Archive for November, 2012
TweetChlorine Residuals The presence of free chlorine in drinking water indicates that: 1) a sufficient amount of chlorine was added to the water to inactivate most of the bacteria and viruses that cause diarrheal disease; and, 2) the water is protected from recontamination during transport to the home, and during storage of water in the [...]
The presence of free chlorine in drinking water indicates that: 1) a sufficient amount of chlorine was added to the water to inactivate most of the bacteria and viruses that cause diarrheal disease; and, 2) the water is protected from recontamination during transport to the home, and during storage of water in the household. Because the presence of free residual chlorine in drinking water indicates the likely absence of disease-causing organisms, it is used as one measure of the potability of drinking water.
When chlorine is added to water as a disinfectant, a series of reactions occurs. These reactions are graphically depicted later in this article. The first of these reactions occurs when organic materials and metals present in the water react with the chlorine and transform it into compounds that are unavailable for disinfection. The amount of chlorine used in these reactions is termed the chlorine demand of the water. Any remaining chlorine concentration after the chlorine demand is met is termed total chlorine. Total chlorine is further subdivided into: 1) the amount of chlorine that then reacts with nitrates present in the water and is transformed into compounds that are much less effective disinfectants than free chlorine (termed combined chlorine); and, 2) the free chlorine, which is the chlorine available to inactivate disease-causing organisms, and is thus a measure used to determine the potability of water.
For example, when chlorine is added to completely pure water the chlorine demand will be zero, and there will be no nitrates present, so no combined chlorine will be formed. Thus, the free chlorine concentration will be equal to the concentration of chlorine added. When chlorine is added to natural waters, especially water from surface sources such as rivers, organic material will exert a chlorine demand, and combined chlorine will be formed by reaction with nitrates. Thus, the free chlorine concentration will be less than the concentration of chlorine initially
Chlorine Addition Flow Chart
Testing Free Chlorine in Drinking Water
Testing free chlorine is recommended in the following circumstances:
• To conduct dosage testing in project areas
• To monitor and evaluate projects by testing stored drinking water in households
The goal of dosage testing is to determine how much sodium hypochlorite solution to add to water that will be used for drinking to maintain free chlorine residual in the water for the average time of storage of water in the household (typically 24 hours). This goal differs from the goal of infrastructure-based (piped) water treatment systems, whose aim is effective disinfection at the endpoints (i.e., water taps) of the system. The WHO recommends “a residual concentration of free chlorine of greater than or equal to 0.5 mg/litre after at least 30 minutes contact time at pH less than 8.0.” This definition is only appropriate for users who obtain water directly from a flowing tap. A free chlorine level of 0.5 mg/L can maintain the quality of water through a distribution network, but is not optimal to maintain the quality of the water when it is stored in the home in a bucket or jerry can for 24 hours.
1. At 1 hour after the addition of sodium hypochlorite solution to water there should be no more than 2.0 mg/L of free chlorine residual present (this ensures the water does not have an unpleasant taste or odor).
2. At 24 hours after the addition of sodium hypochlorite to water in containers that are used by families for water storage there should be a minimum of 0.2 mg/L of free chlorine residual present (this ensures microbiologically clean water).
This methodology is approved by the World Health Organization (WHO), and is graphically depicted below. The maximum allowable WHO value for free chlorine residual in drinking water is 5 mg/L. The minimum recommended WHO value for free chlorine residual in treated drinking water is 0.2 mg/L. CDC recommends not exceeding 2.0 mg/L due to taste concerns, and chlorine residual decays over time in stored water.
1. Free Chlorine as an Indicator of Sanitizing Strength
Chlorine, which kills bacteria by way of its power as an oxidizing agent, is the most popular germicide used in water treatment. Chlorine is not only used as a primary disinfectant, but also to establish a sufficient residual level of Free Available Chlorine (FAC) for ongoing disinfection.
FAC is the chlorine that remains after a certain amount is consumed by killing bacteria or reacting with other organic (ammonia, fecal matter) or inorganic (metals, dissolved CO2, Carbonates, etc) chemicals in solution. Measuring the amount of residual free chlorine in treated water is a well accepted method for determining its effectiveness in microbial control.
