Myron L Meters is proud to be the premier internet retailer of Myron L Ultrameters, Ultrapens, and other fine products. Myron L meters have a well-earned reputation for being accurate, reliable, and easy-to-use. We’d like to thank the following 2013 customers who ordered for the first time through our MyronLMeters.com website, as well as the hundreds not listed here. Thank you for your business.
GLAXO SMITH KLINE
UC IRVINE MEDICAL CENTER
RED BUD REGIONAL HOSPITAL
HALIFAX REGIONAL HOSPITAL
ELIK DIALYSIS CENTER
OAK RIDGE NATIONAL LABORATORY
BROOKHAVEN NATIONAL LABORATORY
PACIFIC NORTHWEST NATIONAL LABORATORY
UNIVERSITY OF ARKANSAS
IDAHO STATE UNIVERSITY
UNIVERSITY OF DELAWARE
UNIVERSITY OF COLORADO
UNIVERSITY OF WYOMING
UNIVERSITY OF REDLANDS
We hope that Myron L Meters has helped your organization continue its fine work. Thanks from the Myron L Meters team and have a great 2014!
WHY ARE TESTS SO IMPORTANT?
Modern growing practices include scientific evaluations of soil, water, fertilizers, diseases, etc. While some tests are best performed by a laboratory, others can be easily conducted on location, saving time and money. Three tests in particular, EC, pH, and ALKALINITY, can reveal valuable information about water quality, soil salinity, and fertilizer concentration. Our portable AGRI-METERS™ provide you with a simple, fast, and accurate means of testing these parameters.
WHAT IS ELECTRICAL CONDUCTIVITY (EC)?
EC is the measurement of a solution’s ability to conduct an electrical current. For horticultural applications, the unit of measure is often expressed as millimhos. Absolutely pure water is actually a poor electrical conductor. It is the substances (or electrolytes) dissolved in the water which determine how conductive the solution will be.
Therefore, EC can be an excellent indicator of:
1. Water quality
2. Soil salinity
3. Fertilizer concentration
EC AND WATER QUALITY
The quality of irrigation water is one of the most critical factors influencing your growing operation. It is important to have a complete water analysis performed on a regular basis. Environmental conditions such as drought, changing seasons, heavy rainfall, etc., can cause the concentrations of dissolved salts in your water to vary significantly. These dissolved salts (i.e. calcium, sodium, etc.) can directly affect your plants’ health and, over time, render even the best soil useless.
You can monitor your overall water quality by testing its electrical conductivity with an AGRI-METER™. The higher the EC, the more salts are dissolved in your water. By comparing your EC with previous readings, you can tell if any dramatic changes have occurred. Nutrient deficiencies are possible when water is too pure (low EC) or if the relative concentrations of some nutrients are unbalanced (i.e. calcium/magnesium). On the other hand, nutrient toxicities or osmotic interferences can also be traced to water quality. Water EC of even one millimho or below can cause problems. High EC readings of more than two millimhos can suggest serious problems, and special cultural procedures may be required.
EC AND SOIL SALINITY
“Water, water, everywhere, but not a drop to drink” is an old saying that applies to your plants when the soil salinity becomes too high. Salts from irrigation water and fertilizers tend to accumulate in your soil or growing media. High soil salinity disrupts the normal osmotic balance in plant roots. In severe cases a plant will become dehydrated even when the soil is wet. Symptoms of high soil salinity include: leaf chlorosis and necrosis, leaf drop, root death, nutrient deficiency symptoms, and wilting. All too often these symptoms are not recognized as being caused by soluble salts in the growing media. Sampling your soil and testing the EC of an extract can reveal important information about a soil’s suitability and your crop’s health.
Samples should be representative of different depths and locations. An easy-to-perform extract method is available with a Soil Test Kit. A 2:1 or 5:1 water-to-soil ratio is made using the small vials provided. Soil test labs often use a method that calls for testing the EC of an extract from a thicker slurry. Therefore, you may see higher soil EC readings from a lab. It is important to standardize your sampling, extract, and testing methods. This will keep the difference between lab and field testing to a predictable factor.
