DEIONIZED WATER APPLICATIONS: MyronLMeters.com

Posted by 11 Apr, 2014

TweetYears ago, high purity water was used only in limited applications. Today, deionized (Dl) water has become an essential ingredient in hundreds of applications including: medical, laboratory, pharmaceutical, cosmetics, electronics manufacturing, food processing, plating, countless industrial processes, and even the final rinse at the local car wash.THE DEIONIZATION PROCESSThe vast majority of dissolved impurities in […]

Years ago, high purity water was used only in limited applications. Today, deionized (Dl) water has become an essential ingredient in hundreds of applications including: medical, laboratory, pharmaceutical, cosmetics, electronics manufacturing, food processing, plating, countless industrial processes, and even the final rinse at the local car wash.

THE DEIONIZATION PROCESSThe vast majority of dissolved impurities in modern water supplies are ions such as calcium, sodium, chlorides, etc. The deionization process removes ions from water via ion exchange. Positively charged ions (cations) and negatively charged ions (anions) are exchanged for hydrogen (H+) and hydroxyl (OH-) ions, respectively, due to the resin’s greater affinity for other ions. The ion exchange process occurs on the binding sites of the resin beads. Once depleted of exchange capacity, the resin bed is regenerated with concentrated acid and caustic which strips away accumulated ions through physical displacement, leaving hydrogen or hydroxyl ions in their place.

DEIONIZER TYPESDeionizers exist in four basic forms: disposable cartridges, portable exchange tanks, automatic units, and continuous units. A two-bed system employs separate cation and anion resin beds. Mixed-bed deionizers utilize both resins in the same vessel. The highest quality water is produced by mixed-bed deionizers, while two-bed deionizers have a larger capacity. Continuous deionizers, mainly used in labs for polishing, do not require regeneration.

TESTING Dl WATER QUALITYWater quality from deionizers varies with the type of resins used, feed water quality, flow, efficiency of regeneration, remaining capacity, etc. Because of these variables, it is critical in many Dl water applications to know the precise quality. Resistivity/ conductivity is the most convenient method for testing Dl water quality. Deionized pure water is a poor electrical conductor, having a resistivity of 18.2 million ohm-cm (18.2 megohm) and conductivity of 0.055 microsiemens. It is the amount of ionized substances (or salts) dissolved in the water which determines water’s ability to conduct electricity. Therefore, resistivity and its inverse, conductivity, are good general purpose quality parameters.

Because temperature dramatically affects the conductivity of water, conductivity measurements are internationally referenced to 25°C to allow for comparisons of different samples. With typical water supplies, temperature changes the conductivity an average of 2%/°C, which is relatively easy to compensate. Deionized water, however, is much more challenging to accurately measure since temperature effects can approach 10%/°C! Accurate automatic temperature compensation, therefore, is the “heart’ of any respectable instrument.

RECOMMENDED MYRON L METERSPortable instruments are typically used to measure Dl water quality at points of use, pinpoint problems in a Dl system confirm monitor readings, and test the feed water to the system. The handheld Myron L meters have been the first choice of Dl water professionals for many years. For two-bed Dl systems, there are several usable models with displays in either microsiemens or ppm (parts per million) of total dissolved solids. The most versatile instruments for Dl water is the 4P or 6PFCE Ultrameter II™, which can measure both ultrapure mixedbed quality water and unpurified water. It should be noted that once Dl water leaves the piping, its resistivity will drop because the water absorbs dissolved carbon dioxide from the air. Measuring of ultrapure water with a hand-held instrument requires not only the right instrument, but the right technique to obtain accurate, repeatable readings. Myron L meters offer the accuracy and precision necessary for ultrapure water measurements.

Inline Monitor/controllers are generally used in the more demanding Dl water applications. Increased accuracy is realized since the degrading effect of carbon dioxide on high purity water is avoided by use of an in-line sensor (cell). This same degradation of ultrapure water is the reason there are no resistivity calibration standard solutions (as with conductivity instruments). Electronic sensor substitutes are normally used to calibrate resistivity Monitor/controllers.

Myron L Meters carries a variety of inline instruments, including resistivity Monitor/controllers designed specifically for Dl water. Seven resistivity ranges are available to suit any Dl water application: 0-20 megohm, 0-10 megohm, 0-5 megohm, 0-2 megohm, 0-1 megohm, 0-500 kilohm, and 0-200 kilohm. Temperature compensation is automatic and achieved via a dual thermistor circuit. Monitor/controller models contain an internal adjustable set point, piezo alarm connectors and a heavy-duty 10 amp relay circuit which can be used to control an alarm, valves, pump, etc. Available options include 4-20 milliamp output, 3 sensor input, 3 range capability and temperature. Internal electronic sensor substitutes are standard on all Monitor/controllers.

Sensors are available constructed in either 316 stainless steel or titanium. All sensors are provided with a 3/4” MNPT polypropylene bushing and 10 ft./3 meters of cable. Optional PVDF or stainless steel bushings can be ordered, as well as longer cable lengths up to 100 ft./30 meters.

The following table briefly covers recommended Myron L meters for Dl water applications.

DEIONIZED WATER APP TABLE

Capture

 

MyronLMeters.com is the premier internet retailer for all recommended Myron L meters above. Save 10% when you order online at MyronLMeters.com.

Categories : Uncategorized

DEIONIZED WATER APPLICATIONS: MyronLMeters.com

Posted by 11 Apr, 2014

TweetYears ago, high purity water was used only in limited applications. Today, deionized (Dl) water has become an essential ingredient in hundreds of applications including: medical, laboratory, pharmaceutical, cosmetics, electronics manufacturing, food processing, plating, countless industrial processes, and even the final rinse at the local car wash. THE DEIONIZATION PROCESS The vast majority of dissolved […]

Years ago, high purity water was used only in limited applications. Today, deionized (Dl) water has become an essential ingredient in hundreds of applications including: medical, laboratory, pharmaceutical, cosmetics, electronics manufacturing, food processing, plating, countless industrial processes, and even the final rinse at the local car wash.

THE DEIONIZATION PROCESS
The vast majority of dissolved impurities in modern water supplies are ions such as calcium, sodium, chlorides, etc. The deionization process removes ions from water via ion exchange. Positively charged ions (cations) and negatively charged ions (anions) are exchanged for hydrogen (H+) and hydroxyl (OH-) ions, respectively, due to the resin’s greater affinity for other ions. The ion exchange process occurs on the binding sites of the resin beads. Once depleted of exchange capacity, the resin bed is regenerated with concentrated acid and caustic which strips away accumulated ions through physical displacement, leaving hydrogen or hydroxyl ions in their place.