The Myron L Company FCE method for measuring residual disinfecting power is based on ORP, the specific chemical attribute of chlorine (and other oxidizing germicides) that kills bacteria and microbes.
2. FCE Free Chlorine Unit
The 6PIIFCE is the first handheld device to detect free chlorine directly, by measuring ORP. The ORP value is converted to a concentration reading (ppm) using a conversion table developed by Myron L Company through a series of experiments that precisely controlled chlorine levels and excluded interferants.
Other test methods typically rely on the user visually or digitally interpreting a color change resulting from an added reagent-dye. The reagent used radically alters the sample’s pH and converts the various chlorine species present into a single, easily measured species. This ignores the effect of changing pH on free chlorine effectiveness and disregards the fact that some chlorine species are better or worse sanitizers than others.
The Myron L Company 6PIIFCE avoids these pitfalls. The chemistry of the test sample is left unchanged from the source water. It accounts for the effect of pH on chlorine effectiveness by including pH in its calculation. For these reasons, the Ultrameter II’s FCE feature provides the best reading-to-reading picture of the rise and fall in sanitizing effectivity of free available chlorine.
The 6PIIFCE also avoids a common undesirable characteristic of other ORP-based methods by including a unique Predictive ORP value in its FCE calculation. This feature, based on a proprietary model for ORP sensor behavior, calculates a final stabilized ORP value in 1 to 2 minutes rather than the 10 to 15 minutes or more that is typically required for an ORP measurement.
Tweet Using Rainwater Those of us who live in cities and towns, and eat food grown on industrial farms, depend on imported water for daily survival. Our water travels hundreds of miles to reach us. It is powered by mountain-leveling coal, mega-dam hydro-power, and nuclear power. The infrastructure that brings us this water costs billions [...]
Those of us who live in cities and towns, and eat food grown on industrial farms, depend on imported water for daily survival. Our water travels hundreds of miles to reach us. It is powered by mountain-leveling coal, mega-dam hydro-power, and nuclear power. The infrastructure that brings us this water costs billions of dollars in public tax money and household utility bills.
Harvesting rainwater can reduce our need for water transport systems that threaten the health of the water cycle and our local environments. Ironically, water use is often highest in the places where rain falls the least. But whether you live in the damp Pacific Northwest, the arid Mojave desert, the thunderstorm Midwest, or beyond, you depend on problematic water infrastructures.
Rainwater harvesting is one strategy to reduce domestic water use. Harvesting rainwater and dozens of other green household practices can bring us greater sustainability. Growing plants that shade and installing insulated windows can reduce energy use. Increasing home food production reduces demand for wasteful water use in industrial fields. Above all, rainwater harvesting increases quality of life: ours, and that of life around the world.
In arid climates and places with salty irrigation water, rainwater flushes salts and chemicals out, increasing health and soil vitality.
Design landscape to welcome the rain
On any house lot, there are three potential ways to harvest the rain: direct rainfall, street harvesting, and roof harvesting.
The easiest rainwater source is that which falls on the yard. Proper placement of plants, trees, and water sources can turn your yard into a water efficient system. Shape the surface of the soil to slow down runoff, raise paths and patios, and sink all planting areas to capture the flow. Choose plants–primarily natives–that can absorb and hold water in their root systems, or pass it down to the water table. This way, rainwater doesn’t run off into the street, where it would be swept away with motor oil, into the sewer system or discharged directly into a local waterway.
The second source of rainwater is the street. Streets aren’t flat; they are graded so that water flows to the curb, down the block to a gutter and into a storm drain. In cities like San Francisco and Portland, storm drains are connected to the sewage treatment plant, and heavy rains cause the sewer plant to overflow raw and partially treated sewer into the bay or river. Other cities connect storm drains to underground creeks, and the polluted water runs straight into the bay or nearby river. By cutting curbs and digging sunken basins into the “right-of way” or “parking strip” area of the sidewalk, you can turn street rainwater from a problem to a resource. Diverted rain that falls on streets can nourish plants, protect creeks, and contribute to cleaner cities.
Store the rain- cisterns and rain barrels
The third source of rainwater is the roof. Even in areas with low rainfall this is an easy way to harvest rainwater.
For example, the roof of a 1,000 square foot house can collect around 600 gallons per ONE inch of rain! In an average year with 12 inches of rain in Los Angeles, that small roof could collect 7,200 gallons.
