and hence, it was taken as one part. The remaining combinations were 2, 3, 4, and 5 parts of the natural coagulants, i.e., 1:2, 1:3, 1:4, and 1:5.
Testing of the following parameters was adopted for evaluating the efficiency of the blended coagulants (pre- and post-coagulation) (Table 2). All the analysis has been performed as per the standard methods given by APHA, 2005 [23].
Table 2. Physico-chemical parameters tested (stage III)
E. coli presence
The E. coli bacterial presence and absence were determined in the pre- and post-coagulated water using H2S strip bottle. The water sample was filled into the bottle and allowed to stand for 24 h at room temperature. After 24 h, the water sample was observed for color change; black color change indicates the presence of E. coli.
Results
Coagulant actions onto colloidal particles take place through charge neutralization of negatively charged particles. If charge neutralization is the predominant mechanism, a stochiometric relation can be established between the particles’ concentration and coagulant optimal dose.
In the initial stage of the experiment, the coagulants were tested against synthetic turbid samples with 70 and 100 NTU. According to Figure 2a,b, the optimum dosage of alum was observed to be 1mg/l for both the turbid samples, and the optimum pH is observed to be 7.
Figure 2. Turbidity removal efficiency of alum with initial turbidities of (a) 100 and (b) 70 NTU.
It is understood from Figure 3a,b that the optimum dosage for chitin as coagulant is 1.5 mg/l (turbidity to 40 NTU) for 100 NTU, whereas not much difference was observed between pH 7 and 8 for both the turbid samples. The optimum pH is observed to be 7 for both 70 and 100 NTU samples.
Figure 3. Turbidity removal efficiency of chitin with initial turbidities of (a) 100 and (b) 70 NTU.
Figure 4a,b exemplifies the trends of sago on the turbidity removal of the synthetic solutions. It is observed that sago was effective at both 1 and 1.5 mg/l (turbidity reduced to 50 and 45 NTU, respectively) for 100 NTU solution, and the efficiency was stable at pH 7 and 8.
Figure 4. Turbidity removal efficiency of sago with initial turbidities of (a) 100 and (b) 70 NTU.
Figure 5a,b illustrates the effect of bean on the synthetic turbid samples and turbidity removal. It is observed that bean was effective at 1mg/l (turbidity reduced to 55 NTU) for 100 NTU solution, and the efficiency was stable at pH 7 and 8.
Figure 5. Turbidity removal efficiency of bean with initial turbidities of (a) 100 and (b) 70 NTU.
Implications from the stage 1 experiment articulate that the coagulants are quite stable at the pH ranges tested; hence, in the proceeding experiments, all the three pH ranges were considered. In the second stage of experiment, the environmental samples from the surface water source were collected and tested for the removal of turbidity and other chemical parameters. The dosages were the same as the previous stage. The results are graphically represented as shown in Figures 6, 7,8, 9.
Figure 6. Turbidity removal efficiency of individual coagulants.
Figure 7. Total hardness removal efficiency of individual coagulants.
Figure 8. Calcium hardness removal efficiency of individual coagulants.
Figure 9. Chloride removal efficiency of coagulants.
The turbidity removal efficiencies of the individual coagulants are depicted in Figure 6 wherein there was a broad variation among the pH ranges. The maximum reduction was observed with 1 mg/l (87%) of bean at pH 6 followed by 1 mg/l (82%) sago at the same pH. At pH 7, the maximum efficiency was shown by bean with 1.5 mg/l dosage (85.37%) followed by bean and sago with 1 (82.49%) and 1.5 mg/l (82.49%), respectively. Removal efficiencies of 41.46% and 36.59% were reported by 1 mg/l of bean and sago, respectively, at pH 8. The minimum reductions are not reported as there was a negative competence of the coagulants at different doses and pH variations. It can be observed from the graph that there was an increase in the turbidity of the water at these dosages like with 2 g of chitin the turbidity removal was −19.51. In the entire study, the best results were obtained with total hardness removal wherein no negative competence was reported as shown in Figure 7. The utmost removal was observed with 0.5-mg/l (97.67%) sago at pH 7. At pH 6, it was (90.70%) with 1.5 mg/l of bean. At pH 8, the reduction was (93.02%) with 0.5 mg/l of alum. Apart from these, the general observation was that all the coagulants were effective in an average removal of 65% total hardness at all pH variations and doses. The tracking for the least efficiency has showed chitin at pH 6 with 2-mg/l dose (34.88%).
The calcium hardness removal efficiencies are directly proportional with the total hardness removal; the highest removal was recorded by chitin (93.33%) at pH 7 with 1.5-mg/l dose as shown in Figure 8. Removal of 90% is at pH 8 and 7 with 0.5-mg/l alum and 1-mg/l chitin, respectively. Minimum effectiveness was observed by chitin (6.67%) at pH 6 with 2-mg/l dose. On an average, the removal competence was more than 60% with all coagulants at doses at all the pH conditions.
Figure 8 illustrates the chloride removal efficiency of the coagulants tested. The average competence was observed to be 40%. The maximum competence was noted at pH 7 by chitin (83.64%) at 1.5 mg/l followed by sago (81.82%) at 1 mg/l. Indeed at pH 7, the removal was observed to be superior as a whole. Similarly, pH has shown inferior effectiveness in the amputation of chloride. The remarkable point that was noted is that at pH 8, where the removal was superior, the increase in doses of sago and bean (1.5 and 2 mg/l) has shown a depressing outcome.
With the results obtained from the second stage experimentation, the study was carried forward for the evaluation of blended coagulants. From the literature, it was understood that blended coagulants show improved competence than that of the individual ones.
The regular test of turbidity was substituted with conductivity to establish a relation and test the difference with these parameters. The conductivity diminution was observed to be preeminent at the ratio of 1:2 of all the blended coagulants 26.12%, 26.00%, and 21.35% with alum/bean, alum/chitin, and alum/sago, respectively. The highest reduction was observed with alum/sago at pH 8 with 1:2 ratio (32.28%) (Figure 10).
Figure 10. Conductivity removal efficiency of blended coagulants.
The total hardness reduction trend of the blended coagulants was recorded as follows: at pH 7, all combinations of alum/bean have resulted in negative competence. Amputation of 100% was observed with alum/chitin and alum/sago at 1:2 and 1:4 and 1:5 doses, respectively (Figure 11). The overall competence of the alum/chitin and alum/sago were registered to be more than 80%. The calcium hardness efficiencies of the blended coagulants were similar to that of the total hardness. The highest removal efficiency was shown by alum/chitin with 1:5 ratio at pH 7 (Figure 12).
Figure 11. Total hardness removal efficiency of blended coagulants.
Figure 12. Calcium hardness removal efficiency of blended coagulants.
As said earlier, the turbidity was replaced by color determination taking into account the fact that turbidity is directly related to the color. pH 7 has been remarkably effective in the highest removal of color from the water. The blended coagulant alum/sago was found to be very effective with 98% to 100% reduction in color at all the ratios of dosage (Figure 13). The blended coagulants alum/chitin and alum/sago were relatively successful at an average rate of 80% decline in the color at almost all ratios of dosage at pH 7 and 8.
Figure 13. Color removal efficiency of blended coagulants.
Alum/sago blend has a noteworthy effect on the removal of chloride from the water samples in which no negative result was noted. The highest reduction was observed with alum/chitin with dose of 1:5 (85.71%) at pH 7. Indeed, pH 7 can be optimized as perfect pH for this blend as all the ratios of dosages were quite efficient in the removal of chloride (Figure 14).
Figure 14. Chloride removal efficiency of blended coagulants.
Discussion
Although many studies have used synthetic water in the experiments, this work chose to use raw water collected directly from the surface source. Therefore, it is important to consider that the natural compounds may cause variations in their composition, which interfere in the treatment process. All those factors are taken into account when evaluating the obtained results.
