Expert Manages Storm Water Discharge in Active Construction Sites With Ultrameter II 6P: MyronLMeters.com
Tweet Mike Alberson, an expert in storm water pollution prevention, uses the Myron L Ultrameter II 6P to meet new and existing state and federal requirements for storm water monitoring. He checks for the presence of pollutants by testing the levels of total dissolved solids (TDS) and conductivity. He also tests storm water pH levels […]
Mike Alberson, an expert in storm water pollution prevention, uses the Myron L Ultrameter II 6P to meet new and existing state and federal requirements for storm water monitoring. He checks for the presence of pollutants by testing the levels of total dissolved solids (TDS) and conductivity. He also tests storm water pH levels in accordance with NPDES guidelines implemented in California in 2010 that mandate pH testing for all Risk Level 2 and 3 sites.
Though TDS and conductivity do not indicate the presence of any specific contaminant, monitoring these parameters is a good way to determine an increase in the concentration of dissolved chemical constituents generally. High conductivity or TDS levels are a red flag to Alberson to investigate potential sources of pollution.
Chemicals used in landscaping, such as herbicides, pesticides and fertilizers, as well as materials such as cement, can all potentially dissolve into storm water runoff. Additionally, acidic or basic pollutants impact the quality of water by altering the pH of the runoff. Monitoring is required because altering the pH alters the types and amounts of all chemical constituents in runoff and, thereby, its toxicity. Changes in pH also impact the ecosystem directly when they exceed the narrow range required by biota to live in the receiving waters. The new California NPDES requirements have set a pH range limit of 6.5 to 8.5 pH Units
The State Water Quality Board’s overall goal in implementing increased monitoring and reporting requirements is to evaluate the effectiveness of Best Management Practices (BMPs) on effluent pollution and the impact that construction activities have on receiving waters. Developers and inspectors like Alberson are continually challenged with preventing potential pollutants from leaving the project sites, and when that happens, they need to remediate any adverse affects on the environment.
As a prerequisite to construction, the Developer of Plan must generate and gain approval of BMPs and Storm Water Pollution Prevention Plans (SWPPPs) which take into account the nature of the project’s building schedule, phasing of the project, building materials, the projected rainfall, the percentage of impervious cover on the project and the impact that potential storm water runoff could have on receiving waters. The plans must also address the required monitoring and critical indicators of specific pollutants projected to discharge from the project site.
The site storm water inspector has to ensure that the necessary BMPs are implemented throughout the length of the project, as defined by the project SWPPP plan, which addresses project-specific site conditions and risk level determinations. Alberson uses the meter frequently on Barnhart Balfour Beatty projects as most fall into a category of Risk Level 2, which now requires pH monitoring along during a rain event of 0.5 in. or more.
New California requirements have required all SWPPP developers and inspectors to be certified by the state since Sept. 2, 2011 via a special course given by designated State Trainers of Record (TOR). Alberson is designated as a TOR and offers California’s new Qualified SWPPP Practitioner and Qualified SWPPP Developers courses.
As a trainer, Alberson passes on knowledge gained from his own experience. Through the years, he has seen inspectors send water samples off to laboratories for analysis, the results of which would not be known for up to two weeks. In addition, the pH of these samples would change in the time it took to get the samples to the labs for analysis. Alberson now trains developers and inspectors to use the Myron L Ultrameter II to immediately measure pH, thereby ensuring storm water runoff on project sites is precisely monitored for potential pollutants in real time.
In his own work as an inspector, Alberson has used the Myron L Ultrameter II to respond to potential pollution issues as they arise. For example, at Barnhart Balfour Beatty’s Otay Ranch Village #6 Elementary School project in Otay Mesa, Calif., he developed a remediation solution that prevented environmental contamination from high pH runoff resulting from a required lime treatment of the campus soil. By performing onsite testing following a rain event, Alberson was able to determine the potential runoff had a pH level of 12.5. He decided to immediately utilize a retention pond with carbon dioxide percolation control techniques. His remediation tactic worked using the meter to continuously monitor the pH until it was at a level acceptable for release into the receiving waters.
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Tweet The Ultrameter III 9P Titration Kit allows for fast, accurate alkalinity, hardness & LSI titrations in the field. The Ultrameter III 9P is based on the tried and tested design of the Ultrameter II 6P and measures conductivity, resistivity, TDS, pH, ORP, free chlorine and temperature quickly and accurately. The 9P also features new […]
The Ultrameter III 9P Titration Kit allows for fast, accurate alkalinity, hardness & LSI titrations in the field.
The Ultrameter III 9P is based on the tried and tested design of the Ultrameter II 6P and measures conductivity, resistivity, TDS, pH, ORP, free chlorine and temperature quickly and accurately. The 9P also features new parameters that allow the user to perform titrations in the field. The Ultrameter III 9P has a unique method of performing alkalinity, hardness and LSI titrations that makes field monitoring fast and feasible.