DEIONIZER TYPES
Deionizers exist in four basic forms: disposable cartridges, portable exchange tanks, automatic units, and continuous units. A two-bed system employs separate cation and anion resin beds. Mixed-bed deionizers utilize both resins in the same vessel. The highest quality water is produced by mixed-bed deionizers, while two-bed deionizers have a larger capacity. Continuous deionizers, mainly used in labs for polishing, do not require regeneration.

TESTING Dl WATER QUALITY
Water quality from deionizers varies with the type of resins used, feed water quality, flow, efficiency of regeneration, remaining capacity, etc. Because of these variables, it is critical in many Dl water applications to know the precise quality. Resistivity/ conductivity is the most convenient method for testing Dl water quality. Deionized pure water is a poor electrical conductor, having a resistivity of 18.2 million ohm-cm (18.2 megohm) and conductivity of 0.055 microsiemens. It is the amount of ionized substances (or salts) dissolved in the water which determines water’s ability to conduct electricity. Therefore, resistivity and its inverse, conductivity, are good general purpose quality parameters.

Because temperature dramatically affects the conductivity of water, conductivity measurements are internationally referenced to 25°C to allow for comparisons of different samples. With typical water supplies, temperature changes the conductivity an average of 2%/°C, which is relatively easy to compensate. Deionized water, however, is much more challenging to accurately measure since temperature effects can approach 10%/°C! Accurate automatic temperature compensation, therefore, is the “heart’ of any respectable instrument.

RECOMMENDED MYRON L METERS
Portable instruments are typically used to measure Dl water quality at points of use, pinpoint problems in a Dl system confirm monitor readings, and test the feed water to the system. The handheld Myron L meters have been the first choice of Dl water professionals for many years. For two-bed Dl systems, there are several usable models with displays in either microsiemens or ppm (parts per million) of total dissolved solids. The most versatile instruments for Dl water is the 4P or 6PFCE Ultrameter II™, which can measure both ultrapure mixedbed quality water and unpurified water. It should be noted that once Dl water leaves the piping, its resistivity will drop because the water absorbs dissolved carbon dioxide from the air. Measuring of ultrapure water with a hand-held instrument requires not only the right instrument, but the right technique to obtain accurate, repeatable readings. Myron L meters offer the accuracy and precision necessary for ultrapure water measurements.

Inline Monitor/controllers are generally used in the more demanding Dl water applications. Increased accuracy is realized since the degrading effect of carbon dioxide on high purity water is avoided by use of an in-line sensor (cell). This same degradation of ultrapure water is the reason there are no resistivity calibration standard solutions (as with conductivity instruments). Electronic sensor substitutes are normally used to calibrate resistivity Monitor/controllers.

Myron L Meters carries a variety of inline instruments, including resistivity Monitor/controllers designed specifically for Dl water. Seven resistivity ranges are available to suit any Dl water application: 0-20 megohm, 0-10 megohm, 0-5 megohm, 0-2 megohm, 0-1 megohm, 0-500 kilohm, and 0-200 kilohm. Temperature compensation is automatic and achieved via a dual thermistor circuit. Monitor/controller models contain an internal adjustable set point, piezo alarm connectors and a heavy-duty 10 amp relay circuit which can be used to control an alarm, valves, pump, etc. Available options include 4-20 milliamp output, 3 sensor input, 3 range capability and temperature. Internal electronic sensor substitutes are standard on all Monitor/controllers.

Sensors are available constructed in either 316 stainless steel or titanium. All sensors are provided with a 3/4″ MNPT polypropylene bushing and 10 ft./3 meters of cable. Optional PVDF or stainless steel bushings can be ordered, as well as longer cable lengths up to 100 ft./30 meters.

The following table briefly covers recommended Myron L meters for Dl water applications.

DEIONIZED WATER APP TABLE

Capture

 

MyronLMeters.com is the premier internet retailer for all recommended Myron L meters above. Save 10% when you order online at MyronLMeters.com.

Categories : Application Advice, Case Studies & Application Stories, Product Updates, Science and Industry Updates, Technical Tips

Frequently Asked Questions – MyronLMeters.com

Posted by 28 Jan, 2013

TweetHow long will my Standard Solutions and Buffers last? The warranty on all standards and buffers is one year from the date it is manufactured (see the label on the bottle). If the standards and buffers become contaminated by the user pouring test samples back into the bottle or inserting the probe into the bottle […]

How long will my Standard Solutions and Buffers last?

The warranty on all standards and buffers is one year from the date it is manufactured (see the label on the bottle). If the standards and buffers become contaminated by the user pouring test samples back into the bottle or inserting the probe into the bottle the solution will not be accurate and should be discarded. The life of standards and buffers can exceed 1 year if the bottle is stored tightly capped and is not exposed to direct sunlight or freezing temperatures. If the solution becomes frozen, do not remove the cap – allow the standard or buffer solution to thaw completely and shake the bottle vigorously before opening.

How do I clean the conductivity cell cup on the handheld units?

With everyday sampling, the cell cup may build up a residue or film on the cell walls that may cause the readings to become erratic. Use a 50/50 mixture of a common household cleaner (i.e. Lime-A-Way, CLR, Tilex, etc) and DI water. Pour into conductivity cell cup and scrub with a q-tip. Be sure to get around all the electrodes and the thermistor probe. On the DS handheld unit, use an acid brush to scrub the cell cup. Let it set for about 10 minutes. Rinse the cell cup thoroughly with tap water, then a final rinse with DI water.

The display on my Ultrameter II 6P reads “Error 1″. What does that mean?

This is possibly caused by contamination to the circuit board. One or more of the traces on the PCB have been jumped/bridged and there is a contamination. Possible moisture, condensation, dirt, dried salts or other condensation inside is a potential cause for this display.

Where can I get an operations manual for my meter?

Go to MyronLMeters.com. Click on Manuals and Literature at the top of the page. Once on the Manuals and Literature page, you’ll find application bulletins, operations manuals, material safety data sheets, and product datasheets.  All are free, downloadable pdf files.

How do I pick the correct range module for my Monitor or Monitor/Controller?

Pick a range module that covers 2/3 of your operating range. If you pick a range module that is too broad, then your accuracy will suffer or it will not show a number on the display. For example, if your operating range is 100-150 microsiemens, a range module of 0-200 microsiemens (-115) would be a good choice. A range module of 0- 5,000 microsiemens (-123) would not be a good choice for this application

Got questions? Visit us at MyronLMeters.com and Ask An Expert.