The characteristics of the superficial water used in this study are observed as that the water used has apparent color, turbidity, solids, and amount of compounds with a relatively high absorption in UV (254 nm). It is noticeable that the water has high turbidity and color.
The effectiveness of alum, commonly used as a coagulant, is severely affected by low or high pH. In optimum conditions, the white flocs were large and rigid and settled well in less than 10 min. This finding is in agreement with other studies at optimum pH [24,25]. The optimum pH was 7 and was similar to the obtained results by Divakaran [26]. At high turbidity, a significant improvement in residual water turbidity was observed. The supernatant was clear after about 20-min settling. Flocs were larger and settling time was lower. The results showed that above optimum dosage, the suspensions showed a tendency to restabilize.
The effectiveness of the chitin in the present study in the removal of various contaminants with varied pH individually and also in blended form can be traced to the explanation from the literature that chitin has been studied as biosorbent to a lesser extent than chitosan; however, the natural greater resistance of the former compared to the last, due to its greater crystallinity, could mean a great advantage. Besides, the possibility to control the degree of acetylation of chitin permits to enhance its adsorption potential by increasing its primary amine group density. Recent studies regarding the production of chitin-based biocomposites and its application as fluoride biosorbents have demonstrated the potential of these materials to be used in continuous adsorption processes. Moreover, these biocomposites could remove many different contaminants, including cations, organic compounds, and anions [27].
Chitosan has high affinity with the residual oil and excellent properties such as biodegradability, hydrophilicity, biocompability, adsorption property, flocculating ability, polyelectrolisity, antibacterial property, and its capacity of regeneration in many applications [28]. It has been used as non-toxic floccules in the treatment of organically polluted wastewater [29].
The effects of coagulation process on hardness are observed for varying levels of hardness, which resulted in significant decrease of hardness removal. The study correlates with the results obtained by [27], wherein they had a maximum hardness removal of 84.3% by chitosan in low turbid water with initial hardness of about 204 mg/l as CaCO3.
Several experiments were carried out to determine the comparative performance of chitosan on E. coli in different turbidities. E. coli negative is present in the chitin-treated waters in all of the turbidities. The conclusive evidence was found for the negative influence of chitosan on E. coli. The regrowth of E. coli was not observed in the experiments after 24 h, which was similar to the observations by [27].
As far as sago is considered, the starch was effective both individually and as blended coagulant. Unlike polyaluminium chloride, the efficiency of the natural coagulants is not affected by pH. The pH increased their efficiency, which is one of the advantages of natural coagulants. The principle behind the efficiency of the sago from the literature can be stated as follows: Sago starch is a natural polymer that is categorized as polyelectrolyte and can act as coagulant aid. Coagulant aid can be classified according to the ionization traits, which are the anions, cations, and amphoteric (with dual charges). Bratskaya et al. [30] mentioned that among the three groups, cation polymer is normally used to remove adsorbed negatively charged particles by attracting the adsorbed particles through electrostatic force. They discovered that anion polymer and those non-ionized cannot be used to coagulate negatively charged particles.
The chemical oxygen demand (COD) reduction is influenced by the concentration of sago used; the lower the concentration the better the removal of the COD. Using less than 1.50 g L-1, better COD reduction is observed. At this low concentration, settling time did not influence the COD reduction. Similarly, concentration of sago used at lower than 1.50 g L-1 reduced the turbidity in less than 15 min of settling time. Sago concentration higher than 1.50 g L-1 increased the turbidity; however, settling time has an influence on the turbidity reduction at higher sago concentrations. This pattern is congruent with the COD removal [31].
The sago starch-graft-polyacrylamide (SS-g-PAm) coagulants were found to achieve water turbidity removal up to 96.6%. The results of this study suggest that SS-g-PAm copolymer is a potential coagulant for reducing turbidity during water treatment [32].
At its optimum concentration, D. lablab seed powder does not affect the pH of the water. Total and calcium hardness remained almost constant and were within acceptable levels according to World Health Organization standards for drinking water. Moreover, coagulation of medium to high turbidity water with D. lablab seed powder with the finest grain size reduced turbidity further. The best performance of the finest seed powder could be due to its large total surface area, whereby most of the water-soluble proteins are at the solid–liquid interface during the extraction process as stated by Gassenschmidtet al. [33]. This might have increased the concentration of active coagulation polymer in the extract, which improved the coagulation process. The coagulant extract from seeds has shown antimicrobial activity in the comparative culture test, which was also observed in the study of Tandonet al. [34].
D. lablab demonstrated the best performance with turbid water, in which a turbidity removal efficiency of 87% was observed. The restabilization of destabilized colloidal particles, which was associated with higher residual turbidities, occurred at dosages above the optimum. It is commonly observed that particles are destabilized by small amounts of hydrolyzing metal salts and that optimum destabilization corresponds with neutralization of the particles’ charge. Larger amounts of coagulants cause charge reversal so that the particles become positively charged and, thus, restabilization occurs, which results in elevated turbidity levels [35]. It has also been observed that the reduction in turbidity is associated with significant improvements in bacteriological quality. The effect of natural coagulants on turbidity removal and the antimicrobial properties against microorganisms may render them applicable for simultaneous coagulation and disinfection of water for rural and peri-urban people in developing countries [36].
It is observed that blended coagulants gave utmost efficiency as compared to the traditional alum coagulants. Here in this blending process, we reduce the alum dose up to 80%; thus, we reduce the drawbacks of the alum. Also, we can reduce the cost of the treatment using the natural coagulants instead of the traditional coagulant.
E. coli is the best coliform indicator of fecal contamination from human and animal wastes. E. colipresence is more representative of fecal pollution because it is present in higher numbers in fecal material and generally not elsewhere in the environment [37]. Results showed the absence of E. coli increases with increasing time. A greater percentage of E. coli was eliminated in higher turbidities. The aggregation and, thus, removal of E. coli was directly proportional to the concentration of particles in the suspension. Chitosan and other natural coagulants showed antibacterial effects of 2 to 4 log reductions.
Antimicrobial effects of water-insoluble chitin and coagulants were attributed to both its flocculation and bactericidal activities. A bridging mechanism has been reported for bacterial coagulation by chitosan [38]. Especially with reference to chitosan, molecules can stack on the microbial cell surface, thereby forming an impervious layer around the cell that blocks the channels, which are crucial for living cells [39]. On the other hand, cell reduction in microorganisms, such as E. coli, occurred without noticeable cell aggregation by chitosan.
This indicates that flocculation was not the only mechanism by which microbial reduction occurred. It was found that when samples were stored during 24 h, regrowth of E. coli was not observed for all turbidities. It should be noted that the test water contained no nutrient to support regrowth of E. coli, and chitosan is not a nutrient source for it. Another experiment was designed to check the effect of alum alone. Regrowth of E. coli was not observed for unaided alum after 24 h. The number of E. coli after resuspension of sediment reached to the initial numbers after 24 h and showed that it cannot be inactivated by alum. Such findings have been previously reported by Bina[40].
Conclusion
Access to clean and safe drinking water is difficult in rural areas of India. Water is generally available during the rainy season, but it is muddy and full of sediments. Because of a lack of purifying agents, communities drink water that is no doubt contaminated by sediment and human feces. Thus, the use of natural coagulants that are locally available in combination with solar radiation, which is abundant and inexhaustible, provides a solution to the need for clean and safe drinking water in the rural communities of India. Use of this technology can reduce poverty, decrease excess morbidity and mortality from waterborne diseases, and improve overall quality of life in rural areas.
The application of coagulation treatment using natural coagulants on surface water was examined in this study. The surface water was characterized by a high concentration of suspended particles with a high turbidity. At a varied range of pH, the suspended particles easily dissolved and settled along with the coagulants added. Research has been undertaken to evaluate the performance of natural starches of sago flour, bean powder, and chitin to act as coagulants individually and in blended form. In all three cases, the main variable was the dosage of the coagulant. The study shows that natural characteristics of starch and other coagulants can be an efficient coagulant for surface water but would need further study in modifying it to be efficient to the maximum. Thus, it can be concluded that the blended coagulants are the best which give maximum removal efficiency in minimum time.