EC AND FERTILIZER CONCENTRATION
You know how important fertilizer is to your plants, but do you know how accurate your fertilizer dosage is? Relying on traditional proportional methods is risky to plants and can waste expensive fertilizer. Improperly mixed fertilizer or a malfunctioning injector can lead to less than optimal results or even a disastrous loss of crops. Many fertilizer companies now recommend using a simple EC test to verify correct fertilizer concentrations. Many growers check their fertilizer injectors on a weekly basis, or they use a continuous EC monitor.
Fertilizer companies and suppliers often can provide a chart relating EC to parts per million concentrations of their various fertilizers. If one is not available for the fertilizer you use, carefully make some stock solutions at commonly used strengths and test their EC. This will give you a data base for future reference.
To test the EC of fertilizer solutions:
- Test and record the EC of the water to be mixed with the fertilizer.
- Test the conductivity of the fertilizer and water mixture.
- Subtract the water conductivity determined in #1 above.
- The resulting figure is an accurate indication of how much fertilizer is present (a higher conductivity means more fertilizer).
Important note: Interpretation of results differs from formula to formula and even among manufacturers of the same formula. Obtain the proper EC charts from the fertilizer company.
Myron L Meters sells both portable and inline instrumentation to make your fertilizer monitoring easy. Myron L AGRI-METERS™, AG-5 and AG6/PH, TH1, waterproof TECHPRO II™ models TP1, TPH1 and TH1, and waterproof ULTRAMETER II™ models 4P and 6PFCEare handheld instruments which make fertilizer testing as simple as filling a cup and pushing a button.
The Myron L 750 Series II™ EC Monitor/controllers can be used to continuously monitor your fertilizer concentration. Their “alarm” relay circuit acts as a safeguard in a fertilizer injection system or even as the main controller for your injector. A 0-10 VDC output for chart recorders or PLC (SCADA) input is standard on all monitor/controller models.
IMPORTANCE OF pH
pH, the measure of acidity or basicity, should be included in any soil or water test. It is well documented that growing media pH is critical to successful plant growth. This is especially true for new soilless mixes and hydroponics. pH affects the roots’ ability to absorb many plant nutrients. Examples include iron and manganese, which are insoluble at high pHs and toxic at low pHs. pH also directly affects the health of necessary micro-organisms in soil.
The effectiveness of pesticides and growth regulators can be severely limited by spray water pH that is either too low or too high.
It is important to note that testing the pH of irrigation water reveals only part of the story. Testing water alkalinity (bicarbonates and carbonates) is much more important than generally recognized. Alkalinity dictates how much influence the water’s pH will have on your soil and nutrient availability. In addition, alkalinity has a very great effect on the ease or difficulty of reducing the pH of water.
Most Myron L analog meters have a battery indicator glow light visible through the small hole on the lower right-hand corner of the meter face plate. If this light fails to glow when the black button is pressed, replace both batteries.
To replace the batteries detach the battery connectors. Pull on the plastic straps to remove the batteries. Replace with fresh zinc carbon or alkaline 9 volt batteries. Reinsert the plastic straps to secure batteries.
Self-conditioning of the built-in electrodes occurs each time the button is pressed with a sample in the cell cup. This ensures consistent results each time. With some samples a small downward swing of the pointer is a result of this conditioning action. This action is powerful and removes normal films of oil and dirt. However, if very dirty samples – particularly scaling types – are allowed to dry in the cell cup, a film will build up. This film reduces accuracy. When there are visible films of oil, dirt, or scale in the cell cup or on the electrodes, scrub them lightly with a small brush and household cleanser. Rinse out the cleanser, and the meter is ready for accurate measurements. pH SENSOR The unique pH electrode in your pDS meter is a nonrefillable combination type which features a porous Teflon* liquid junction (covered by U.S. Patent No. 4128468). It should never be allowed to dry out (see pH MEASUREMENT). If it does, the sensor can sometimes be renewed by soaking in a saturated potassium chloride (KCI) solution for several days. “Drifting” can be caused by a film on the sensor bulb. Use a liquid cleaner such as Windex™ or fantastik™ to clean it. The sensor buIb is very thin and delicate. Excessive pressure during cleaning may break it. Leaving high pH (alkaline) solutions in contact with the pH sensor for long periods of time can damage it. Rinsing such liquids from the pH compartment and moistening it with 4 buffer or tap water will extend its useful life. Samples containing chlorine, sulphur, or ammonia can “poison” any pH electrode. If it is necessary to measure the pH of any such sample, thoroughly rinse the pH sensor with clean water immediately after taking the measurement. Any sample element which will reduce (add an electron to) silver, such as cyanide, will attack the reference electrode. Replacement sensors are available from MyronLMeters.com. *™ DuPont Company
WATER INSIDE THE METER
Your Myron L meter is a rugged instrument and will withstand water exposure around its cell, meter movement, and switches. However, care should be taken to keep water from leaking in around the bottom cover. It is not sealed (to prevent condensation from forming). If the water is relatively clean (i.e., tap water or better), and there are only a few drops inside the meter, dry it as described below. Large amounts of water, or corrosive or very dirty solutions will almost certainly damage the meter movement or electronics. Such meters should be returned to the Myron L Company for repair.