The rain catchment system
A water catchment system for roof rainwater is simple, and can store water for outdoor irrigation.
200 gallons of storage tucked next to a garage
• Gutters: Roof water gathers in the gutters and runs to a pipe towards the tank.
• “First Flush”: The first rain of the year is the dirtiest as it cleans the roof. This water is directed away from the tank in a “first flush system” and the subsequent water continues to the tank.
• Screen: The rainwater goes through a screen to remove leaves and debris, and then funnels into the top of the covered tank.
• Storage: The tank is dark, to prevent algea from growing, and screened, to prevent mosquitoes from entering.
• Irrigation: A hose attachment is located near the bottom for irrigation.
Rain barrels are a popular way to begin rainwater harvesting, especially in urban areas; they are low cost, and can be installed along houses, under decks, or in other unused spaces.
There is a huge range of options for cisterns, large single storage tanks. They can be made from plastic, ferrocement, metal, or fiberglass, ranging in size from 50 gallons to tens of thousands of gallons.
Ceramic drinking water filter: This highly-effective, passive filter removes pollutants and pathogens including viruses from drinking water.
In Australia, rainwater cisterns supply potable water to thousands of homes. In the US, it’s becoming more common for people to use rainwater indoors for non-potable uses. These systems can reduce or eliminate use of municipal or well water during the rainy season, when outdoor irrigation is unnecessary. Most household rainwater systems use a pump and pressure tank to pressurize water. Many states do not have codes covering indoor rainwater use, and people seeking permits may be required to filter and disinfect the water, increasing system cost and complexity. However, EPA and other research has shown that rainwater harvested using a “first flush” system and protected from light is safe to use for bathing and other household use. Filtering only the small amount of water used for drinking with passive filters such as the ceramic filter shown at left, or with slow sand filters, greatly reduces system cost, and offers an affordable solution for people needing clean drinking water.
Information from Greywateraction.org shared via Creative Commons Attribution-ShareAlike 3.0 Unported (CC BY-SA 3.0)
TweetThe PT1 is designed to be very reliable and requires only infrequent calibration. Myron L Meters recommends calibrating each measurement mode you use once monthly. However, you should check the calibration whenever measurements are not as expected. The PT1 is programmed for 2 calibration options: Wet Calibration or Factory Calibration. Wet calibration is most accurate. [...]
The PT1 is designed to be very reliable and requires only infrequent calibration. Myron L Meters recommends calibrating each measurement mode you use once monthly. However, you should check the calibration whenever measurements are not as expected. The PT1 is programmed for 2 calibration options: Wet Calibration or Factory Calibration. Wet calibration is most accurate. But if a high quality standard KCl-1800 µS or 442-3000 ppm solution is not available, the PT1 can be returned to factory settings.
Use calibration solution specified for measurement mode: Use KCL- 1800 for Cond KCl; Use 442-3000 for tdS 442, SALt 442, tdS NaCl, and SALt NaCl. See Specifications table for 442 solution ppm NaCl equivalent value. Calibrating TDS simultaneously calibrates SALt for the same value and vice versa.
1. Pour calibration solution into a clean container.
2. Rinse the pen 3 times by submerging the cell in fresh calibration solution and swirling it around.
3. Remove pen from solution, then fill the container one more time.
4. Press and release the push button. The LCD will briefly display the firmware version then the current measurement mode. Ensure the PT1 is in the correct solution mode.
5. Immediately push and hold the push button. The display will scroll through “CAL”, “SOL SEL”, “FAC CAL”, “ºCºF TEMP”, and “ESC”. Release the button when “CAL” displays.
6. Grasp the pen by its case with your fingers positioned between the
display and the pen cap to avoid sample contamination.
7. While the LED flashes rapidly, dip the pen in calibration solution so that the cell is completely submerged. If you do not submerge the cell in solution before the flashing slows, allow the pen to power off and start over.
8. While the LED flashes slowly, swirl the pen around to remove bubbles, keeping the cell submerged. Keep pen at least 1 inch (2½ cm) away from sides/bottom of container.
9. When the LED light stays on solid, remove the pen from the solution. “CAL SAVED” will display indicating a successful calibration.