It is chitin and chitosan which can readily be derivatized by utilizing the reactivity of the primary amino group and the primary and secondary hydroxyl groups to find applications in diversified areas. In this work, an attempt has been made to increase the understanding of the importance and effects of chitin at various doses and pH conditions, upon the chemical and biological properties of water. In view of this, this study will attract the attention of academicians and environmentalists.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License ( http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Saritha Vara
Author Affiliations
Department of Environmental Studies, GITAM Institute of Science, GITAM University, Visakhapatnam, Andhra Pradesh 530045, India
International Journal of Energy and Environmental Engineering 2012, 3:29 doi:10.1186/2251-6832-3-29
The electronic version of this article is the complete one and can be found online at:http://www.journal-ijeee.com/content/3/1/29
| Received: |
24 May 2012 |
| Accepted: |
30 July 2012 |
| Published: |
5 October 2012 |
© 2012 Vara; licensee BioMed Central Ltd.
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admin 31 Jan, 2013
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Anyone responsible for operating and maintaining a swimming pool or spa has to test, monitor, and control complex, interdependent chemical factors that affect the quality of water. Additionally, aquatic facilities operators must be familiar with all laws, regulations, and guidelines governing what these parameters should be.
Why? Because the worst breeding ground for any kind of microorganism is a warm (enough) stagnant pool of water. People plus stagnant water equals morbid illness. That’s why pools have to be circulated, filtered, and sanitized – with any number of chemicals or methods, but most frequently with chlorine compounds. However, adding chemicals that kill the bad microorganisms can also make the water uncomfortable, and in some cases unsafe, for swimmers. Additionally, if all the chemical factors of the water are not controlled, the very structures and equipment that hold the water and keep it clean are ruined.
So the pool professional must perform a delicate balancing act with all the factors that affect both the health and comfort of bathers and the equipment and structures that support this. Both water balance – or mineral saturation control – and sanitizer levels must constantly be maintained. This is achieved by measuring pertinent water quality factors and adding chemicals or water to keep the factors within acceptable parameters.
WATER BALANCE
Water is constantly changing. Anything and everything directly and indirectly affects the relationship of its chemical parameters to each other: sunlight, wind, rain, oil, dirt, cosmetics, other bodily wastes, and any chemicals you add to it. Balanced water not only keeps swimmers comfortable, but also protects the pool shell, plumbing, and all other related equipment from damage by etching or build-up and stains.
The pool professional is already well acquainted with pH, Total Alkalinity (TA), and Calcium Hardness (CH); along with Total Dissolved Solids (TDS) and Temperature, these are the factors that influence water balance. Water that is in balance is neither aggressive nor oversaturated. Aggressive water lacks sufficient calcium to saturate the water, so it is hungry for more. It will eat anything it comes into contact with to fill its need, including the walls of your pool or spa or the equipment it touches. Over-saturated water cannot hold any more minerals, so dissolved minerals come out of solution and form scale on pool and equipment surfaces.
The pH of pool water is critical to the effectiveness of the sanitizer as well as the water balance. pH is determined by the concentration of Hydrogen ions in a specific volume of water. It is measured on a scale of 0-14, 0-7 being acidic and 7-14 being basic.
You must maintain the pH of the water at a level that assures the sanitizer works effectively and at the same time protects the pool shell and equipment from corrosion or scaling and the bathers from discomfort or irritation. If the pH is too high, the water is out of balance, and the sanitizer’s ability to work decreases. More and more sanitizer is then needed to maintain the proper level to kill off germs. Additionally, pH profoundly affects what and how much chemical must be added to control the balance. A pH of between 7.2 – 7.6 is desirable in most cases.*
As one of the most important pool water balance and sanitation factors, pH should be checked hourly in most commercial pools.* Even if you have an automatic chemical monitor/controller on your system, you need to double- check its readings with an independent pH test. With salt- water pools, pH level goes up fast, so you need to check it more often. Tests are available that require reagents and subjective evaluation of color depth and hue to judge their pH. But different users interpret these tests differently, and results can vary wildly. The PooLPRo and ULTRAPEN PT2 give instant lab-accurate, precise, easy-to-use, objective pH measurements, invaluable in correctly determining what and how much chemical to add to maintain water balance and effective sanitizer residuals.
Total Alkalinity (TA) is the sum of all the alkaline minerals in the water, primarily in bicarbonate form in swimming pools, but also as sodium, calcium, magnesium, and potassium carbonates and hydroxides, and affects pH directly through buffering. The greater the Total Alkalinity, the more stable the pH. In general, TA should be maintained at 80 – 120 parts per million (ppm) for concrete pools to keep the pH stable.* Maintaining a low TA not only causes pH bounce, but also corrosion and staining of pool walls and eye irritation. Maintaining a high TA causes overstabilization of the water, creating high acid demands, formation of bicarbonate scale, and may result in the formation of white carbonate particles (suspended solids), which clouds the water. Reducing TA requires huge amounts of effort. So the best solution to TA problems is prevention through close monitoring and controlling. The PoolPro PS9 Titration Kit features an in-cell conductometric titration for determining alkalinity.
Calcium Hardness (CH) is the other water balance parameter pool professionals are most familiar with. CH represents the calcium content of the water and is measured in parts per million. Low CH combined with a low pH and low TA significantly increases corrosivity of water. Under these conditions, the solubility of calcium carbonate also increases. Because calcium carbonate is a major component of both plaster and marcite, these types of pool finishes will deteriorate quickly. Low CH also leads to corrosion of metal components in the pool plant, particularly in heat exchangers. Calcium carbonate usually provides a protective film on the surface of copper heat exchangers and heat sinks, but does not adversely affect the heating process. Without this protective layer, heat exchangers and associated parts can be destroyed prematurely. At the other extreme, high CH can lead to the precipitation of calcium carbonate from solution, resulting in cloudy water, the staining of structures and scaling of equipment. The recommended range for most pools is 200 – 400 ppm.* Calcium hardness should be tested at least monthly. The PoolPro PS9 Titration Kit features an in-cell conductometric titration for determining hardness.
Total Dissolved Solids (TDS) is the sum of all solids dissolved in water. If all the water in a swimming pool was allowed to evaporate, TDS would be what was left on the bottom of the pool – like the white deposits left in a boiling pot after all the water has evaporated. Some of this dissolved material includes hardness, alkalinity, cyanuric acid, chlorides, bromides, and algaecides. TDS also includes bather wastes, such as perspiration, urine, and others. TDS is often confused with Total Suspended Solids (TSS). But TDS has no bearing on the turbidity, or cloudiness, of the water, as all the solids are truly in solution. It is TSS, or undissolved, suspended solids, present in or that precipitate out of the water that make the water cloudy.
High TDS levels do affect chlorine efficiency, algae growth, and aggressive water, but only minimally. TDS levels have the greatest bearing on bather comfort and water taste – a critical concern for commercial pool operators. At levels of over 5,000 ppm, people can taste it. At over 10,000 ppm bather towels are scratchy and mineral salts accumulate around the pool and equipment. Still some seawater pools comfortably operate with TDS levels of 32,000 ppm or more.
As methods of sanitization have changed, high TDS levels have become more and more of a problem. The best course of action is to monitor and control TDS by measuring levels and periodically draining and replacing some of your mature water with new, lower TDS tap water. This is a better option than waiting until you must drain and refill your pool, which is not allowed in some areas where water conservation is required by law. However, you can also decrease TDS with desalinization equipment as long as you compensate with Calcium Hardness. (Do not adjust water balance by moving pH beyond 7.8.)*
Regardless, you do need to measure and compensate for TDS to get the most precise saturation index and adjust your pH and Calcium Hardness levels accordingly. It is generally recommended that you adjust for TDS levels by subtracting one tenth of a saturation index unit (.1) for every 1,000 ppm TDS over 1,000 to keep your water properly balanced. When TDS levels exceed 5,000 ppm, it is recommended that you subtract half of a tenth, or one twentieth of unit (.05) per 1,000 ppm.* And as the TDS approaches that of seawater, the effect is negligible.