How does it work?
The 9P titrations are based on conductometric titration methods that are possible with the 9P’s advanced conductivity cell and microprocessor based design. Titrations are chemically equivalent to standard methods using colorimetric techniques, but replace color change identification of equivalence points with changes in conductivity, thereby replacing a subjective, qualitative assessment with a quantitative one. This means the instrument determines the equivalence point instead of the user and the method of analyzing the equivalence point is objective, rather than subjective.
What is a conductometric titration?
A conductometric titration is performed just like a colorimetric titration, only the equivalence point is determined by a change in conductivity rather than a change in color. This is based on the fact that changes in ionic concentration that occur as constituents react with reagents change the electrical conductivity of the solution.
A simple example can be given of the titration of a strong acid with a strong base. The acid solution, before the addition of the base, has a very high conductance owing to the concentration and mobility of the small hydrogen ions.
With the addition of the base, the hydroxide reacts with the hydrogen to form water, thus reducing the hydrogen ion concentration and effectively lowering the conductivity of the solution. The conductivity continues to decrease until all the hydrogen ions are consumed in the reaction, but then sharply increases with the next addition of base, which contains highly conductive hydroxide ions. The solution conductivity then continues to increase with each base addition. The equivalence point in this example would be a clearly defined minimum point of lowest conductivity (see Figure 2).
Not all solutions will give a plot with an equivalence point that is as easy to distinguish as the sharp upturn found in a strong acid-base titration, however. The 9P plots several reagent additions beyond any changes in conductivity and matches the derived curve to the behavior of solutions of known concentration.
Is a conductometric titration a standard method?
(Standard method comparison to methods listed in the Standard Methods for the Examination of Water and Wastewater published by the American Public Health Assn., the American WaterWorks Assn. and the Water Environment Assn.)
Myron L’s conductometric titration methods are chemically equivalent to standard methods that use the same procedure, but with pH indicators. That means that they use the same reagents in the same sequence with the same theoretical approach. The difference lies in the 9P’s ability to determine the equivalence point based on numerical data, rather than subjective observation of a color change.
The alkalinity titration is modeled after standard method 2320. The sample is titrated with sulfuric acid and conductivity changes are recorded at each titration point.
The hardness titration is modeled after standard method 2340. To reduce the affects of high alkalinity in the form of bicarbonate, acid is first added to the sample. This shifts the bicarbonate toward carbonic acid, then carbon dioxide (reference the carbonic acid equilibrium), which is gassed off the sample. The sample is buffered above pH 10 (effectively pH 12) by the addition of sodium hydroxide. EDTA reagent is then added incrementally, with conductivity measured after each addition.
The LSI titration uses a simplified version of the thermodynamic equations for the determination of the scaling tendency of water developed in 1936 by Dr. Wilfred Langelier. The user simply titrates for alkalinity and hardness, then measures pH and temperature, and the 9P generates the saturation index value automatically.
Conductometric vs. Colorimetric
The benefits of determining the equivalence points by conductometric titrations are that the user does not have to interpret any results. The 9P does it for you using objective measurements. And the 9P is a faster method. For example, a typical colorimetric titration for hardness can take up to 30 drops of reagent, while the 9P method for the same concentration only requires six to eight drops. Colorimetric distinctions are sometimes hard to make, as well, especially when adding reagents drop by drop while trying to carefully observe the precise point at which the color changes—and that can lead to inaccurate data. This is especially true in colored or turbid solutions.
The conductometric method can also be used with very dilute solutions or for solutions for which there is no suitable indicator. The conductometric titration method gives you empirical results that are calculated for you, eliminating potential sources of error. And the measurements can be stored in memory for later data transfer using the optional U2CI software and bluDock Bluetooth hardware installed on the 9P . This makes data analysis and reporting seamless.
What else can the Ultrameter III 9P do?
Alkalinity, hardness, pH and temperature values used to compute the saturation index of a sample can be manipulated in the LSI Calculator function, allowing you to perform on the spot analysis of water balance scenarios. You can use historical or theoretical data to populate the required values in the calculator.
And the 9P titration kit comes with all required accessories, reagents, and calibration solutions (see Figure 6). Streamline your field testing with an Ultrameter III 9P from MyronLMeters, where you can save 10% when you order online.
Myron L Meters is the premier online retailer of accurate, reliable, and easy-to-use Myron L meters like the Ultrameter III 9P. Save 10% when you order online at MyronLMeters.com. Find out more about the Ultrameter III 9P in our Myron L Meters – Ultrameter III 9P Titration Kit Overview video.