To dry your meter:
1. Shake excess water out of the inside of the meter.
2. Dab the exposed surface dry with an absorbent cloth or tissue. Avoid pushing any water into the Calibration Controls or the switches.
3. Air dry the meter in a warm area with the bottom cover off. Allow several hours for thorough drying. If the water entered through a leak in the case or cell, or if the instrument shows erratic readings or other unusual behavior, return it for servicing.
For more on repairs and maintenance, or to download an operations manual, please visit us HERE.
When disaster strikes, people are scared and disorganized. They need resources — safe water and proper sanitation — that aren’t easy to come by in the aftermath. Without the help of humanitarian organizations to provide assistance, large populations of survivors are subject to epidemics of cholera, diarrhea, meningitis, and other diseases as they struggle to meet these basic needs.
Dr. Roddy Tempest, a leading designer and manufacturer of water purification systems has headed the efforts of public and private aid organizations, such as the United Nations and AmeriCares, in responding to people in crisis all over the world for over 15 years.
Dr. Tempest contributed his expertise and experience in such situ- ations as the aftermath of Hurricane Andrew in 1992, the Kosovar refugee crisis in the Balkans, the devastating earthquakes in Tur- key and the flood and mudslides that ravaged the coastal states of Venezuela in 1999. He has assisted in disaster relief efforts in Japan, Africa, Central America, and Taiwan, as well.
So when AmeriCares launched its water purification program for the inhabitants of Sri Lanka following the devastation of the tsunami on December 26, 2004, it turned to Dr. Tempest.
For this heroic effort, Dr. Tempest used two Ultrameter II 6P portable, handheld water testing instruments. Dr Tempest said the instruments gave him “a good, quick first-brush assessment of the possible water sources.”
The Ultrameter II reported and recorded instant precise measurements of Conductivity, Resistivity, TDS, ORP (REDOX), pH, and Temperature. But creating a livable situation for hundreds of thousands of displaced survivors wasn’t as easy as testing the water.
Water Doctor to the Rescue
From his offices in the United States, Dr. Tempest responded to the call for help by first reviewing satellite maps that showed the location of potential water sources in relation to groups of survivors, or Internally Displaced Persons (IDPs). He assessed the total situation of the potential water sources, trying at a glance to deter- mine possible contamination by flooding or infiltration of seawater. Upon his arrival in Sri Lanka, Dr. Tempest worked 24 hours a day to determine a suitable survival supply of water for the IDPs. As indicated in the World Health Organization’s Environmental Health in Emergencies and Disasters, the required water per person per day is 15 liters / 3.963 gallons.
Faced with this daunting task, Dr. Tempest surveyed the land via helicopter and fixed wing aircraft to record the extent of the damage, the location of IDPs, and the viability of potential water sources. Some of the photographs reveal the mammoth challenge he had ahead of him. Debris lay everywhere, indicating the likelihood of surface water and well contamination. Filtration was a must.
Dr. Tempest then combined satellite imagery, the photographs and sketches of water sources from his survey and a list of supplies to determine which water sources would be targeted for testing.
Following World Health Organization guidelines, Dr. Tempest considered as many potential water sources as possible, not just the most obvious ones. These included surface and groundwater near the groups of IDPs and tankered or bottled water brought in from a distance – though this would not be suitable for the long- term supply. The preferred source would have been groundwater, especially for the long-term.
Ultrameter II in Action
Dr. Tempest used the Ultrameter II 6P to screen these sources for their potential disinfection and filtering.