Hot tubs and spas have a more significant problem with TDS levels than pools. Because the bather load is relatively higher, more chemicals are added for superchlorination and sudsing along with a higher concentration of bather wastes. The increased electrical conductance that high TDS water promotes can also result in electrolysis or galvanic corrosion. Every hot water pool operator should consider a TDS analyzer as a standard piece of equipment.
A TDS analyzer is required to balance the water of any pool or spa in the most precise way. PoolPro, PoolMeter and ULTRAPEN PT1 instantly display accurate TDS levels giving you the information you need to take corrective action before TDS gets out of hand.
Temperature is the last and least significant factor in maintaining water balance. As temperature increases, the water balance tends to become more basic and scale- producing. Calcium carbonate becomes less soluble, causing it to precipitate out of solution. As temperature drops, water becomes more corrosive.
In addition to helping determine water balance, temperature also affects bather comfort, evaporation, chlorination, and algae growth (warmer temperatures encourage growth). Myron L’s PooLPRo also precisely measures temperature to one tenth of a degree at the same time any other parameter is measured.
In the pool and spa industry water balance is calculated using the Langelier Saturation Index (LSI) formula:
SI = (pH + TF + CF + AF ) – 12.1
Where:
PH = pH value
TF = 0.0117 x Temperature value – 0.4116 CF = 0.4341 x ln(Hardness value) – 0.3926 AF = 0.4341 x ln(Alkalinity value) – 0.0074
The following is a general industry guideline for interpreting LSI values:
• An index between -0.5 and +0.5 is acceptable pool water.
- An index of more than +0.5 is scale-forming.
- An index below -0.5 is corrosive.
pH, Total Alkalinity, and Calcium Hardness are the largest contributors to water balance. Pool water will often be balanced if these factors are kept within the recommended ranges.
The PoolPro PS9 Titration Kit features an LSI function that steps you through alkalinity & hardness titrations and pH & temperature measurements to quickly and accurately determine LSI. An LSI calculator allows you to manipulate pH, alkalinity, hardness and temperature values in the equation to determine water balance adjustments on the spot.
SANITATION
The most immediate concern of anyone monitoring and maintaining a pool is the effectiveness of the sanitizer – the germ-killer. There are many types of sanitizers, the most common being chlorine in swimming pools and bromine in hot tubs and spas. The effectiveness of the sanitizer is directly related to the pH and, to a lesser degree, the other factors influencing water balance.
To have true chemical control, you need to monitor both the sanitizer residual and the pH and use that information to chemically treat the water. To check chlorine residual, free chlorine measurements are made. For automatic chlorine dosing systems, ORP must also be monitored to ensure proper functioning.
Free Chlorine is the amount of chlorine available as hypochlorous acid (HOCl-) and hypochlorite ion (OCl-), the concentrations of which are directly dependent on pH and temperature. pH is maintained at the level of greatest concentration of HOCl- because hypochlorous acid is a much more powerful sanitizer than hypochlorite ion. Free chlorine testing is usually required before and after opening of commercial pools. Samples should be taken at various locations to ensure even distribution. Residual levels are generally kept between 1-2 mg/L or ppm.* PooLPRo V.4.03 and later features the ability to measure ppm free chlorine in pools and spas sanitized by chlorine only. With this feature PoolPro can measure a dynamic range of chlorine concentrations wider than that of a colorimetric test kit with a greater degree of accuracy.
ORP stands for Oxidation Reduction Potential (or REDOX ) of the water and is measured in millivolts (mV). The higher the ORP, the greater the killing power of all sanitizers, not just free chlorine, in the water. ORP is the only practical method available to monitor sanitizer effectiveness. Thus, every true system of automatic chemical control depends on ORP to work.
The required ORP for disinfection will vary slightly between disinfecting systems and is also dependent on the basic water supply potential, which must be assessed and taken into account when the control system is initialized. 650 mV to 700 – 750 mV is generally considered ideal.*
Electronic controllers can be inaccurate and inconsistent when confronted with certain unique water qualities, so it is critical to perform manual testing with separate instrumentation. For automatic control dosing, it is generally recommended that you manually test pH and ORP prior to opening and then once during the day to confirm automatic readings.*
Samples for confirming automatic control dosing should be taken from a sample tap strategically located on the return line as close as possible to the probes in accordance with the manufacturer’s instructions. If manual and automatic readings consistently move further apart or closer together, you should investigate the reason for the difference.*
ORP readings can only be obtained with an electronic instrument. PoolPro provides the fastest, most precise, easy-to-use method of obtaining ORP readings to check the effectiveness of the sanitizer in any pool or spa. This is the best way to determine how safe your water is at any given moment.
SALTWATER SANITATION
A relatively new development, saltwater pools use regular salt, sodium chloride, to form chlorine with an electrical current much in the same way liquid bleach is made. As chlorine – the sanitizer – is made from the salt in the water, it is critical to maintain the salt concentration at the appropriate levels to produce an adequate level of sanitizer. It is even more important to test water parameters frequently in these types of pools and spas, as saltwater does not have the ability to respond adequately to shock loadings (superchlorination treatments).
Most saltwater chlorinators require a 2,500 – 3,000 ppm salt concentration in the water (though some may require as high as 5,000-7,000 ppm).* This can barely be tasted, but provides enough salt for the system to produce the chlorine needed to sanitize the water.
(It is important to have a good stabilizer level – 30 – 50 ppm* – in the pool, or the sunlight will burn up the chlorine. Without it, the saltwater system may not be able to keep up with the demand regardless of salt concentration.)
Taste and salt shortages are of little concern to seawater systems that maintain an average of 32,000 ppm. In these high-salt environments, you need to beware of corrosion to system components that can distort salt level and other parameter readings.
Additionally, incorrect salt concentration readings can occur in any saltwater system. The monitoring/controlling components can and do fail or become scaled— sometimes giving a false low salt reading. Thus, you must test manually for salt concentration with separate instrumentation before adding salt.
You must also test salt concentration manually with separate instrumentation to re-calibrate your system. This is critical to system functioning and production of required chlorine. Both the PoolPro and PT1 conveniently test for salt concentration at the press of a button as a check against automatic controller systems that may have disabled equipment or need to be re-calibrated.
Though no one instrument or method can be used to determine ALL of the factors that affect the comfort and sanitation of pool and spa water, PoolPro is a comprehensive water testing instrument that is reliable durable, easy-to-use and easy-to-maintain and calibrate. As a pool professional, a PoolPro will not only simplify your life, it will save you time and money.
RECORD KEEPING – WHAT TO DO WITH ALL THOSE MEASUREMENTS …
Data handling should be done objectively, and data recorded in a common format in the most accurate way. Also, data should be stored in more than one permanent location and made available for future analysis. Most municipalities require commercial aquatic facilities to keep permanent records on site and available for inspection at any time.
PoolPro makes it easy to comply with record keeping requirements. The PoolPro is an objective means to test free chlorine, ORP, pH, TDS, temperature and the mineral/salt content of any pool or spa. You just rinse and fill the cell cup by submerging the waterproof unit and press the button of the parameter you wish to measure. You immediately get a standard, numerical digital readout – no interpretation required – eliminating all subjectivity. And model PS9TK features the added ability to perform in-cell conductometric titrations for Alkalinity, Hardness and LSI on the spot. Up to 100 date-time-stamped readings can be stored in memory and then later transferred directly to a computer wirelessly using the bluDock™ accessory package. Simply pair the bluDock with your computer, then open the U2CI software application to download data. The user never touches the data, reducing the potential for human error in transcription. The data can then be imported into any program necessary for record-keeping and analysis. The bluDock is a quick and easy way to keep records that comply with governing standards.*
*Consult your governing bodies for specific testing, chemical concentrations, and all other guidelines and requirements. The ranges and methods suggested here are meant as general examples.