 

 

 

 

Categories : Application Advice, Care and Maintenance, Product Updates, Technical Tips

Reverse Osmosis and RO Meters – MyronLMeters.com

Posted by 1 Oct, 2012

TweetReverse Osmosis and RO Meters – MyronLMeters.com               Schematics of a reverse osmosis system (desalination) using a pressure exchanger. 1: Sea water inflow, 2: Fresh water flow (40%), 3: Concentrate flow (60%), 4: Sea water flow (60%), 5: Concentrate (drain), A: Pump flow (40%), B: Circulation pump, C: Osmosis unit […]

Reverse Osmosis and RO Meters – MyronLMeters.com

 

 

 

 

 

 

 

Schematics of a reverse osmosis system (desalination) using a pressure exchanger.
1: Sea water inflow,
2: Fresh water flow (40%),
3: Concentrate flow (60%),
4: Sea water flow (60%),
5: Concentrate (drain),
A: Pump flow (40%),
B: Circulation pump,
C: Osmosis unit with membrane,
D: Pressure exchanger

Reverse osmosis (RO) is a membrane-technology filtration method that removes many types of large molecules and ions from solutions by applying pressure to the solution when it is on one side of a selective membrane. The result is that the solute is retained on the pressurized side of the membrane and the pure solvent is allowed to pass to the other side. To be “selective,” this membrane should not allow large molecules or ions through the pores (holes), but should allow smaller components of the solution (such as the solvent) to pass freely.

In normal osmosis, the solvent naturally moves from an area of low solute concentration (High Water Potential), through a membrane to an area of high solute concentration (Low Water Potential). The movement of a pure solvent to equalize solute concentrations on each side of a membrane generates osmotic pressure. Applying an external pressure to reverse the natural flow of pure solvent, thus, is reverse osmosis. The process is similar to other membrane technology applications. However, there are key differences between reverse osmosis and filtration. The predominant removal mechanism in membrane filtration is straining, or size exclusion, so the process can theoretically achieve perfect exclusion of particles regardless of operational parameters such as influent pressure and concentration. Reverse osmosis, however, involves a diffusive mechanism so that separation efficiency is dependent on solute concentration, pressure, and water flux rate. Reverse osmosis is most commonly known for its use in drinking water purification from seawater, removing the salt and other substances from the water molecules.

Reverse osmosis is the process of forcing a solvent from a region of high solute concentration through a semipermeable membrane to a region of low solute concentration by applying a pressure in excess of the osmotic pressure. The largest and most important application of reverse osmosis is to the separation of pure water from seawater and brackish waters; seawater or brackish water is pressurized against one surface of the membrane, causing transport of salt-depleted water across the membrane and emergence of potable drinking water from the low-pressure side.

The membranes used for reverse osmosis have a dense layer in the polymer matrix — either the skin of an asymmetric membrane or an interfacially polymerized layer within a thin-film-composite membrane — where the separation occurs. In most cases, the membrane is designed to allow only water to pass through this dense layer, while preventing the passage of solutes (such as salt ions). This process requires that a high pressure be exerted on the high concentration side of the membrane, usually 2–17 bar (30–250 psi) for fresh and brackish water, and 40–82 bar (600–1200 psi) for seawater, which has around 27 bar (390 psi)[3] natural osmotic pressure that must be overcome. This process is best known for its use in desalination (removing the salt and other minerals from sea water to get fresh water), but since the early 1970s it has also been used to purify fresh water for medical, industrial, and domestic applications.

Osmosis describes how solvent moves between two solutions separated by a permeable membrane to reduce concentration differences between the solutions. When two solutions with different concentrations of a solute are mixed, the total amount of solutes in the two solutions will be equally distributed in the total amount of solvent from the two solutions. Instead of mixing the two solutions together, they can be put in two compartments where they are separated from each other by a semipermeable membrane. The semipermeable membrane does not allow the solutes to move from one compartment to the other, but allows the solvent to move. Since equilibrium cannot be achieved by the movement of solutes from the compartment with high solute concentration to the one with low solute concentration, it is instead achieved by the movement of the solvent from areas of low solute concentration to areas of high solute concentration. When the solvent moves away from low concentration areas, it causes these areas to become more concentrated. On the other side, when the solvent moves into areas of high concentration, solute concentration will decrease. This process is termed osmosis. The tendency for solvent to flow through the membrane can be expressed as “osmotic pressure”, since it is analogous to flow caused by a pressure differential. Osmosis is an example of diffusion.

In reverse osmosis, in a similar setup as that in osmosis, pressure is applied to the compartment with high concentration. In this case, there are two forces influencing the movement of water: the pressure caused by the difference in solute concentration between the two compartments (the osmotic pressure) and the externally applied pressure.

Around the world, household drinking water purification systems, including a reverse osmosis step, are commonly used for improving water for drinking and cooking.

Such systems typically include a number of steps:

a sediment filter to trap particles, including rust and calcium carbonate

optionally, a second sediment filter with smaller pores

an activated carbon filter to trap organic chemicals and chlorine, which will attack and degrade TFC reverse osmosis membranes

a reverse osmosis (RO) filter, which is a thin film composite membrane (TFM or TFC)

optionally, a second carbon filter to capture those chemicals not removed by the RO membrane

optionally an ultra-violet lamp for sterilizing any microbes that may escape filtering by the reverse osmosis membrane

In some systems, the carbon prefilter is omitted, and cellulose triacetate membrane (CTA) is used. The CTA membrane is prone to rotting unless protected by chlorinated water, while the TFC membrane is prone to breaking down under the influence of chlorine. In CTA systems, a carbon postfilter is needed to remove chlorine from the final product, water.

Portable reverse osmosis (RO) water processors are sold for personal water purification. To work effectively, the water feeding to these units should be under some pressure (40 psi or greater is the norm). Portable RO water processors can be used by people who live in rural areas without clean water, far away from the city’s water pipes. Rural people filter river or ocean water themselves, as the device is easy to use (saline water may need special membranes). Some travelers on long boating, fishing, or island camping trips, or in countries where the local water supply is polluted or substandard, use RO water processors coupled with one or more UV sterilizers. RO systems are also now extensively used by marine aquarium enthusiasts. In the production of bottled mineral water, the water passes through an RO water processor to remove pollutants and microorganisms. In European countries, though, such processing of Natural Mineral Water (as defined by a European Directive) is not allowed under European law. In practice, a fraction of the living bacteria can and do pass through RO membranes through minor imperfections, or bypass the membrane entirely through tiny leaks in surrounding seals. Thus, complete RO systems may include additional water treatment stages that use ultraviolet light or ozone to prevent microbiological contamination.

Membrane pore sizes can vary from 0.1 nanometres (3.9×10−9 in) to 5,000 nanometres (0.00020 in) depending on filter type. “Particle filtration” removes particles of 1 micrometre (3.9×10−5 in) or larger. Microfiltration removes particles of 50 nm or larger. “Ultrafiltration” removes particles of roughly 3 nm or larger. “Nanofiltration” removes particles of 1 nm or larger. Reverse osmosis is in the final category of membrane filtration, “hyperfiltration”, and removes particles larger than 0.1 nm.

Water and waste water purification

Rain water collected from storm drains is purified with reverse osmosis water processors and used for landscape irrigation and industrial cooling in Los Angeles and other cities, as a solution to the problem of water shortages.