Note: If an incorrect solution is used or the measurement is NOT within calibration limits for any other reason, “Error” displays alternately with “CLEAn CEL/CHEC SOL”. Check to make sure you are using the correct calibration solution. If the solution is correct, clean the cell by submerging the cell in a 1:1 solution of Lime-A-Way® and water for 5 minutes. Rinse the cell and start over.
10. Small bubbles trapped in the cell can give a false calibration. Measure the calibration solution again to verify correct calibration. If the reading is not within ±1% of the calibration solution value, repeat calibration.
If you do not have the proper calibration solution or wish to restore the pen to its original factory settings for any other reason, use the FAC CAL function to calibrate the PT1.
1. Press and release the push button. The LCD will briefly display the firmware version then the current measurement mode.
2. Immediately push and hold the push button. The display will scroll
through “CAL”, “SOL SEL”, “FAC CAL”, “ºCºF TEMP”, and “ESC”. Release
the button when “FAC CAL” displays.
3. While the display scrolls through “PUSHnHLD” and “FAC CAL”, push and hold the push button until the display scrolls through “SAVEd” and “FAC CAL”, indicating the pen has been reset to its factory calibration.
4. Allow the pen to time out to turn power off.
Tweet Hard water is water that has high mineral content. Hard drinking water is generally not harmful to one’s health, but can pose serious problems in industrial settings, where water hardness is monitored to avoid costly breakdowns in boilers, cooling towers, and other equipment that handles water. In domestic settings, hard water is often indicated [...]
Hard drinking water is generally not harmful to one’s health, but can pose serious problems in industrial settings, where water hardness is monitored to avoid costly breakdowns in boilers, cooling towers, and other equipment that handles water. In domestic settings, hard water is often indicated by a lack of suds formation when soap is agitated in water. Wherever water hardness is a concern, water softening is commonly used to reduce hard water’s adverse effects.
Sources of hardness
Water’s hardness is determined by the concentration of multivalent cations in the water. Multivalent cations are cations (positively charged metal complexes) with a charge greater than 1+. Usually, the cations have the charge of 2+. Common cations found in hard water include Ca2+ and Mg2+. These ions enter a water supply by leaching from minerals within an aquifer. Common calcium-containing minerals are calcite and gypsum. A common magnesium mineral is dolomite (which also contains calcium). Rainwater and distilled water are soft, because they also contain few ions.
The following equilibrium reaction describes the dissolving/formation of calcium carbonate scales:
CaCO3 + CO2 + H2O ⇋ Ca2+ + 2HCO3−
Calcium carbonate scales formed in water-heating systems are called limescale.
Calcium and magnesium ions can sometimes be removed by water softeners.
Temporary hardness is a type of water hardness caused by the presence of dissolved bicarbonate minerals (calcium bicarbonate and magnesium bicarbonate). When dissolved, these minerals yield calcium and magnesium cations (Ca2+, Mg2+) and carbonate and bicarbonate anions (CO32-, HCO3-). The presence of the metal cations makes the water hard. However, unlike the permanent hardness caused by sulfate and chloride compounds, this “temporary” hardness can be reduced either by boiling the water, or by the addition of lime (calcium hydroxide) through the softening process of lime softening. Boiling promotes the formation of carbonate from the bicarbonate and precipitates calcium carbonate out of solution, leaving water that is softer upon cooling.
Permanent hardness is hardness (mineral content) that cannot be removed by boiling. When this is the case, it is usually caused by the presence of calcium and magnesium sulfates and/or chlorides in the water, which become more soluble as the temperature increases. Despite the name, the hardness of the water can be easily removed using a water softener, or ion exchange column.
Effects of hard water
With hard water, soap solutions form a white precipitate (soap scum) instead of producing lather. This effect arises because the 2+ ions destroy the surfactant properties of the soap by forming a solid precipitate (the soap scum). A major component of such scum is calcium stearate, which arises from sodium stearate, the main component of soap:
2 C17H35COO- + Ca2+ → (C17H35COO)2Ca
Hardness can thus be defined as the soap-consuming capacity of a water sample, or the capacity of precipitation of soap as a characteristic property of water that prevents the lathering of soap. Synthetic detergents do not form such scums.