Save 10% when you order online here at MyronLMeters.com.
Posted by
admin 18 Jan, 2013
Tweet For Pool Professionals The PoolPro is a comprehensive high performance tool designed to simplify pool and spa water quality control for the pool professional. Both PoolPro models – the PS6 and the PS9TK feature innovative user-friendly features and functions that make [...]

PoolPro PS9TK and PoolPro PS6
For Pool Professionals
The PoolPro is a comprehensive high performance tool designed to simplify pool and spa water quality control for the pool professional. Both PoolPro models – the PS6 and the PS9TK feature innovative user-friendly features and functions that make it easy to manage parameters critical to disinfection, water balance, system maintenance and compliance.
New! Fce FAC Readings
FCE function reports FAC quickly and accurately by measuring ORP, the chemical characteristic of chlorine that directly reflects its effectiveness, cross referenced with pH. Both DPD kits and colorimeters may tell the user the FAC value of the sample in the test tube, but since the chemistry of that sample is quite different from the source water being analyzed, the results are imprecisely related to actual disinfection power.
FCE function measures the real, unaltered chemistry of source water, including moment-to-moment changes in that chemistry.
FCE can be used for other types of oxidizing germicides and will track the effect of additives, such as cyanuric acid, that degrade chlorine effectively without changing the actual concentration of free available chlorine present.
In-Cell Titration Functions
The PS9TK adds the ability to perform in-cell conductometric titrations that provides a convenient way to determine alkalinity, hardness and LSI in the field. This eliminates the need to collect and transport samples to another location for analysis. User intuitive display prompts guide you through titration procedures from start to finish. All required reagents and equipment are included in the PS9 titration kit.
Water Balance Analysis
The PS9TK features both an LSI Calculator and an LSI Titration measurement mode. The Calculator allows you to perform what-if scenarios to predict how changes in solution parameters would affect the water balance of a system. The titration measurement function allows you to accurately calculate a saturation index value of a specific solution to determine whether the solution is balanced, scaling or corrosive.
Hardness Unit Conversion The Hardness and LSI Titrations and LSI Calculator functions allow you to set the hardness unit preference to either grains of hardness or ppm CaCO3 according to your needs.
System Validation & Calibration
The PoolPro provides a fast, precise, easy-to-use method of obtaining Oxidation Reduction Potential (ORP or REDOX) mV readings to check the true level of effectiveness of ALL sanitizers in any pool or spa. ORP objectively and precisely measures sanitizer ability to burn up, or oxidize, organic matter in the water. ORP can only be determined by an electronic instrument.
PoolPro ORP mV readings serve as a necessary check to ensure automatic ORP control systems are working properly. PoolPro also provides independent readings for recalibration and to detect system failure.
Saltwater Chlorine Generation
PoolPro provides a convenient one-touch test for Mineral/Salt concentration. This is ideal for saltwater systems where manual testing with separate instrumentation is necessary to ensure the proper amount of sodium chloride is present for chlorine generation in quantities specified for microbial disinfection. PoolPro can also be used to recalibrate equipment as part of regular maintenance.
Wireless Benefits
The optional bluDock™ accessory package is an integrated data solution for your record keeping requirements, eliminating the need for additional hardware, wires and hassle. Because the user never touches the data, there is little opportunity for data tampering and human error. bluDock software has an easy to use interface with user intuitive functions for storing, sorting and exporting data.
Simply the Best
PoolPro is lightweight, portable, buoyant, waterproof, easy-to-calibrate, and easy-to-use. Simply rinse and fill the cell cup by dipping the PoolPro in the water, then press the button of the parameter you wish to measure. You immediately get a standard, numerical digital readout — eliminating all subjectivity. And you can store up to 100 date-time-stamped readings in PoolPro’s non-volatile memory.
Watch for the product launch later this year.
Posted by
admin 9 Jan, 2013
TweetIntroduction Water desalination via reverse osmosis (RO) technology provides a solution to the world’s water shortage problem. Until now, the production of fresh water from seawater has reached 21-million cubic meter per day all around the world (Wangnick, 2005). However, the success of RO technology is subject to improvement as the technology is challenged by [...]
Introduction
Water desalination via reverse osmosis (RO) technology provides a solution to the world’s water shortage problem. Until now, the production of fresh water from seawater has reached 21-million cubic meter per day all around the world (Wangnick, 2005). However, the success of RO technology is subject to improvement as the technology is challenged by a biofouling problem –a problem related to biological material development which forms a sticky layer on the membrane surface (Flemming, 1997; Baker and Dudley, 1998).
Continuous biofouling problems in RO lead to higher energy input requirement as an effect of increased biofilm resistance (Rf) and biofilm enhanced osmotic pressure (BEOP), lower quality of product water due to concentration polarization (CP) – increased concentration due to solutes accumulation on the membrane surface, (Herzberg and Elimelech, 2007), and thus significant increase in both operating and maintenance costs.
Recent studies and objectives
Recent studies show the importance of the operating conditions (e.g. flux and cross flow velocities) in RO biofouling. The presence of feed channel spacers has also been getting more attention as it may have adverse effects. A previous study (Chong et al., 2008) without feed channel spacers showed that RO biofouling was a flux driven process where higher flux increased fouling rate. It was also shown that biofouling caused a BEOP effect due to elevated CP of solutes at the membrane surface, thus resulted in loss of driving force. The BEOP effect was more severe at high flux and low crossflow operation.
In another recent study (Vrouwenvelder et al., 2009a) involving feed channel spacers suggested that flux did not affect fouling and biofouling was more severe when the crossflow velocity was higher. However, these studies were conducted on river water at low level of salinity and under no/very low flux conditions, which may suggested that BEOP effect was not observed in the above studies. These contradictory observations relating to the biofouling process in RO need to be systematically addressed as it is critical to understand the mechanism for sustainable operation of RO technology.
The objective of this study was to observe the impact of spacer towards RO biofouling as well as to investigate the development of biofilm in a spacer filled channel. The experiments were conducted at constant flux and biofouling was observed by the increase of transmembrane pressure (TMP). Observation with confocal light scanning microscope (CLSM) method was conducted to the fouled membrane and spacers to provide information of biofilm development inside the membrane module.
Materials and methods
A lab-scale set-up was arranged to resemble the real RO operation where experiments were performed with elevated salinity, high pressure, imposed flux, and permeation. The schematic diagram of the set-up is depicted in Figure 1. It is a fully-recycled system with two identical RO modules running in series. Feed solution contained constant amounts NaCl and nutrient broth (NB) to provide sufficient TOC level.
The study was conducted in the constant flux mode and biofouling was measured via the rise in TMP. A mass-flow controller was installed at the permeate side to maintain the amount of permeate withdrawn. A bacteria solution was injected into the system before the feed solution entered the RO modules and a set of microfilters (5 μm and 0.2 μm) were installed at downstream to prevent excess bacteria from entering the feed tank and turning the feed tank into an “active bioreactor”.

Model bacteria Pseudomonas aeruginosa (PAO1) was used in the experiment. Bacteria stock solution used in the biofouling tests was prepared in batch and the stock solution was replenished every 24 hours. Bacteria were grown in mixture of NB and NaCl solution where they were harvested after 24 hours and diluted into autoclaved salt solution. The concentration of bacteria was controlled and measured by optical density (OD) using UV spectrophotometer at 600 nm. Batch prepared bacteria stock solution has some advantages over using continuous feed from a chemostat (Chong et al., 2008). A more consistent and fresh bacteria load and without excess nutrient was introduced into the system as nutrient content was completely removed in the harvesting step.