In industry, reverse osmosis removes minerals from boiler water at power plants. The water is boiled and condensed repeatedly. It must be as pure as possible so that it does not leave deposits on the machinery or cause corrosion. The deposits inside or outside the boiler tubes may result in under-performance of the boiler, bringing down its efficiency and resulting in poor steam production, hence poor power production at turbine.

It is also used to clean effluent and brackish groundwater. The effluent in larger volumes (more than 500 cu. meter per day) should be treated in an effluent treatment plant first, and then the clear effluent is subjected to reverse osmosis system. Treatment cost is reduced significantly and membrane life of the RO system is increased.

The process of reverse osmosis can be used for the production of deionized water.

RO process for water purification does not require thermal energy. Flow through RO system can be regulated by high pressure pump. The recovery of purified water depends upon various factors including membrane sizes, membrane pore size, temperature, operating pressure and membrane surface area.

In 2002, Singapore announced that a process named NEWater would be a significant part of its future water plans. It involves using reverse osmosis to treat domestic wastewater before discharging the NEWater back into the reservoirs.

Food industry

In addition to desalination, reverse osmosis is a more economical operation for concentrating food liquids (such as fruit juices) than conventional heat-treatment processes. Research has been done on concentration of orange juice and tomato juice. Its advantages include a lower operating cost and the ability to avoid heat-treatment processes, which makes it suitable for heat-sensitive substances like the protein and enzymes found in most food products.

Reverse osmosis is extensively used in the dairy industry for the production of whey protein powders and for the concentration of milk to reduce shipping costs. In whey applications, the whey (liquid remaining after cheese manufacture) is concentrated with RO from 6% total solids to 10–20% total solids before UF (ultrafiltration) processing. The UF retentate can then be used to make various whey powders, including whey protein isolate used in bodybuilding formulations. Additionally, the UF permeate, which contains lactose, is concentrated by RO from 5% total solids to 18–22% total solids to reduce crystallization and drying costs of the lactose powder.

Although use of the process was once avoided in the wine industry, it is now widely understood and used. An estimated 60 reverse osmosis machines were in use in Bordeaux, France in 2002. Known users include many of the elite classed growths.

Car washing

Because of its lower mineral content, reverse osmosis water is often used in car washes during the final vehicle rinse to prevent water spotting on the vehicle. Reverse osmosis is often used to conserve and recycle water within the wash/pre-rinse cycles, especially in drought stricken areas where water conservation is important. Reverse osmosis water also enables the car wash operator to reduce the demands on the vehicle drying equipment, such as air blowers.

Maple syrup production

In 1946, some maple syrup producers started using reverse osmosis to remove water from sap before the sap is boiled down to syrup. The use of reverse osmosis allows approximately 75-90% of the water to be removed from the sap, reducing energy consumption and exposure of the syrup to high temperatures. Microbial contamination and degradation of the membranes has to be monitored.

Hydrogen production

For small-scale production of hydrogen, reverse osmosis is sometimes used to prevent formation of minerals on the surface of electrodes.

Reef aquariums

Many reef aquarium keepers use reverse osmosis systems for their artificial mixture of seawater. Ordinary tap water can often contain excessive chlorine, chloramines, copper, nitrogen, phosphates, silicates, or many other chemicals detrimental to the sensitive organisms in a reef environment. Contaminants such as nitrogen compounds and phosphates can lead to excessive, and unwanted, algae growth. An effective combination of both reverse osmosis and deionization (RO/DI) is the most popular among reef aquarium keepers, and is preferred above other water purification processes due to the low cost of ownership and minimal operating costs. Where chlorine and chloramines are found in the water, carbon filtration is needed before the membrane, as the common residential membrane used by reef keepers does not cope with these compounds.

Desalination

Areas that have either no or limited surface water or groundwater may choose to desalinate seawater or brackish water to obtain drinking water. Reverse osmosis is a common method of desalination, although 85 percent of desalinated water is produced in multistage flash plants.[5]

Large reverse osmosis and multistage flash desalination plants are used in the Middle East, especially Saudi Arabia. The energy requirements of the plants are large, but electricity can be produced relatively cheaply with the abundant oil reserves in the region. The desalination plants are often located adjacent to the power plants, which reduces energy losses in transmission and allows waste heat to be used in the desalination process of multistage flash plants, reducing the amount of energy needed to desalinate the water and providing cooling for the power plant.

Sea water reverse osmosis (SWRO) is a reverse osmosis desalination membrane process that has been commercially used since the early 1970s. Its first practical use was demonstrated by Sidney Loeb and Srinivasa Sourirajan from UCLA in Coalinga, California. Because no heating or phase changes are needed, energy requirements are low in comparison to other processes of desalination, but are still much higher than those required for other forms of water supply (including reverse osmosis treatment of wastewater).

The Ashkelon seawater reverse osmosis (SWRO) desalination plant in Israel is the largest in the world. The project was developed as a BOT (Build-Operate-Transfer) by a consortium of three international companies: Veolia water, IDE Technologies and Elran.

The typical single-pass SWRO system consists of the following components:

Intake

Pretreatment

High pressure pump

Membrane assembly

Remineralization and pH adjustment

Disinfection

Alarm/control panel

Pretreatment

Pretreatment is important when working with RO and nanofiltration (NF) membranes due to the nature of their spiral wound design. The material is engineered in such a fashion as to allow only one-way flow through the system. As such, the spiral wound design does not allow for backpulsing with water or air agitation to scour its surface and remove solids. Since accumulated material cannot be removed from the membrane surface systems, they are highly susceptible to fouling (loss of production capacity). Therefore, pretreatment is a necessity for any RO or NF system. Pretreatment in SWRO systems has four major components:

Screening of solids: Solids within the water must be removed and the water treated to prevent fouling of the membranes by fine particle or biological growth, and reduce the risk of damage to high-pressure pump components.

Cartridge filtration: Generally, string-wound polypropylene filters are used to remove particles of 1–5 µm diameter.

Dosing: Oxidizing biocides, such as chlorine, are added to kill bacteria, followed by bisulfite dosing to deactivate the chlorine, which can destroy a thin-film composite membrane. There are also biofouling inhibitors, which do not kill bacteria, but simply prevent them from growing slime on the membrane surface and plant walls.

Prefiltration pH adjustment: If the pH, hardness and the alkalinity in the feedwater result in a scaling tendency when they are concentrated in the reject stream, acid is dosed to maintain carbonates in their soluble carbonic acid form.

CO32– + H3O+ = HCO3– + H2O

HCO3– + H3O+ = H2CO3 + H2O

Carbonic acid cannot combine with calcium to form calcium carbonate scale. Calcium carbonate scaling tendency is estimated using the Langelier saturation index (LSI). Adding too much sulfuric acid to control carbonate scales may result in calcium sulfate, barium sulfate or strontium sulfate scale formation on the RO membrane.