Hard water also forms deposits that clog plumbing. These deposits, called “scale”, are composed mainly of calcium carbonate (CaCO3), magnesium hydroxide (Mg(OH)2), and calcium sulfate (CaSO4). Calcium and magnesium carbonates tend to be deposited as off-white solids on the surfaces of pipes and the surfaces of heat exchangers. This precipitation (formation of an insoluble solid) is principally caused by thermal decomposition of bi-carbonate ions but also happens to some extent even in the absence of such ions. The resulting build-up of scale restricts the flow of water in pipes. In boilers, the deposits impair the flow of heat into water, reducing the heating efficiency and allowing the metal boiler components to overheat. In a pressurized system, this overheating can lead to failure of the boiler. The damage caused by calcium carbonate deposits varies depending on the crystalline form, for example, calcite or aragonite.
The presence of ions in an electrolyte, in this case, hard water, can also lead to galvanic corrosion, in which one metal will preferentially corrode when in contact with another type of metal, when both are in contact with an electrolyte. The softening of hard water by ion exchange does not increase its corrosivity per se. Similarly, where lead plumbing is in use, softened water does not substantially increase plumbo-solvency.
In swimming pools, hard water is manifested by a turbid, or cloudy (milky), appearance to the water. Calcium and magnesium hydroxides are both soluble in water. The solubility of the hydroxides of the alkaline-earth metals to which calcium and magnesium belong (group 2 of the periodic table) increases moving down the column. Aqueous solutions of these metal hydroxides absorb carbon dioxide from the air, forming the insoluble carbonates, giving rise to the turbidity. This often results from the alkalinity (the hydroxide concentration) being excesively high (pH > 7.6). Hence, a common solution to the problem is to, while maintaining the chlorine concentration at the proper level, raise the acidity (lower the pH) by the addition of hydrochloric acid, the optimum value being in the range of 7.2 to 7.6.
For the reasons discussed above, it is often desirable to soften hard water. Most detergents contain ingredients that counteract the effects of hard water on the surfactants. For this reason, water softening is often unnecessary. Where softening is practiced, it is often recommended to soften only the water sent to domestic hot water systems so as to prevent or delay inefficiencies and damage due to scale formation in water heaters. A common method for water softening involves the use of ion exchange resins, which replace ions like Ca2+ by twice the number of monocations such as sodium or potassium ions.
The World Health Organization says that “there does not appear to be any convincing evidence that water hardness causes adverse health effects in humans”.
Some studies have shown a weak inverse relationship between water hardness and cardiovascular disease in men, up to a level of 170 mg calcium carbonate per litre of water. The World Health Organization has reviewed the evidence and concluded the data were inadequate to allow for a recommendation for a level of hardness.
Recommendations have been made for the maximum and minimum levels of calcium (40–80 ppm) and magnesium (20–30 ppm) in drinking water, and a total hardness expressed as the sum of the calcium and magnesium concentrations of 2–4 mmol/L.
Other studies have shown weak correlations between cardiovascular health and water hardness.
Some studies correlate domestic hard water usage with increased eczema in children.
The Softened-Water Eczema Trial (SWET), a multicenter randomized controlled trial of ion-exchange softeners for treating childhood eczema, was undertaken in 2008. However, no meaningful difference in symptom relief was found between children with access to a home water softener and those without.
Hardness can be quantified by instrumental analysis. The total water hardness is the sum of the molar concentrations of Ca2+ and Mg2+, in mol/L or mmol/L units. Although water hardness usually measures only the total concentrations of calcium and magnesium (the two most prevalent divalent metal ions), iron, aluminium, and manganese can also be present at elevated levels in some locations. The presence of iron characteristically confers a brownish (rust-like) colour to the calcification, instead of white (the color of most of the other compounds).
Water hardness is often not expressed as a molar concentration, but rather in various units, such as degrees of general hardness (dGH), German degrees (°dH), parts per million (ppm, mg/L, or American degrees), grains per gallon (gpg), English degrees (°e, e, or °Clark), or French degrees (°f). The table below shows conversion factors between the various units.