First, Dr. Tempest considered whether or not potential water sources could be protected from pollution and secured. Any potential source water had to be filterable and sanitizable. If the water was brackish, it would require a certain treatment method. If it was high in turbidity, then it would require another. If the pH needed adjusting, then yet another. If the source water was not easily treatable, then the source had to be discarded as an option and a better alternative found.
The Ultrameter II provided Dr. Tempest with fast, reliable, accurate initial information on whether or not to pursue further testing and treatment of a potential source. Dr. Tempest used a multiparameter approach and tested for Total Dissolved Solids (TDS), pH, ORP (REDOX), and temperature (recorded with every reading taken.) He also tested for turbidity and bacteria using other instrumentation.
Initially, Dr. Tempest used a measurement of the mineral salt concentration using TDS calibrated to a sodium chloride solution and TDS calibrated to a natural water standard.
Right away Dr. Tempest knew whether or not the water was too saline or saturated to be filtered economically. If the TDS is too high, filtration systems that work by reverse osmosis can be overwhelmingly expensive to operate in a disaster area, especially considering electrical costs alone. At the very least, the systems become less efficient as the TDS increases and a burden in operation and maintenance costs. This is critical for the short-term disaster response, where Dr. Tempest has to get as much safe water to IDPs in as short amount of time as possible.
High TDS can also indicate an unacceptable level of specifically known inorganic contaminants caused by industrial pollution.
And though it is not a health consideration, high TDS water often has an unpleasant taste that deters people from using it. People may try to return to old wells or other sources of previously safe drinking water that have been contaminated in the disaster. The old source may be more trusted than one that tastes “polluted.” So even though TDS is a secondary water quality standard, it can profoundly impact whether or not the new source is acceptable.
Dr. Tempest also took instant electronic pH readings using the Ultrameter II. The pH directly affects the potential to disinfect the water. pH levels beyond 8 will require substantial increases in the amount of disinfectant required or the length of time the water must be disinfected before safe consumption. And at a pH beyond 9, a residual disinfectant is extremely difficult to maintain.
pH is also critical in the long-term disaster recovery planning. pH that is too low or too high affects water balance, as well, and can contribute to either corrosion or scaling of filtration and disinfection system components and plumbing. An electronic meter is the best choice in this application as compared to colored strips or solutions or other colorimetric methods that do not produce the accuracy required to consistently and correctly balance water and maintain proper disinfection levels. The more precisely the pH is maintained, the less costly safe water production is.
Dr. Tempest also took quick ORP (REDOX) measurements using the Ultrameter II. ORP (REDOX) is the oxidation reduction potential of the water and indicates the state of the water for gaining or losing electrons. Unlike pH, which measures the water’s ability to donate or receive hydrogen ions, ORP (REDOX) values reflect the presence of all oxidizing and reducing agents — not just acids and bases. Initially, the ORP (REDOX) value gave Dr. Tempest a rough idea of the organic load in the water. A reading of 650 mV or greater indicated good water quality that could effectively be sanitized by a minimal amount of free chlorine. A value like 250 mV indicated that the organic contaminants would significantly increase chlorine demand and thereby significantly increase operation and management costs.
ORP (REDOX) is not only a good first indicator about the viability of a water source, but it also is the best way of measuring the disinfectant present in the water after treatment has begun.
Putting It All Together
Using all of the results from these parameters and based on his knowledge of the location of IDPs in relation to potential water sources, Dr. Tempest decided which source would satisfy the needs of each specific location of groups of IDPs. Where possible, water treatment technology would be designed around the quality of the source waters tested where IDPs had gathered, since it was not practical to re-locate large groups of people to distant water sources. Unfortunately, in the case of the Tsunami in Sri Lanka, oftentimes the water closest to IDPs could not be filtered and relocation was necessary.
Dr. Tempest found after his first quick assessment of potential water sources that it was not practical to supply the IDPs in parts of the Batticoloa and Ampara Districts along the eastern coast, because the source water was too saline from seawater intrusion. With limited electricity, this
made the use of reverse osmosis or desalination equipment impractical.
He ended up settling on sites that were more inland, using source waters from man-made reservoirs. IDPs were then settled inland near the cleaner water source.
However, the water in the man-made reservoirs was heavily contaminated with toxic blue-green algae.