Antiscalants: Scale inhibitors (also known as antiscalants) prevent formation of all scales compared to acid, which can only prevent formation of calcium carbonate and calcium phosphate scales. In addition to inhibiting carbonate and phosphate scales, antiscalants inhibit sulfate and fluoride scales, disperse colloids and metal oxides. Despite claims that antiscalants can inhibit silica formation, there is no concrete evidence to prove that silica polymerization can be inhibited by antiscalants. Antiscalants can control acid soluble scales at a fraction of the dosage required to control the same scale using sulfuric acid.

Some small scale desalination units use Beach wells, they are usually drilled on the seashore in close vicinity to the ocean. These intake facilities are relatively simple to build and the seawater they collect is pretreated via slow filtration through the subsurface sand/seabed formations in the area of source water extraction. Raw seawater collected using beach wells is often of better quality in terms of solids, silt, oil and grease, natural organic contamination and aquatic microorganisms, compared to open seawater intakes. Sometimes, beach intakes may also yield source water of lower salinity.

High pressure pump

The pump supplies the pressure needed to push water through the membrane, even as the membrane rejects the passage of salt through it. Typical pressures for brackish water range from 225 to 375 psi (15.5 to 26 bar, or 1.6 to 2.6 MPa). In the case of seawater, they range from 800 to 1,180 psi (55 to 81.5 bar or 6 to 8 MPa). This requires a large amount of energy.

Membrane assembly

The layers of a membrane

The membrane assembly consists of a pressure vessel with a membrane that allows feed water to be pressed against it. The membrane must be strong enough to withstand whatever pressure is applied against it. RO membranes are made in a variety of configurations, with the two most common configurations being spiral-wound and hollow-fiber.

Remineralization and pH adjustment

The desalinated water is very corrosive and is “stabilized” to protect downstream pipelines and storages, usually by adding lime or caustic to prevent corrosion of concrete lined surfaces. Liming material is used to adjust pH between 6.8 and 8.1 to meet the potable water specifications, primarily for effective disinfection and for corrosion control.

Disinfection

Post-treatment consists of preparing the water for distribution after filtration. Reverse osmosis is an effective barrier to pathogens, however post-treatment provides secondary protection against compromised membranes and downstream problems. Disinfection by means of UV lamps (sometimes called germicidal or bactericidal) may be used to sterilize pathogens which bypassed the reverse osmosis process. Chlorination or chloramination (chlorine and ammonia) protects against pathogens which may have lodged in the distribution system downstream, such as from new construction, backwash, compromised pipes, etc.[citation needed]

Disadvantages

Household reverse osmosis units use a lot of water because they have low back pressure. As a result, they recover only 5 to 15 percent of the water entering the system. The remainder is discharged as waste water. Because waste water carries with it the rejected contaminants, methods to recover this water are not practical for household systems. Waste water is typically connected to the house drains and will add to the load on household septic systems. An RO unit delivering 5 gallons of treated water a day may discharge anywhere between 20 and 90 gallons of waste water a day. For household use, however, and based on consumption of half a gallon per day, this may amount to less than a toilet-flush per day.

Large-scale industrial/municipal systems have a production efficiency of 75% – 80%, or as high as 90%, because they can generate the high pressure needed for more efficient RO filtration. On the other hand, as efficiency of waste water rates increases in commercial operations effective removal rates tend to become reduced, as evidenced by TDS counts.

Reverse Osmosis Removes Minerals

Reverse Osmosis (RO) removesd more than 90-99.99% of all the contaminants including minerals from the drinking water supply. RO removes minerals because they have larger molecules than water. The subject of minerals and RO created controversy and disagreement among water and health professionals.  The World Health Organization (WHO) stated that most of healthy minerals needed by the human body come from food or dietary supplementary sources and not from drinking tap water. In addition, some minerals found in water can be harmful to human health.  The evidence is strong that calcium and magnesium are essential elements for human body.  However, this is not to suggest that we should make up this deficiency through water consumption. Tap water presents a variety of inorganic minerals which human body has difficulty absorbing. Their presence is suspect in a wide array of degenerative diseases, such as hardening of the arteries, arthritis, kidney stones, gall stones, glaucoma, cataracts, hearing loss, emphysema, diabetes, and obesity. What minerals are available, especially in “hard” tap water, are poorly absorbed, or rejected by cellular tissue sites, and, if not evacuated, their presence may cause arterial obstruction, and internal damage (Dennison, 193; Muehling, 1994; Banik, 1989).

A number of studies have looked at the long term health effects of drinking demineralized water. However, demineralized water can be remineralized, and this process has been done in instances when processing demineralized water for consumption. Dasani water uses this process.

Water filtered or treated by RO is generally pure, clean, and healthy.  RO treatment is currently the only technology that can remove emerging contaminants (prescription drugs and perchlorate) and some others (i.e., arsenic, cyanide, and fluoride) that are difficult to remove by other methods. Consumers should not be concerned about the removal of minerals by RO system.  WHO (2009) and WQA (2011) pointed out, that the human body obtains most minerals from food or supplements, not from drinking water.

Popular RO Meters

RO Meter – RO-1: 0-1250 ppm with color band

 

 

 

 

 

 

 

 

 

Instant and accurate TDS tests
Electronic Internal Standard for easy field calibration
Fast Auto Temperature Compensation
Rugged design for years of trouble-free testing
Simple to use

 

758II: Conductivity Digital Monitor/Controller

Conductivity monitor/controller

 

 

 

 

 

 

 

 

 

The choice of professionals for years, this compact instrument has been designed specifically to demonstrate and test Point of Use (POU) reverse osmosis or distillation systems. By measuring electrical conductivity, it will quickly determine the parts per million/Total Dissolved Solids (ppm/TDS) of any drinking water.

With a single ‘before and after’ test, this handy device effectively demonstrates how your RO or distillation system eliminates harmful dissolved solids. It will also service test systems, including membrane evaluation programs.

The unique circuitry of the 750 Series II Conductivity Monitor/controllers guarantees accurate and reliable measurements. Drift-free performance is assured by “field proven” electronics, including automatic DC offset compensation and highly accurate drive voltage.

Since temperature compensation is at the heart of accurate water measurement, all Myron L Monitor/controllers feature a highly refined and precise TC circuit. This feature perfectly matches the water temperature coefficient as it changes. All models corrected to 25’C. The TC may be disabled to conform with USP requirements.

Built-in electronic calibration allows for fast quality checks without standard solutions. (Note: for maximum system accuracy standard solutions are recommended).

Aquaswitch I 

Aquaswitch

 

 

 

 

 

 

 

 

 

For use with any two-bank supply systems (DI banks, RO systems, etc)

Must use with Inline Monitor/Controller

The AQUASWITCH I is a special purpose dedicated instrument which automatically “switches” from an exhausted DI or RO bank to a fresh stand-by bank. LEDs continually give the condition of both banks. An alarm output is activated as each bank is depleted.