Prior to every experiment, cut RO membranes (DOW Filmtec, BW-30) were soaked in Milli-Q water and sterilized in 70% ethanol solution. Similar pretreatment procedures were applied to membrane support layers and feed channel spacers prior every experiment. The spacers used in the experiments are obtained from unused Hydranautics LFC-1 spiral wound module (Figure 2).

The membranes were compacted at a maximum flux (~65 L/m2.h) overnight with Milli-Q water until a stable flux was achieved. Following compaction, the flux was set to the desired values and NaCl solution was added into the feed tank until the desired concentration was achieved. The system was let to mix for 1.5 hours. NB solution was then added into the feed tank to provide an average background nutrient concentration of 6.5 mg/L TOC. The system was allowed to well-mix for 1.5 hours.
The biofouling test was initiated by continuous injection of bacteria stock solution into the flow line at a dilution rate of 1:500 based on RO cross-flow rate. Biofilm was allowed to grow on the RO membranes. TMP rise due to biofouling was measured over time. The solution in the feed tank was removed and replaced with a fresh solution at the same NaCl and NB concentration twice per day in order to maintain the freshness level of the feed solution.
Upon completion of the fouling test, the RO system was cleaned with:
Tap water adjusted to pH 2 with HNO3 for 1.5 hours
Tap water adjusted to pH 11 with NaOH for 1.5 hours
Flowing tap water for rinsing for 1.5 hours
Final rinsing with Milli-Q water at unadjusted pH
The fouled membranes were removed from the RO cells for membrane autopsy. In this analysis, fluorescence staining methods and confocal laser scanning microscope (CLSM) were used to detect the biofilm.
Biofilms were prepared for CLSM by staining with the LIVE/DEAD BacLight Bacterial Viability Kits (Molecular Probes, L7012). It consists of SYTO 9 green-fluorescent nucleic acid stain and the red-fluorescent nucleic acid stain, propidium iodide (PI). These stains possess different spectral characteristics and different ability to penetrate healthy bacterial cells. When used alone, the SYTO 9 stain generally labels all bacteria in a population — those with intact and damaged membranes. In contrast, propidium iodide penetrates only bacteria with damaged membranes, causing a reduction in the SYTO 9 stain fluorescence when both dyes are present. Thus, with an appropriate mixture of the SYTO 9 and propidium iodide stains, bacteria with intact cell membranes stain fluorescent green, whereas bacteria with damaged membranes stain fluorescent red.
Microscopic observation and image acquisition of biofilms were performed using a confocal laser scanning microscope (ZEISS, model LSM710), equipped with Argon laser at 488 nm and DPSS561-10 laser at 561 nm. Images were captured using confocal microscope bundled program ZEN 2009.
Results and discussions
The cross-flow velocity (CFV) in RO membrane operations is known to affect fouling rate. At higher CFV, the flow causes scouring effects which results in slower fouling (Koltuniewicz et al., 1995). On the other hand, experiments of RO modules without the presence of flux shows that a higher cross-flow velocity may increase biofouling due to more nutrients supply (Vrouwenvelder et al., 2009b).
In our study, the investigation was carried out by varying the cross-flow velocity (CFV) from
0.1, 0.17, to 0.34 m/s. The NaCl concentration used was constant at 2000 mg/L and the applied flux was constant at 35 LMH. TMP values were measured overtime and normalized to the initial TMP.

Figure 3 shows the normalized TMP profiles. Faster TMP rise was observed at lower CFV and both operation with and without spacer show similar profiles. The delay of TMP rise caused by spacer was quantified by measuring the time needed for the TMP to increase by 10 % (Table 1). The effect of spacer was higher at higher CFV where the percentage of the delay was 21.21 % and 42.87 % at 0.10 m/s and 0.17 m/s respectively. An interesting phenomenon was observed during the earlier TMP rise (0-3 days) where change in CFV gives little effect on TMP profiles. Similar phenomenon was observed for operation with and without spacer. A possible explanation for this phenomenon is that during this period bacterial attachment was dominant and therefore operation at constant flux gives similar initial TMP rise. Previous studies (Chong et al., 2008) have shown previously that membrane biofouling is a flux driven process where higher flux increases the TMP rise. However, their study did not include spacers and did not focus on initial TMP rise.
Table 1. The delay of biofouling rate caused by spacer at different CFV


The effect of different salt concentrations was also investigated. In this experiment the flux and CFV were fixed at 35 LMH and 0.17 m/s respectively. Figure 4 shows the normalized TMP profile of three different NaCl concentrations in the feed solution. When the feed channel spacer was absent it was very obvious that faster TMP rise was observed at higher salt concentration. This suggests that the effect of concentration polarization (CP) increases with the salt concentration and confirms the presence of the biofilm enhanced osmotic pressure (BEOP) effect (Herzberg and Elimelech, 2007; Chong et al., 2008). This phenomenon however, was less obvious when the spacer was present on the membrane. The spacer appears to provide flow eddies thus reducing the effect of CP and to be useful to prevent biofouling on the membrane which was indicated with slower TMP rise. The spacer gives bigger effect at higher salt concentration where the time to reach 10 % TMP rise was delayed by 30 % at 100 mg/L and 2000 mg/L NaCl, and 95.7 % at 4000 mg/L (Table 2).

4.2 Biofilm development in spacer-filled RO membrane channel The development of biofilm in spacer-filled channel was observed via microscopic and microscopic method. Macroscopic images are to show overall uniformity of biofilm distribution, while the microscopic images are able to show a more detailed biofilm patterns. All of the images in this study were taken from separate experiments as the samples were unable to be reused after analysis, however all the conditions for the experiments were maintained the same.
Figure 5 shows the macroscopic images of biofilm development. The biofilm sample on the membranes and spacers were stained with 5-cyano-2,3-ditolyl tetrazolium chloride (CTC) dye. CTC stains bacteria with respiration activity and stained cells appear in red colour. Analysis was done after 0, 3, 6, and 10 days, the condition was 35 LMH flux, 0.17 m/s CFV, and 4000 mg/L NaCl concentration. Longer experiment duration gives thicker and denser biofilm, which can be seen from higher red colour intensity. The biofilms have also shown overall uniformity across the membrane area where similar patterns were observed among each spacer squares.

Figure 5. Macroscopic images of biofilm development on membranes and spacers. (A) 0-day, (B) 3-day, (C) 6-day, (D) 10-day. Biofilms stained with CTC dye and images taken with SONY NEX-5 digital camera.
Confocal laser scanning microscope (CLSM) provides a more detailed analysis of biofilm development (Figure 6). Based on the images, it appears that biofilm was initiated on the membrane; it later covered more areas and started to appear on the spacer. Areas behind the attached filaments of the spacer fiber seem to be suitable for the initial bacterial attachments rather than the centre of the spacer. Biofilm build-up observed on areas under the detached filaments was caused by higher shear due to accelerated CFV. Our experiments confirmed that biofouling in RO is a flux driven process. A lower TMP rise was observed at lower flux, which means slower biofouling rate. This is also supported with the biofilm coverage data where less coverage was observed at lower flux.

Conclusions
From the findings above, several conclusions can be drawn. The hydrodynamic condition of the flow is affecting the biofouling process. Cross flow velocity (CFV) is an important parameter and lower fouling can be achieved at higher CFV. Having feed channel spacers on the membrane is advantageous as it provides a more well-mixed flow, reduces concentration polarization and reduces TMP increase. Biofilm enhanced osmotic pressure (BEOP) was another phenomenon observed in this study. Due to the BEOP effect, a faster TMP rise was achieved at higher salinity. However, with the presence of the spacer the BEOP effect was reduced significantly.