Dr. Tempest chose microfiltration and ultrafiltration water treatment systems in the eastern district locations, taking algae-infested water over the salt-saturated, so that treatment and operation costs would be significantly less. Dr. Tempest designed, built and commissioned 4 large transportable water treatment systems, each capable of producing over 500,000 liters/day.
Plans then continued to follow through with long-term water treatment using the Tempest Environmental Systems equipment for the Sri Lankan Ministry of Urban Development and Water Supply and their National Water Supply & Drain- age Board (NWSDB). The NWSDB has 14 Ultrameter II 6Ps in current use in Sri Lanka, which are providing continuing confidence checks to ensure system equipment remains up and running properly.
The Ultrameter II 6P is an excellent multiparameter water quality meter used by thousands of water treatment professionals. The instrument can test for pH, total dissolved solids, conductivity, resistivity, oxidation reduction potential, temperature, and has the capability of testing for free chlorine. This meter handles the job of SIX single parameter testers using one single water sample. Save 10% on the Ultrameter II 6P at MyronLMeters.com.
The economic development of any region, state or country, depends not only on its natural resources and productive activities, but also on the infrastructure that account for the exploitation, processing and marketing of goods. Irrigation systems, roads, bridges, airports, maritime, land and air transport, school buildings, offices and housing, industrial installations are affected by corrosion and therefore susceptible to deterioration and degradation processes.
Corrosion is a worldwide crucial problem that strongly affects natural and industrial environments. Today, it is generally accepted that corrosion and pollution are interrelated harmful processes since many pollutants accelerate corrosion and corrosion products such as rust, also pollute water bodies. Both are pernicious processes that impair the quality of the environment, the efficiency of the industry and the durability of the infrastructure assets. Therefore, it is essential to develop and apply corrosion engineering control methods and techniques.
Other critical problems, that impact on infrastructure and industry are climate change, global warming and greenhouse emissions, all interrelated phenomena.
This post presents important aspects of corrosion in industrial infrastructure, its causes, impacts, control, protection and prevention methods.
1. Materials in industry
Metallic materials play a key role in the development of a country and its sustained growth in the context of the global economy. Table 1 shows a classification and the properties of different types of materials used in the industry. During the course of the metal production it undergoes various types of processes: mining of minerals, manufacturing and application and generation of gases, liquids or solids that are released into the environment. In the industrial development, production and use of materials in general, economic cycles are due to take effect that influence the environment (Raichev et al., 2010). The selection of a predominant group of materials depends on the particular industries; they determine to a greater or lesser extent the pattern of consumption of a given product, inducing the market to adapt itself to this new reality. The materials industry follows two general strategies: re‐ search the materials and the available technology recommended for their. Recycled materi‐ als typically require less capital and energy consumption, but need more manpower, for primary processing. Also, the costs of pollution control are lower than those required for primary processing of minerals. Recycling becomes more intense, as economies tend to be more sophisticated, since viable quantities of recycled material must be available for reuse (Garcia, R., et al, 2012, Lopez, G. 2011, Schorr, M., 2010).
In the production of a material waste is generated: for example, parts of material that was left aside, through the production steps. There are called effluent, which consist of waste that comes from the processes linked to the technology involved in each step of production, although not necessarily with the main material. Industrial processes for the recovery of ore from the mine to produce a metal, are related to technological development and therefore varies from one country to another, including regulatory laws, financial aspects etc.. Therefore, the environmental impacts vary widely. A low grade or poor quality of the ore, with low metal content, increase the cost of recovery, requiring large amounts of mineral raw material and en‐ ergy invested for the recovery of small amounts of metal. Also important is the feasibility of the mineral that can be worked out e.g., the cost of physical removal of rock, accessibility to the mines, thickness and regularity of the ore zone, and its hardness. Figure 1, shows the material cycle, which involves processes from raw material, extraction from natural sources, processing and conversion into industrial materials, their processing and application, the deterioration rate effects, its mechanical properties, environmental behavior, corrosion, disposal and possible recovery of some of these through the use of recycling methods.
There are many examples of recovery of metals, which could help to describe step by step the various interactions with the environment itself. A mineral submitted to a production process will impact the environment, during four steps: extraction, processing, fabrication and manufacturing, of goods as seen in the cycle of materials. (Figure 1)
In the mineral extraction step, the effluents of N, C, S, NOx, SOx and COx, from machinery and equipment, operation process water, particulate matter and ground movement in landfills.