Ultrameter III – 9PTK

Measures 9 Parameters: Conductivity, Resistivity, TDS, Alkalinity, Hardness, LSI, pH, ORP/Free Chlorine, Temperature
LSI Calculator for hypothetical water balance calculations
Wireless data transfer capability with bluDock option
Auto-ranging delivers increased resolution across diverse applications
Adjustable Temperature Compensation and Cond/TDS conversion ratios for user-defined solutions
Nonvolatile memory of up to 100 readings for stored data protection
Date & time stamp makes record-keeping easy
pH calibration prompts alert you when maintenance is required
Auto-off minimizes energy consumption
Low battery indicator
(Includes instrument with case and solutions)

 

Categories : Product Updates, Science and Industry Updates, Technical Tips

Circuit Board Cleanliness Testing – MyronLMeters.com

Posted by 19 Sep, 2012

TweetContamination of circuit boards can bring about severe degradation of insulation resistance and dielectric strength. Cleanliness of completed circuit boards is, therefore, of vital interest. For those companies who have established circuit board cleaning procedures, the MIL Spec P-28809 has been used as a guideline for control. Now a simple “on line” test for the […]

Contamination of circuit boards can bring about severe degradation of insulation resistance and dielectric strength. Cleanliness of completed circuit boards is, therefore, of vital interest.

For those companies who have established circuit board cleaning procedures, the MIL Spec P-28809 has been used as a guideline for control. Now a simple “on line” test for the relative measurement of ionic contamination has been developed.

This fast and economical method for testing circuit board cleanliness uses an Ultrameter II™ 4P or 6P, a suitable container, and a mixture of Dl (deionized) water and alcohol. The procedure is as follows:

1. Mix a stock quantity of solution using 25 parts by volume of Dl water and 75 parts by volume of 99% isopropyl alcohol. The conductivity, measured with the Ultrameter II 4P or 6P should be a maximum of 0.166 micromhos/microseimens/cm.

2. Measure out an amount of the water/alcohol mixture equal to 100 ml per 10 square inches of circuit board surface to be tested (considering both sides of the board but not components), and add 60 ml additional. In other words: 2(L X W) (10 ml) + 60 ml = total solution needed.

3. Fill a poly “zip-lock” bag or other suitable plastic or glass container with the measured water/alcohol solution.

4. Using the measured water/alcohol solution in the poly bag, rinse out the Ultrameter II’s cell cup three (3) times, discarding the rinse solution each time. Fill the instrument cell cup a fourth time and take a meter reading. This value should be 0.166 micromhos/microseimens/cm or less and is the very clean control (or “comparison”) reading for the test.

5. Being very careful not to contaminate the PCB, totally immerse the circuit board in the solution. Seal bag. Allow it to soak for three (3) minutes with mild agitation.

6. At the conclusion of the soaking, pour the solution directly into the instruments cell cup four (4) times; take the fourth reading.

7. Compare the control reading in Step 4 with the reading taken in Step 6 (The higher the difference between the two readings, the greater the ionic contamination). Record this final extract reading for comparison with other boards tested in the same manner.

The level of cleanliness needed can be determined by each individual company.

Mil Spec P-28809 can be used as a guideline, or standards can be established based upon available data. In either event, the comparative method using the Myron L Ultrameter II will assist in the determination of that level of cleanliness.

 

 

Categories : Application Advice, Technical Tips

Application Bulletin: Deionized Water – MyronLMeters.com

Posted by 15 Sep, 2012

TweetYears ago, high purity water was used only in limited applications. Today, deionized (Dl) water has become an essential ingredient in hundreds of applications including: medical, laboratory, pharmaceutical, cosmetics, electronics manufacturing, food processing, plating, countless industrial processes, and even the final rinse at the local car wash. THE DEIONIZATION PROCESS The vast majority of dissolved […]

Years ago, high purity water was used only in limited applications. Today, deionized (Dl) water has become an essential ingredient in hundreds of applications including: medical, laboratory, pharmaceutical, cosmetics, electronics manufacturing, food processing, plating, countless industrial processes, and even the final rinse at the local car wash.

THE DEIONIZATION PROCESS

The vast majority of dissolved impurities in modern water supplies are ions such as calcium, sodium, chlorides, etc. The deionization process removes ions from water via ion exchange. Positively charged ions (cations) and negatively charged ions (anions) are exchanged for hydrogen (H+) and hydroxyl (OH-) ions, respectively, due to the resin’s greater affinity for other ions. The ion exchange process occurs on the binding sites of the resin beads. Once depleted of exchange capacity, the resin bed is regenerated with concentrated acid and caustic which strips away accumulated ions through physical displacement, leaving hydrogen or hydroxyl ions in their place.

DEIONIZER TYPES

Deionizers exist in four basic forms: disposable cartridges, portable exchange tanks, automatic units, and continuous units. A two-bed system employs separate cation and anion resin beds. Mixed-bed deionizers utilize both resins in the same vessel. The highest quality water is produced by mixed-bed deionizers, while two-bed deionizers have a larger capacity. Continuous deionizers, mainly used in labs for polishing, do not require regeneration.

TESTING Dl WATER QUALITY

Water quality from deionizers varies with the type of resins used, feed water quality, flow, efficiency of regeneration, remaining capacity, etc. Because of these variables, it is critical in many Dl water applications to know the precise quality. Resistivity/ conductivity is the most convenient method for testing Dl water quality. Deionized pure water is a poor electrical conductor, having a resistivity of 18.2 million ohm-cm (18.2 megohm) and conductivity of 0.055 microsiemens. It is the amount of ionized substances (or salts) dissolved in the water which determines water’s ability to conduct electricity. Therefore, resistivity and its inverse, conductivity, are good general purpose quality parameters.

Because temperature dramatically affects the conductivity of water, conductivity measurements are internationally referenced to 25°C to allow for comparisons of different samples. With typical water supplies, temperature changes the conductivity an average of 2%/°C, which is relatively easy to compensate. Deionized water, however, is much more challenging to accurately measure since temperature effects can approach
10%/°C! Accurate automatic temperature compensation, therefore, is the “heart’ of any respectable instrument.

RECOMMENDED INSTRUMENTATION

Portable instruments are typically used to measure Dl water quality at points of use, pinpoint problems in a Dl system confirm monitor readings, and test the feed water to the system. The handheld Myron L meters have been the first choice of Dl water professionals for many years. For two-bed Dl systems, there are several usable models with displays in either microsiemens or ppm (parts per million) of total dissolved solids. The most versatile instruments for Dl water is the 4P or 6P Ultrameter II™, which can measure both ultrapure mixed- bed quality water and unpurified water. It should be noted that once Dl water leaves the piping, its resistivity will drop because the water absorbs dissolved carbon dioxide from the air. Measuring of ultrapure water with a hand-held instrument requires not only the right instrument, but the right technique to obtain accurate, repeatable readings. Myron L meters offer the accuracy and precision necessary for ultrapure water measurements.