Tweet Water Industry News from MyronLMeters.com Published by Myron L Meters 18 April 2014 Read paper â†’ Environment Health Science World Stories California’s Governor Wants Water Tunnels. Antitax Group Wants to Know Who Pays – Businessweek Shared by Myron L Meters www.businessweek.com – California has a $25 billion plan to transport snowmelt from […]
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TweetThe right meter is essential for measuring any of several key water quality parameters:Conductivity is the ability of water to conduct an electrical current and is an indirect measure of the conductive ionic mineral concentration. The more conductive ions that are present, the more electricity can be conducted by the water. This measurement is expressed […]
The right meter is essential for measuring any of several key water quality parameters:
Conductivity is the ability of water to conduct an electrical current and is an indirect measure of the conductive ionic mineral concentration. The more conductive ions that are present, the more electricity can be conducted by the water. This measurement is expressed in microsiemens per centimeter (µS/cm) at 25º Celsius. Myron L Meters carries a complete line of conductivity meters, including the Ultrameter II 4P.
Resistivity is the inverse of conductivity. Electrical conductivity is a measure of water’s resistance to an electric current. Water itself has a weak electrical conductivity. Electric current is transported in water by dissolved ions, making conductivity measurement a quick and reliable way to monitor the total amount of ionic contaminants in water. Myron L Meters carries a complete line of resistivity meters, including inline monitor/controllers like the 753II Resistivity Digital Monitor/Controller.
Total Dissolved Solids (TDS) is also a measurement of the amount of dissolved minerals in the water. In this instance they would be called solids in solution. The quantity of dissolved solids in the solution is directly proportional to the conductivity. In this case, conductivity is the measurement but it is used to estimate TDS. It is measured with a conductivity meter but is reported as TDS in parts per million (ppm), via a complex algorithm. Myron L Meters carries a complete line of TDS meters, including the Ultrapen PT1.
pH is a measure of the concentration of hydrogen ions in the water, indicating the acidity or alkalinity of the water. On the pH scale of 0-14, a reading of 7 is considered to be neutral. Readings below 7 indicate acidic conditions, while readings above 7 indicate the water is alkaline or basic. Naturally occurring fresh waters have a pH range between 6 and 8. Myron L Meters carries a complete line of pH meters, including the Ultrapen PT2
Temperature is expressed in degrees Celsius (C) or Fahrenheit (F). Most digital handheld Myron L Meters include a temperature function.
Oxidation reduction potential (ORP)can correlate millivolt readings to the sanitization strength of the water. Microbes can cause corrosion, fouling, and disease, and oxidizing biocides are usually used to keep microbial levels under control. ORP is expressed in millivolts (mV). Myron L Meters carries a complete line of ORP meters, including the Ultrapen PT3
Free Chlorine refers to both hypochlorous acid (HOCl) and the hypochlorite (OCl–) ion or bleach, and is commonly added to water systems for disinfection. Free chlorine is typically measured in drinking water disinfection systems to find whether the water system contains enough disinfectant. Myron L Meters Ultrameter II 6PFCe and Ultrapen PT4 can both be used to measure free chlorine.
Salinity is simply a measure of the amount of salts dissolved in water, a measurement useful to pool service technicians and others. You can measure salinity with a Myron L Pool Pro PS6.
Alkalinity is a measure of the capacity of water or any solution to neutralize or “buffer” acids. This measure of acid-neutralizing capacity is important in figuring out how “buffered” the water is against sudden changes in pH. Alkalinity is a titration function of the Ultrameter III 9PTKA.
Hardness is caused by compounds of calcium and magnesium, and by a variety of other metals. As water moves through soil and rock, it dissolves very small amounts of minerals and holds them in solution. Calcium and magnesium dissolved in water are the two most common minerals that make water “hard.” Hardness is a titration function of the Ultrameter III 9PTKA.
LSI or Langelier Saturation Index helps you determine the scaling potential of water. LSI is a calculated number used to predict the calcium carbonate stability of water. It indicates whether the water will precipitate, dissolve, or be in equilibrium with calcium carbonate. LSI is a titration function of the Ultrameter III 9PTKA.
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Tweet Ultrapen PT3 ORP tester Though the measurement of free chlorine concentration is often indicated for the disinfection of water and disinfectant byproduct control, there is a better way. Because free chlorine works through oxidation, ORP instrumentation can be used to monitor and control its effectiveness. ORP measures the actual oxidation power of the solution, […]
TweetYears ago, high purity water was used only in limited applications. Today, deionized (Dl) water has become an essential ingredient in hundreds of applications including: medical, laboratory, pharmaceutical, cosmetics, electronics manufacturing, food processing, plating, countless industrial processes, and even the final rinse at the local car wash.THE DEIONIZATION PROCESSThe vast majority of dissolved impurities in […]
Years ago, high purity water was used only in limited applications. Today, deionized (Dl) water has become an essential ingredient in hundreds of applications including: medical, laboratory, pharmaceutical, cosmetics, electronics manufacturing, food processing, plating, countless industrial processes, and even the final rinse at the local car wash.