The processing stage, chemical operations or extractive metallurgy for converting the concentrate into metal apply selected technologies. The effluents are gases such as SO2, NO2 and CO2, water contaminated with heavy metals, and hazard sediments.
In the manufacturing step the material undergoes operations that transform it into rods, bars, sheets; losses are scrap metal, such as cuts, burrs, mill scale, which recycled with no net loss of metal. In the manufacturing stage the metal is formed by stamping, machining and forging.
Focus on good operations management involves control of air emissions, water management and treatment, solid waste disposal and good land use, will greatly help to maintain a good balance with the environment. It is also necessary to analyze the production area to identify what improvements or measures should be implemented. The role of hydrometallurgist is particularly important and so he is responsible for the design of environmentally friendly processes in each of his steps, to promote sustainable production.
2.1 Processes of materials biodeterioration in industrial systems
In addition to the common processes of deterioration of materials by chemical reactions and mechanical fracture, there are others who are concerned with the participation of various types of microorganisms that adhere in colonies or develop on their surfaces.
Biocorrosion and biodeterioration of metallic materials and nonmetallic materials are two important processes that cause serious problems to the infrastructure of various industrial systems. Generally, microorganisms do not deteriorate or corrode metals directly, but modify the conditions of interface material / environment and surroundings, favoring the degradation of these materials in such a way that induce or influence the development process.
Biofouling is a common term that indicates the presence of microbiological growth on the surfaces of structures built of different materials favoring the formation of biofilms with the colonies of various types of microorganisms.
In the case of metal, biocorrosion occurs due to corrosion electrochemical processes and bio‐ logical agents due to the action of microorganisms and / or bacteria present in the system. The knowledge of these biological processes and their effects is necessary in order to establish preventive measures and control measures in industrial systems.
An industrial plant containing several biocorrosion environments is a potential risk:
In a heat exchangers system, usually dust accumulates biological waste; biocorrosion could occur, leading to corrosion film formation on walls surface. Therefore, it will be energy loss by increasing the resistance to fluid flow and heat transfer. Loss by evaporation of water favors the increase of the concentration of nutrients, the residence time, the water temperature and the surface / volume ratio, which leads to higher rate of microbial growth (Stoytcheva et al., 2010, Carrillo M. et al., 2010).
Until the early 80′s of the twentieth century, we used mixtures of anodic and cathodic inhibitors, such as chromium, zinc and phosphates, to lessen the effects of corrosion in water systems. In some cases we added a polymer, as is still done to date, to avoid or eliminate the problems of fouling on the metal walls. On the other hand, to prevent microbiological growth, we added biocides such as chlorine and quaternary ammonium compounds under acidic conditions.
In the early 90′s, the strategies for industrial water treatment changed because of pressure from laws for the preservation of the environment. Chromates and acid pH values are replaced by the use of organic phosphonates as corrosion inhibitors, while for the control of fouling polycarboxylate type polymers are used. However, this change brought about an increase in the amount of suspended solids, a greater number and variety of microorganisms and therefore a greater amount of inorganic deposits on the heat exchangers walls.
2.2. Biodeterioration of metallic and nonmetallic materials
The metal nature has an effect on the distribution and development of microbial films on its surface. These films influence on the wear and corrosion of the metal substrate. The lack of homogeneity in the biofilm is a precursor of differential aeration processes with formation of differential cell concentration, for example, stainless steels (SS) and nickel-copper (Ni-Cu) alloys in seawater. The oxides passive films or hydrated hydroxides (corrosion products) are a good place for the establishment and growth of bacteria, especially when these products are at a physiological pH values (pH ≈ 7.4)
- Carbon Steel (CS)
CS are very active metals in aggressive media, such as seawater. In this case, the action of microorganisms involves the dissolution of films of corrosion products, by processes of oxidation and reduction. This creates new metal active areas, exposed to the aggressive medium and suffers corrosion processes. In the case of sulfate-reducing bacteria (SRB), the species generated by their metabolism (sulfides) are corrosive to the metal. Figure 2 shows the final state pitting outside a CS pipe, which was affected by microbial growth inside, prompting a process of microbial corrosion with not uniform localized attack.