The various alternative units represent an equivalent mass of calcium oxide (CaO) or calcium carbonate (CaCO3) that, when dissolved in a unit volume of pure water, would result in the same total molar concentration of Mg2+ and Ca2+. The different conversion factors arise from the fact that equivalent masses of calcium oxide and calcium carbonates differ, and that different mass and volume units are used. The units are as follows:
Parts per million (ppm) is usually defined as 1 mg/L CaCO3 (the definition used below). It is equivalent to mg/L without chemical compound specified, and to American degree.
Grains per Gallon (gpg) is defined as 1 grain (64.8 mg) of calcium carbonate per U.S. gallon (3.79 litres), or 17.118 ppm.
a mmol/L is equivalent to 100.09 mg/L CaCO3 or 40.08 mg/L Ca2+.
A degree of General Hardness (dGH or ‘German degree (°dH, deutsche Härte)’ is defined as 10 mg/L CaO or 17.848 ppm.
A Clark degree (°Clark) or English degrees (°e or e) is defined as one grain (64.8 mg) of CaCO3 per Imperial gallon (4.55 litres) of water, equivalent to 14.254 ppm.
A French degree (°F or f) is defined as 10 mg/L CaCO3, equivalent to 10 ppm. The lowercase f is often used to prevent confusion with degrees Fahrenheit.
Because it is the precise mixture of minerals dissolved in the water, together with the water’s pH and temperature, that determines the behavior of the hardness, a single-number scale does not adequately describe hardness.
Langelier Saturation Index (LSI)
The Langelier Saturation Index (sometimes Langelier Stability Index) is a calculated number used to predict the calcium carbonate stability of water. It indicates whether the water will precipitate, dissolve, or be in equilibrium with calcium carbonate. In 1936, Wilfred Langelier developed a method for predicting the pH at which water is saturated in calcium carbonate (called pHs). The LSI is expressed as the difference between the actual system pH and the saturation pH:
LSI = pH (measured) — pHs
For LSI > 0, water is super saturated and tends to precipitate a scale layer of CaCO3.
For LSI = 0, water is saturated (in equilibrium) with CaCO3. A scale layer of CaCO3 is neither precipitated nor dissolved.
For LSI < 0, water is under saturated and tends to dissolve solid CaCO3.
If the actual pH of the water is below the calculated saturation pH, the LSI is negative and the water has a very limited scaling potential. If the actual pH exceeds pHs, the LSI is positive, and being supersaturated with CaCO3, the water has a tendency to form scale. At increasing positive index values, the scaling potential increases.
In practice, water with an LSI between -0.5 and +0.5 will not display enhanced mineral dissolving or scale forming properties. Water with an LSI below -0.5 tends to exhibit noticeably increased dissolving abilities while water with an LSI above +0.5 tends to exhibit noticeably increased scale forming properties.
It is also worth noting that the LSI is temperature sensitive. The LSI becomes more positive as the water temperature increases. This has particular implications in situations where well water is used. The temperature of the water when it first exits the well is often significantly lower than the temperature inside the building served by the well or at the laboratory where the LSI measurement is made. This increase in temperature can cause scaling, especially in cases such as hot water heaters. Conversely, systems that reduce water temperature will have less scaling.
Hard water in the United States
More than 85% of American homes have hard water. The softest waters occur in parts of the New England, South Atlantic-Gulf, Pacific Northwest, and Hawaii regions. Moderately hard waters are common in many of the rivers of the Tennessee, Great Lakes, and Alaska regions. Hard and very hard waters are found in some of the streams in most of the regions throughout the country. The hardest waters (greater than 1,000 ppm) are in streams in Texas, New Mexico, Kansas, Arizona, and southern California.
Measuring Hardness and LSI
The Myron L Ultrameter III 9PTK measures water hardness and LSI, as well as 7 other water quality parameters.
Measures 9 Parameters: Conductivity, Resistivity, TDS, Alkalinity, Hardness, LSI, pH, ORP/Free Chlorine, Temperature
LSI Calculator for hypothetical water balance calculations
Wireless data transfer capability with bluDock option
Auto-ranging delivers increased resolution across diverse applications
Adjustable Temperature Compensation and Cond/TDS conversion ratios for user-defined solutions
Nonvolatile memory of up to 100 readings for stored data protection
Date & time stamp makes record-keeping easy
pH calibration prompts alert you when maintenance is required
Auto-off minimizes energy consumption
Low battery indicator
(Includes instrument with case and solutions)
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