From our microscopic analysis of biofilm shows that initial bacterial deposition and biofilm development was started on the membrane especially on areas behind the attached spacer filaments. Biofilm develops over time to cover more areas and starts to grow on the spacer at the later stages. Imposed flux also influences the biofilm development where lower biofouling is achieved at lower flux.
References
Baker, J. S. and Dudley, L. Y. (1998), “Biofouling in membrane systems – a review”, Desalination, Vol. 118, No. 1-3, pp. 81-90.
Chong, T. H., Wong, F. S. and Fane, A. G. (2008), “The effect of imposed flux on biofouling in reverse osmosis: Role of concentration polarisation and biofilm enhanced osmotic pressure phenomena”, Journal of Membrane Science, Vol. 325, No. 2, pp. 840-850.
Flemming, H. C. (1997), “Reverse osmosis membrane biofouling”, Experimental Thermal and Fluid Science, Vol. 14, No. 4, pp. 382-391.
Herzberg, M. and Elimelech, M. (2007), “Biofouling of reverse osmosis membranes: Role of biofilm-enhanced osmotic pressure”, Journal of Membrane Science, Vol. 295, No. 1-2, pp.
11-20.
Koltuniewicz, A. B., Field, R. W. and Arnot, T. C. (1995), “Cross-flow and dead-end microfiltration of oily-water emulsion. Part I: Experimental study and analysis of flux decline”, Journal of Membrane Science, Vol. 102, No. 1-3, pp. 193-207.
Suwarno, S. R., Puspitasari, V. L., Chong, T. H., Fane, A. G., Chen, X., Rice, S. A., Mcdougald, D. and Cohen, Y. (2010) “The hydrodynamic effect on biofouling in reverse osmosis membrane processes”, IWA International Young Water Professionals Conference, Sydney,
Vrouwenvelder, J. S., Hinrichs, C., Van Der Meer, W. G., Van Loosdrecht, M. C. and Kruithof, J. C. (2009b), “Pressure drop increase by biofilm accumulation in spiral wound RO and NF membrane systems: role of substrate concentration, flow velocity, substrate load and flow direction”, Biofouling, Vol. 25, No. 6, pp. 543-555.
Wangnick (2005), 2004 Worldwide Desalting Plants Directory, Global Water Intelligence, Oxford, England.
Publication Date: Jan 2014 – ISBN – 9781780404769
Posted by
admin 25 Dec, 2012
TweetTo help brighten your New Year, I have compiled a list of the top 10 New Year’s resolutions for business development – things you can do to dramatically help yourself, your brands and your company. 1. Experiment with nontraditional media Media isn’t about to stop proliferating or fragmenting. Marketers need to put a plan in [...]
To help brighten your New Year, I have compiled a list of the top 10 New Year’s resolutions for business development – things you can do to dramatically help yourself, your brands and your company.
1. Experiment with nontraditional media
Media isn’t about to stop proliferating or fragmenting. Marketers need to put a plan in place to determine the nature, extent and return on an investment of something nontraditional.
2. Stop hating the sales people
Start treating the sales folks as marketing’s clients. Start mining your marketing database and giving information back to them. Show them how the information will help make them more money.
3. Lose your fear of numbers
Decide what you want to measure before you launch a campaign. It’s infinitely easier to explain your value to the boss with hardcore data, rather than offering nothing but your good name to back up major marketing decisions.
4. Use your relationships
Word-of-mouth is your best salesman – harness it with a robust referral program. When purchasers and business owners talk, they talk about business. Make the next happy hour discussion about your company, your products, and your referral program.
Got an easy way to help build your customers’ business? Share it! MyronLMeters.com has a stockless reseller program that’s easy, effective, and risk-free. Believe me, we tell our customers.
5. Stop promoting your brands to death and start building them
Spend money on real marketing communications – rather than just promotions – to tell folks what your brand stands for. Give them good reasons to buy your products or services that have nothing to do with a special offer or freebie. Are your products as durable as Myron L meters? Tell people!
6. Don’t specialize in only Partial Customer Satisfaction (PCS)
The University of Michigan‘s American Customer Satisfaction Index shows that the average cross-industry customer satisfaction score has fallen below 75% — basically a C grade. It goes without saying there is tremendous room for improvement here.
7. Walk a mile in your customers’ shoes
Get to know what makes your customers tick and what problems they have, and let insights about them drive your decisions.
8. Account-based marketing is always a sure thing
If you can’t get to anything else, make the time to hug your best customers. The fastest way to increase revenue is through customers who already know and love your brand.
9. Stop ignoring social media
It’s not going away soon, and there are some tangible, measurable results to be gained by using new marketing channels such as blogs, podcasts, RSS and video.
10. Monitor your online reputation
Today companies must closely watch their online reputation. Think about how you can put a system in place to monitor and react in case of a reputation crisis in the blogosphere.
All of us at Myron L Meters would like to take a moment to thank you for your business, and to wish you the best for 2013. Our business nearly doubled in 2012 and we have you to thank. We have great things in store for the new year – new products, new partners, expanded international shipping, and more. Let us know how we can be a better part of your growing business.
Material from Marketing Darwinism by Paul Dunay is licensed under a Creative Commons Attribution 3.0 United States License. Original found here: http://pauldunay.com/top-10-cmo-new-years-resolutions/
Posted by
admin 25 Nov, 2012
TweetChlorine Residuals The presence of free chlorine in drinking water indicates that: 1) a sufficient amount of chlorine was added to the water to inactivate most of the bacteria and viruses that cause diarrheal disease; and, 2) the water is protected from recontamination during transport to the home, and during storage of water in the [...]
Chlorine Residuals
The presence of free chlorine in drinking water indicates that: 1) a sufficient amount of chlorine was added to the water to inactivate most of the bacteria and viruses that cause diarrheal disease; and, 2) the water is protected from recontamination during transport to the home, and during storage of water in the household. Because the presence of free residual chlorine in drinking water indicates the likely absence of disease-causing organisms, it is used as one measure of the potability of drinking water.
Adding Chlorine
When chlorine is added to water as a disinfectant, a series of reactions occurs. These reactions are graphically depicted later in this article. The first of these reactions occurs when organic materials and metals present in the water react with the chlorine and transform it into compounds that are unavailable for disinfection. The amount of chlorine used in these reactions is termed the chlorine demand of the water. Any remaining chlorine concentration after the chlorine demand is met is termed total chlorine. Total chlorine is further subdivided into: 1) the amount of chlorine that then reacts with nitrates present in the water and is transformed into compounds that are much less effective disinfectants than free chlorine (termed combined chlorine); and, 2) the free chlorine, which is the chlorine available to inactivate disease-causing organisms, and is thus a measure used to determine the potability of water.
For example, when chlorine is added to completely pure water the chlorine demand will be zero, and there will be no nitrates present, so no combined chlorine will be formed. Thus, the free chlorine concentration will be equal to the concentration of chlorine added. When chlorine is added to natural waters, especially water from surface sources such as rivers, organic material will exert a chlorine demand, and combined chlorine will be formed by reaction with nitrates. Thus, the free chlorine concentration will be less than the concentration of chlorine initially
added.
Chlorine Addition Flow Chart

Testing Free Chlorine in Drinking Water
Testing free chlorine is recommended in the following circumstances:
• To conduct dosage testing in project areas
• To monitor and evaluate projects by testing stored drinking water in households
The goal of dosage testing is to determine how much sodium hypochlorite solution to add to water that will be used for drinking to maintain free chlorine residual in the water for the average time of storage of water in the household (typically 24 hours). This goal differs from the goal of infrastructure-based (piped) water treatment systems, whose aim is effective disinfection at the endpoints (i.e., water taps) of the system. The WHO recommends “a residual concentration of free chlorine of greater than or equal to 0.5 mg/litre after at least 30 minutes contact time at pH less than 8.0.” This definition is only appropriate for users who obtain water directly from a flowing tap. A free chlorine level of 0.5 mg/L can maintain the quality of water through a distribution network, but is not optimal to maintain the quality of the water when it is stored in the home in a bucket or jerry can for 24 hours.