- Stainless steel
The presence of chromium and molybdenum as alloying elements, enable passive behavior of stainless steels in different environments. However, the passive surface of these SS provides an ideal location for microbial adhesion and therefore are susceptible to corrosion pit‐ ting, crevice corrosion under stress or in solutions containing chlorides, as sea water.
In marine environments, the generation of peroxides during bacterial metabolism causes an ennoblement of the pitting potential of SS, thus promoting corrosion. Obviously, not all SS have the same behavior, but in general they tend to deteriorated in the presence of colonies of microorganisms.
- Copper and nickel alloys
Alloys of Cu with Zn, Sn and Al, brasses, bronzes, aluminum bronzes; also the nickel alloys: Monel, Hastelloy, nickel superalloys: Ni-Mo, Ni-Cr-Mo, Ni-Cr-Fe- Mo; the traditional nickel alloys: Ni-Cr-Fe, Ni-Fe-Cr, Fe-Ni-Cr-Mo), and the Cu-ni alloys CuNi\70/30, CuNi\90/10, have shown great corrosion resistance in different environments, so they have found a wide use in different industries and environments. However, despite these skills, there are reports that these alloys are colonized by bacteria after several months of exposure in seawater (Acuña, N. et al., 2004).
- Aluminum and its alloys
Al is an active metal which is passivated rapidly in some neutral and acid media, thus offer‐ ing a good resistance to corrosion. Al alloys with copper, magnesium and zinc, are widely used in the aviation industry. However, there have been cases of biocorrosion on fuel tanks of jet aircraft made of Al alloys by microbial contaminants in turbo combustibles. The presence of water (moisture), even in minimal amounts, allows growth of microorganisms (typically fungi), when these are able to utilize hydrocarbons as a carbon source.
Ti is considered as the most resistant metal to biocorrosion, according to the results of tests carried in different conditions, due to its passive behavior that is reinforced in the presence of oxidizing agents. This is the reason why Ti is the material of choice, for example, for the manufacture of tubes in cooling systems that use seawater.
- Nonmetallic materials
Non-metallic materials such as fiberglass reinforced polyester (FGRP), concrete and wood, are also affected by biodeterioration processes in the presence of microorganisms
In the case of FGRP, bacteria and algae are able to use the polyester matrix as a carbon source, consuming and considerably reducing the mechanical strength of composite material, ultimately causing its failure. This is easily observable in screens of this material in cool‐ ing towers or tanks containing fresh water or salt water. Wood suffers biodeterioration by the presence of fungi in moist environments that promote the delignification of this material (Valdez B., et al., 1996, 1999, 2008).
2.2. Facing the problems of biodeteriorationThe inevitable presence of microorganisms in the feed water causes a sequence of biofouling, biocorrosion and biodeterioration of the materials component of the structures. This sequence depends on the degree of microbial contamination and the system operating characteristics.
The most common methods of controlling these problems involve the application of continuous or metered biocides such as chlorine. Currently, we use substances more compatible with the environment, since the use of chlorine is limited to certain concentrations. Such is the case of ozone, which is also ascribed with passivating effects on certain metals and alloys commonly applied in industry, and also in antifouling action.
In order to tackle a biodeterioration problem it is required a prior analysis of the problem, to know when conditions are suitable for the development of this process. In industrial systems we need to know some parameters: temperature, pH, nutrients; carbon, phosphorus, nitrogen, sulfate ion levels and flow rates. The places where we find biodeterioration are: biofouling deposits, under any deposit, zones of localized metal corrosion. to check their presence it is necessary to utilize sampling techniques, isolation and identification of micro‐ organisms. It is interesting to note that there are commercial devices for in situ measurements that are practical and useful for the plant engineer.