In-line Monitor/controllers are generally used in the more demanding Dl water applications. Increased accuracy is realized since the degrading effect of carbon dioxide on high purity water is avoided by use of an in-line sensor (cell). This same degradation of ultrapure water is the reason there are no resistivity calibration standard solutions (as with conductivity instruments). Electronic sensor substitutes are normally used to calibrate resistivity Monitor/controllers.

Myron L manufactures a variety of in-line instruments, including resistivity Monitor/controllers which are designed specifically for Dl water. Seven resistivity ranges are available to suit any Dl water application: 0-20 megohm, 0-10 megohm,
0-5 megohm, 0-2 megohm, 0-1 megohm, 0-500 kilohm, and 0-200 kilohm. Temperature compensation is automatic and achieved via a dual thermistor circuit. Monitor/controller models contain an internal adjustable set point, Piezo alarm connectors and a heavy-duty 10 amp relay circuit which can be used to control an alarm, valves, pump, etc. Available options include 4-20 milliamp output, 3 sensor input, 3 range capability and temperature. Internal electronic sensor substitutes are standard on all Monitor/controllers.

Sensors are available constructed in either 316 stainless steel or titanium. All sensors are provided with a 3/4″ MNPT polypropylene bushing and 10 ft./3 meters of cable. Optional PVDF or stainless steel bushings can be ordered, as well as longer cable lengths up to 100 ft./30 meters.

For details  and recommendations, please refer to Myron L data sheets, visit our website (www.myronlmeters.com), or contact us by email (myronlmeters@gmail.com).

 

 

 

Categories : Technical Tips

Reverse Osmosis and Measurement for Home and Commercial Systems

Posted by 23 Aug, 2012

Tweet OSMOSIS Osmosis is the phenomenon of lower dissolved solids in water passing through a semi-permeable membrane into higher dissolved solids water until a near equilibrium is reached. Reverse Osmosis (RO) is a membrane process of purification which removes most of the total dissolved solids (TDS) in water by reversing the natural process of osmosis. […]

OSMOSIS

Osmosis is the phenomenon of lower dissolved solids in water passing through a semi-permeable membrane into higher dissolved solids water until a near equilibrium is reached. Reverse Osmosis (RO) is a membrane process of purification which removes most of the total dissolved solids (TDS) in water by reversing the natural process of osmosis. Pressure is applied to a TDS-concentrated solution against a semi-permeable membrane, causing pure water to diffuse through the membrane. RO has become an important process for a wide variety of applications including: medical, laboratory, desalination, industrial wastewater, Deionized (Dl) pretreatment, and drinking water.

TESTING RO WATER QUALITY

Electrical conductivity is the most convenient method for testing RO water quality and membrane performance. Pure water is actually a poor electrical conductor. The amount of ionized substances (salts, acids, or bases) dissolved in water determines its conductivity. Normally, the vast majority of the dissolved minerals in tap, surface or ground water are conductive impurities. Myron L Company has conducted extensive research relating conductivity to TDS, resulting in instrumentation and calibration solutions which have become the standard of the RO industry.

When calibrating your conductivity instrument for testing fresh water, the “442 Natural Water Standard™” solutions are the best choice. These solutions are available in various concentrations.
442 solutions contain the following salts diluted in pure water: 40% sodium bicarbonate, 40% sodium sulfate and 20% sodium chloride. These are the most common salt compounds in surface and ground water. A sodium chloride solution provides better results in brackish or sea water because the predominant salt in these waters is sodium chloride.

ORP

ORP (Oxidation Reduction Potential/REDOX) and pH are important parameters in measuring the success and useful life of an RO membrane. The ORP may be used to determine the activity of an oxidizer. RO membranes are susceptible to attack by oxidizers such as chlorine, bromine, ozone and hydrogen peroxide. The activity of the oxidizer is more informative than the chemical residual because it determines the ability and speed of oxidation. A high ORP reading would indicate a need for pretreatment. A low ORP may indicate biological activity which may cause fouling of the membranes.

ORP can also be used to determine an overfeed of sodium bisulfite, which is used to reduce chlorine. If the ORP reading is under 200 mV, you have a reducing condition. This overfeed costs extra money and can lead to environmental discharge problems. It is best to check the reject water, where the concentration is highest. This will show even minute quantities of oxidizers or reducers.

pH

pH is very useful in predicting membrane life and the scaling potential of feedwater. The higher the pH and calcium, the more likely it is that scale will form on the membranes. However, with silicon based compounds, a low pH will increase the tendency for scaling. Membranes also have a pH range where operation is optimal. It is often useful to check the pH of the reject water to help determine scaling potential.

HOME SYSTEMS
Myron L Meters carries single and multiple range handheld instruments. Model RO-1 and RO-1NC are reliable, single range instruments used to demonstrate the RO process to a prospective buyer. The color coding of the model RO-1 dial dramatizes the difference between high TDS (red- above EPA recommended limits for drinking water), medium TDS (orange – within EPA recommended standards for drinking water), and low TDS RO water (blue-high purity water). Installers prefer the three range 532 models or TechPro II™ TP1 or TPH1 because they are ideal for accurately testing both feed and product water.

COMMERCIAL/INDUSTRIAL
Larger RO systems such as those found in bottled water plants, hospitals, industrial process, or seawater desalination require continuous monitoring to verify water quality and membrane condition. For continuous measurement of water quality, Myron L Meters carries the 720 and 750 Series II Monitor/ controllers. Monitor only, and monitor/controller models are available. Monitor/controller models contain an adjustable set point and a heavy-duty 10 amp relay which can be used to activate alarms, valves, autodialers, etc. A variety of options and outputs are available to cost-effectively tailor the monitor to the particular RO application.

The Ultrameter™ 9PTK, 6PII and 4PII are preferred by water treatment professionals for calibrating and checking Commercial/industrial RO systems. They appreciate the waterproof case, ability to store and record 100 memory data records, and three preprogrammed solution curves. Ultrameters are compact, but their multiple parameters give them the versatility of several instruments.

Myron L Meters also carries pen style meterss for dip or scoop sampling. The ULTRAPEN PT1 delivers stable, lab-accurate readings of Conductivity, TDS, Salinity and Temperature. The PT2 pH and Temperature pen is also available for spot checks and pretreatment screening. Both pens are waterproof, durable, and easy to use with one-button functioning.