Recommendations:
1. At 1 hour after the addition of sodium hypochlorite solution to water there should be no more than 2.0 mg/L of free chlorine residual present (this ensures the water does not have an unpleasant taste or odor).
2. At 24 hours after the addition of sodium hypochlorite to water in containers that are used by families for water storage there should be a minimum of 0.2 mg/L of free chlorine residual present (this ensures microbiologically clean water).
This methodology is approved by the World Health Organization (WHO), and is graphically depicted below. The maximum allowable WHO value for free chlorine residual in drinking water is 5 mg/L. The minimum recommended WHO value for free chlorine residual in treated drinking water is 0.2 mg/L. CDC recommends not exceeding 2.0 mg/L due to taste concerns, and chlorine residual decays over time in stored water.

1. Free Chlorine as an Indicator of Sanitizing Strength
Chlorine, which kills bacteria by way of its power as an oxidizing agent, is the most popular germicide used in water treatment. Chlorine is not only used as a primary disinfectant, but also to establish a sufficient residual level of Free Available Chlorine (FAC) for ongoing disinfection.
FAC is the chlorine that remains after a certain amount is consumed by killing bacteria or reacting with other organic (ammonia, fecal matter) or inorganic (metals, dissolved CO2, Carbonates, etc) chemicals in solution. Measuring the amount of residual free chlorine in treated water is a well accepted method for determining its effectiveness in microbial control.
The Myron L Company FCE method for measuring residual disinfecting power is based on ORP, the specific chemical attribute of chlorine (and other oxidizing germicides) that kills bacteria and microbes.

2. FCE Free Chlorine Unit
The 6PIIFCE is the first handheld device to detect free chlorine directly, by measuring ORP. The ORP value is converted to a concentration reading (ppm) using a conversion table developed by Myron L Company through a series of experiments that precisely controlled chlorine levels and excluded interferants.
Other test methods typically rely on the user visually or digitally interpreting a color change resulting from an added reagent-dye. The reagent used radically alters the sample’s pH and converts the various chlorine species present into a single, easily measured species. This ignores the effect of changing pH on free chlorine effectiveness and disregards the fact that some chlorine species are better or worse sanitizers than others.
The Myron L Company 6PIIFCE avoids these pitfalls. The chemistry of the test sample is left unchanged from the source water. It accounts for the effect of pH on chlorine effectiveness by including pH in its calculation. For these reasons, the Ultrameter II’s FCE feature provides the best reading-to-reading picture of the rise and fall in sanitizing effectivity of free available chlorine.
The 6PIIFCE also avoids a common undesirable characteristic of other ORP-based methods by including a unique Predictive ORP value in its FCE calculation. This feature, based on a proprietary model for ORP sensor behavior, calculates a final stabilized ORP value in 1 to 2 minutes rather than the 10 to 15 minutes or more that is typically required for an ORP measurement.
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admin 13 Nov, 2012
Tweet Using Rainwater Those of us who live in cities and towns, and eat food grown on industrial farms, depend on imported water for daily survival. Our water travels hundreds of miles to reach us. It is powered by mountain-leveling coal, mega-dam hydro-power, and nuclear power. The infrastructure that brings us this water costs billions [...]

Using Rainwater
Those of us who live in cities and towns, and eat food grown on industrial farms, depend on imported water for daily survival. Our water travels hundreds of miles to reach us. It is powered by mountain-leveling coal, mega-dam hydro-power, and nuclear power. The infrastructure that brings us this water costs billions of dollars in public tax money and household utility bills.
Harvesting rainwater can reduce our need for water transport systems that threaten the health of the water cycle and our local environments. Ironically, water use is often highest in the places where rain falls the least. But whether you live in the damp Pacific Northwest, the arid Mojave desert, the thunderstorm Midwest, or beyond, you depend on problematic water infrastructures.
Rainwater harvesting is one strategy to reduce domestic water use. Harvesting rainwater and dozens of other green household practices can bring us greater sustainability. Growing plants that shade and installing insulated windows can reduce energy use. Increasing home food production reduces demand for wasteful water use in industrial fields. Above all, rainwater harvesting increases quality of life: ours, and that of life around the world.
In arid climates and places with salty irrigation water, rainwater flushes salts and chemicals out, increasing health and soil vitality.
Design landscape to welcome the rain
On any house lot, there are three potential ways to harvest the rain: direct rainfall, street harvesting, and roof harvesting.
The easiest rainwater source is that which falls on the yard. Proper placement of plants, trees, and water sources can turn your yard into a water efficient system. Shape the surface of the soil to slow down runoff, raise paths and patios, and sink all planting areas to capture the flow. Choose plants–primarily natives–that can absorb and hold water in their root systems, or pass it down to the water table. This way, rainwater doesn’t run off into the street, where it would be swept away with motor oil, into the sewer system or discharged directly into a local waterway.
The second source of rainwater is the street. Streets aren’t flat; they are graded so that water flows to the curb, down the block to a gutter and into a storm drain. In cities like San Francisco and Portland, storm drains are connected to the sewage treatment plant, and heavy rains cause the sewer plant to overflow raw and partially treated sewer into the bay or river. Other cities connect storm drains to underground creeks, and the polluted water runs straight into the bay or nearby river. By cutting curbs and digging sunken basins into the “right-of way” or “parking strip” area of the sidewalk, you can turn street rainwater from a problem to a resource. Diverted rain that falls on streets can nourish plants, protect creeks, and contribute to cleaner cities.
Store the rain- cisterns and rain barrels
The third source of rainwater is the roof. Even in areas with low rainfall this is an easy way to harvest rainwater.
For example, the roof of a 1,000 square foot house can collect around 600 gallons per ONE inch of rain! In an average year with 12 inches of rain in Los Angeles, that small roof could collect 7,200 gallons.
The rain catchment system
A water catchment system for roof rainwater is simple, and can store water for outdoor irrigation.
200 gallons of storage tucked next to a garage
• Gutters: Roof water gathers in the gutters and runs to a pipe towards the tank.
• “First Flush”: The first rain of the year is the dirtiest as it cleans the roof. This water is directed away from the tank in a “first flush system” and the subsequent water continues to the tank.
• Screen: The rainwater goes through a screen to remove leaves and debris, and then funnels into the top of the covered tank.
• Storage: The tank is dark, to prevent algea from growing, and screened, to prevent mosquitoes from entering.
• Irrigation: A hose attachment is located near the bottom for irrigation.
Rain barrels are a popular way to begin rainwater harvesting, especially in urban areas; they are low cost, and can be installed along houses, under decks, or in other unused spaces.
There is a huge range of options for cisterns, large single storage tanks. They can be made from plastic, ferrocement, metal, or fiberglass, ranging in size from 50 gallons to tens of thousands of gallons.
Indoor use
Ceramic drinking water filter: This highly-effective, passive filter removes pollutants and pathogens including viruses from drinking water.
In Australia, rainwater cisterns supply potable water to thousands of homes. In the US, it’s becoming more common for people to use rainwater indoors for non-potable uses. These systems can reduce or eliminate use of municipal or well water during the rainy season, when outdoor irrigation is unnecessary. Most household rainwater systems use a pump and pressure tank to pressurize water. Many states do not have codes covering indoor rainwater use, and people seeking permits may be required to filter and disinfect the water, increasing system cost and complexity. However, EPA and other research has shown that rainwater harvested using a “first flush” system and protected from light is safe to use for bathing and other household use. Filtering only the small amount of water used for drinking with passive filters such as the ceramic filter shown at left, or with slow sand filters, greatly reduces system cost, and offers an affordable solution for people needing clean drinking water.
Information from Greywateraction.org shared via Creative Commons Attribution-ShareAlike 3.0 Unported (CC BY-SA 3.0)