THE DEIONIZATION PROCESSThe vast majority of dissolved impurities in modern water supplies are ions such as calcium, sodium, chlorides, etc. The deionization process removes ions from water via ion exchange. Positively charged ions (cations) and negatively charged ions (anions) are exchanged for hydrogen (H+) and hydroxyl (OH-) ions, respectively, due to the resin’s greater affinity for other ions. The ion exchange process occurs on the binding sites of the resin beads. Once depleted of exchange capacity, the resin bed is regenerated with concentrated acid and caustic which strips away accumulated ions through physical displacement, leaving hydrogen or hydroxyl ions in their place.
DEIONIZER TYPESDeionizers exist in four basic forms: disposable cartridges, portable exchange tanks, automatic units, and continuous units. A two-bed system employs separate cation and anion resin beds. Mixed-bed deionizers utilize both resins in the same vessel. The highest quality water is produced by mixed-bed deionizers, while two-bed deionizers have a larger capacity. Continuous deionizers, mainly used in labs for polishing, do not require regeneration.
TESTING Dl WATER QUALITYWater quality from deionizers varies with the type of resins used, feed water quality, flow, efficiency of regeneration, remaining capacity, etc. Because of these variables, it is critical in many Dl water applications to know the precise quality. Resistivity/ conductivity is the most convenient method for testing Dl water quality. Deionized pure water is a poor electrical conductor, having a resistivity of 18.2 million ohm-cm (18.2 megohm) and conductivity of 0.055 microsiemens. It is the amount of ionized substances (or salts) dissolved in the water which determines water’s ability to conduct electricity. Therefore, resistivity and its inverse, conductivity, are good general purpose quality parameters.
Because temperature dramatically affects the conductivity of water, conductivity measurements are internationally referenced to 25°C to allow for comparisons of different samples. With typical water supplies, temperature changes the conductivity an average of 2%/°C, which is relatively easy to compensate. Deionized water, however, is much more challenging to accurately measure since temperature effects can approach 10%/°C! Accurate automatic temperature compensation, therefore, is the “heart’ of any respectable instrument.
RECOMMENDED MYRON L METERSPortable instruments are typically used to measure Dl water quality at points of use, pinpoint problems in a Dl system confirm monitor readings, and test the feed water to the system. The handheld Myron L meters have been the first choice of Dl water professionals for many years. For two-bed Dl systems, there are several usable models with displays in either microsiemens or ppm (parts per million) of total dissolved solids. The most versatile instruments for Dl water is the 4P or 6PFCE Ultrameter II™, which can measure both ultrapure mixedbed quality water and unpurified water. It should be noted that once Dl water leaves the piping, its resistivity will drop because the water absorbs dissolved carbon dioxide from the air. Measuring of ultrapure water with a hand-held instrument requires not only the right instrument, but the right technique to obtain accurate, repeatable readings. Myron L meters offer the accuracy and precision necessary for ultrapure water measurements.
Inline Monitor/controllers are generally used in the more demanding Dl water applications. Increased accuracy is realized since the degrading effect of carbon dioxide on high purity water is avoided by use of an in-line sensor (cell). This same degradation of ultrapure water is the reason there are no resistivity calibration standard solutions (as with conductivity instruments). Electronic sensor substitutes are normally used to calibrate resistivity Monitor/controllers.
Myron L Meters carries a variety of inline instruments, including resistivity Monitor/controllers designed specifically for Dl water. Seven resistivity ranges are available to suit any Dl water application: 0-20 megohm, 0-10 megohm, 0-5 megohm, 0-2 megohm, 0-1 megohm, 0-500 kilohm, and 0-200 kilohm. Temperature compensation is automatic and achieved via a dual thermistor circuit. Monitor/controller models contain an internal adjustable set point, piezo alarm connectors and a heavy-duty 10 amp relay circuit which can be used to control an alarm, valves, pump, etc. Available options include 4-20 milliamp output, 3 sensor input, 3 range capability and temperature. Internal electronic sensor substitutes are standard on all Monitor/controllers.
Sensors are available constructed in either 316 stainless steel or titanium. All sensors are provided with a 3/4” MNPT polypropylene bushing and 10 ft./3 meters of cable. Optional PVDF or stainless steel bushings can be ordered, as well as longer cable lengths up to 100 ft./30 meters.
The following table briefly covers recommended Myron L meters for Dl water applications.
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