Visit us here to save 10% on any of our Myron L meters: http://www.myronlmeters.com/Digital-Multiparameter-Meters-s/48.htm

Categories : Product Updates, Science and Industry Updates

Deionized water

Posted by 9 Aug, 2012

Tweet     Today, deionized (Dl) water has become an essential ingredient in hundreds of applications including: medical, laboratory, pharmaceutical, cosmetics, electronics manufacturing, food processing, plating, countless industrial processes –   even the final rinse  at the local car wash. THE DEIONIZATION PROCESS Most dissolved impurities in modern water supplies are ions like calcium, sodium, chlorides, […]

 

 

Today, deionized (Dl) water has become an essential ingredient in hundreds of applications including: medical, laboratory, pharmaceutical, cosmetics, electronics manufacturing, food processing, plating, countless industrial processes –   even the final rinse  at the local car wash.

THE DEIONIZATION PROCESS

Most dissolved impurities in modern water supplies are ions like calcium, sodium, chlorides, etc. The deionization process removes ions from water via ion exchange. Positively charged ions (cations) and negatively charged ions (anions) are exchanged for hydrogen (H+) and hydroxyl (OH-) ions,  respectively, due  to the  resin’s greater affinity for other ions. The ion exchange process occurs on the binding sites of the resin beads. Once depleted of exchange capacity, the resin bed is regenerated with concentrated acid and caustic which strips away accumulated ions through physical displacement, leaving hydrogen or hydroxyl ions in their place.

DEIONIZER TYPES

Deionizers exist in four basic forms: disposable cartridges, portable exchange tanks, automatic units, and continuous units. A two-bed system employs separate cation and anion resin beds. Mixed-bed deionizers utilize both resins in the same vessel. The highest quality water is produced by mixed-bed deionizers, while two-bed deionizers have a larger capacity. Continuous deionizers, mainly used in labs for polishing, do not require regeneration.

TESTING Dl WATER QUALITY

Water quality from deionizers varies with the type of resins used, feed  water  quality,  flow, efficiency  of regeneration, remaining capacity, etc. Because of these variables, it is critical in many Dl water applications to know the precise quality. Resistivity/ conductivity is the most convenient method for testing Dl water quality. Deionized pure water is a poor electrical conductor, having a resistivity of 18.2 million ohm-cm (18.2 megohm) and conductivity of 0.055 microsiemens. It is the amount of ionized substances (or salts) dissolved in the water which determines water’s ability to conduct electricity. Therefore, resistivity and its inverse, conductivity, are good general purpose quality parameters.

Because temperature dramatically affects the conductivity of water, conductivity measurements are internationally referenced to 25°C to allow for comparisons of different samples. With typical water supplies, temperature changes the conductivity an average of 2%/°C, which is relatively easy to compensate. Deionized water, however, is much more challenging to accurately measure since temperature effects can approach 10%/°C!  Accurate automatic temperature compensation, therefore, is the heart of any respectable instrument.

 RECOMMENDED INSTRUMENTATION

Portable instruments are typically used to measure Dl water quality at points of use, pinpoint problems in a Dl system confirm monitor readings, and test the feed water to the system. The handheld Myron L meters have been the  first choice of Dl water professionals for many years. For two-bed Dl systems, there are several usable models with displays in either microsiemens or ppm (parts per million) of total dissolved solids. The most versatile instruments for Dl water is the Ultrameter II 4P or Ultrameter II 6PFCE , which can measure both ultrapure mixed-bed quality water and unpurified water. It should be noted that once Dl water leaves the piping, its resistivity will drop because the water absorbs dissolved carbon dioxide from the air.  Measuring of ultrapure water with a hand-held instrument requires not only the right instrument, but the right technique to obtain accurate, repeatable readings. Myron L meters offer the accuracy and precision necessary for ultrapure water measurements.

In-line Monitor/controllers are generally used in the more demanding Dl water applications. Increased accuracy is realized since the degrading effect of carbon dioxide on high purity water is avoided by use of an in-line sensor (cell). This same degradation of ultrapure water is the reason there are no resistivity calibration standard solutions (as with conductivity instruments). Electronic sensor substitutes are normally used to calibrate resistivity Monitor/controllers.

Myron L Meters carries a variety of in-line instruments, including resistivity Monitor/controllers which are designed specifically for Dl water. Seven resistivity  ranges are  available to suit any Dl water application: 0-20 megohm, 0-10 megohm,

0-5 megohm,  0-2 megohm,  0-1 megohm,  0-500 kilohm, and 0-200 kilohm. Temperature compensation is automatic and achieved via a dual thermistor circuit. Monitor/controller models contain an internal adjustable set point, Piezo alarm connectors and a heavy-duty 10 amp relay circuit which can be used to control an alarm, valves, pump, etc. Available options include 4-20 milliamp output, 3 sensor input, 3 range capability and temperature.  Internal electronic sensor substitutes are standard on all Monitor/controllers.

 

Categories : Application Advice, Science and Industry Updates, Technical Tips

6 Tips for Measuring pH of Pure DI Water

Posted by 28 Dec, 2010

TweetMeasuring the pH of pure DI water is easy when you know what to expect. In theory, pure water should have a pH of 7. When you actually measure the pH, it will most likely fall between 5.5 and 7 due to its absorption of CO2 from the atmosphere. This natural occurrence forms carbonic acid […]

Measuring the pH of pure DI water is easy when you know what to expect. In theory, pure water should have a pH of 7. When you actually measure the pH, it will most likely fall between 5.5 and 7 due to its absorption of CO2 from the atmosphere. This natural occurrence forms carbonic acid in the water, lowering the pH. Since DI water is pure, there is nothing to buffer it and stabilize the pH. Below are a few tips to increase the accuracy of your pH measurements.

Tips for accurate pH readings

  1. First and foremost, use a high quality ph meter and ensure that it is properly calibrated with pH buffer solution. Check the manufacturer’s recommendations for calibration. The Ultrameter II 6P and the Techpro II TPH1 are portable pH meters that are extremely accurate and easy to use.
  2. When using a portable pH meter, avoid cross-contamination by thoroughly rinsing with the DI water that you will be sampling. If a glass beaker or cup is to be used, rinse that as well.
  3. Use small samples and minimize exposure to air, as this will lower the pH value. Taking samples from an open-air drum or tank will typically give erroneous readings. Collect samples from a sample port if possible.
  4. If you have access to high-purity reagent grade KCl (Potassium Chloride) salts, then you can buffer the DI water to stabilize the pH. Adding a tiny amount to the pure DI water sample will increase the ionic strength and reduce the absorption of CO2 from the atmosphere. Be careful not to contaminate the KCl salts. Use proper tools/utensils to add the KCl salts
  5. If no salt is available and all you need is a quick check of your system, you can flow the water from a sample port into your portable pH meter to measure the pH values. This will take slightly longer to stabilize. Be sure to use an accurate, waterproof pH meter and hold it closely to the sample port.
  6. Changes in temperature can affect the pH. Use a pH meter that is temperature compensated to remedy this issue.

If you need pH buffer solution, you can find it here at an affordable price.

Categories : Application Advice, Technical Tips