1. Corrosion in the electronics industry
Corrosion of device components, manufactured by the electronics industry, is a problem that has occurred during a long time. Often, especially corrosion of one or more of the metallic ele‐ ments of an electronic component is the primary cause of failure in various electronic equip‐ ments. The high density of components required to reduce the size of electronic equipment, also for a better signal processing, leads to the generation of enclosed corrosion between thin metal sections. Furthermore, when electronic devices are in more severe environments such as tropical, subtropical, contaminated deserts, etc., they have high failure rates. Problems, due to the aggressiveness of the medium in electronic equipment for military use, have also occurred in aircraft and submarine guidance systems. Another common problem is corrosion damage suffered by components music players, when exposed to humid environments contaminated with chlorides, for example, during transport by ship, from the manufacture location to the consumer place. Thin layers of corrosion products on the surface of the metal component change their electrical characteristics: resistance, capacity and lead to partial or total failure of the electronic system. There are reported cases where small amounts of moisture have caused corrosion in tablets with printed circuits, nichrome resistors, fittings, electrical connectors and a wide range of components, and micro-electronic components, which have been coated with metallic films (Valdez B. et al., 2006, G. Lopez et. al., 2007)
Corrosion of metal components in the electronics industry may occur at different stages: during manufacture, storage, shipping and service. The main factors in the onset of corrosion and subsequent development are moisture and corrosive pollutants, such as chlorides, fluorides, sulfides and nitrogen compounds, organic solvent vapors, emanating from the resins used as label, or coatings formed during the curing process and packaging of microcircuits.
The sources providing aggressive pollutants are diverse, from flux residues used for welding processes, waste and vapors from electrolytic baths, arising volatile organic adhesives, plastics and acidification of their environment. Assays in artificial atmosphere, which simulates an in‐ door environment of an electronic plant have shown that the surface of the silver undergoes browning or tarnishing and the formation of dendrite whiskers due to corrosion (Figure 3).
The elemental chemical analysis of the surface (EDX – Scattered Electron Spectroscopy and XRD – X-rays) shows that the corrosion product formed on the silver surface is silver sulfide (Ag2S), due to the action of pollutant gases such as SO2 and H2S present in a humid environment (Figure 4). Moreover, the micrograph of the silver surface (SEM) shows a dendritic growth of corrosion products, characteristic for silver components.
The design of electronics equipment requires a great variety of different metals, due to their different physical and electrical features. Metals and alloys used in the electronics industry are:
- Gold (Au) coating and / or foil in electrical connectors, printed circuits, hybrid and miniature circuits.;
- Silver (Ag) for protective coating in contact relays, cables, EMI gaskets, etc..;
- Magnesium (Mg) alloys for radar antenna dishes and light structures, chassis brackets, etc..;
- Iron (Fe), steel and ferroalloys for guide components, magnetic shielding, magnetic coatings memory disks, processors, certain structures, etc..;
- Aluminum (Al) alloys for armor equipment, chassis, mounting frames, brackets, trusses, etc..;
- Copper and its alloys for cables, tablets printed circuit terminals, nuts and bolts, RF pack‐ aging, etc..;
- Cadmium (Cd) for sacrificial protective coating on iron and safe electrical connectors;
- Nickel (Ni) coating for layers such as barrier between copper and gold electrical contacts, corrosion protection, electromagnetic interference applications and compatibility of dis‐ similar material joints;
- Tin (Sn) coating for corrosion protection of welding; for compatibility between dissimilar metals, electrical connectors, RF shielding, filters, automatic switching mechanisms;
- Welding and weld coatings for binding, weldability, and corrosion protection.
Many of these metals are in contact with each other, so that in the presence of moisture, galvanic corrosion / bimetallic corrosion occurs. When using similar metals, due to design the following requirements must be taken into account.
- Designing the contact of different metals such that the area of the more noble cathodic metal should be appreciably smaller than the area of the more active anodic metal. The area of the cathode can be decreased by applying paint or coating.
- Coating the contact area of a metal with a compatible metal.
- Interpose between dissimilar metals in a metal compatible packaging.
- Sealing interfaces to prevent ingress of moisture.
- Set the electronic device in a hermetically sealed arrangement.
Other corrosion problems can occur due to the characteristics of electronic components such as electromagnetic interference, electromagnetic pulse, flux residues, finishes and materials component tips, organic products that are used for various purposes and emitting gases during curing, whiskers, embrittlement inter-metallic electrical contacts.
Metal components may corrode during manufacture and storage prior to assembly, needing protection against corrosion. In plants and warehouses, air conditioning systems must operate efficiently, removing moisture and suspended particulate matter. Filters and traps should be cleaned and replaced regularly. For closed containers, we recommend the installation of dryers with visual indicators, and the use of volatile vapor phase corrosion inhibitors. In the case of sealed black boxes, the temperature inside these drops should never be below the dew point (Veleva L. et al., 2008, Vargas L. et al., 2009, Lopez G. et al., 2010).
1. Corrosion in water
Abundant water sources are essential to a country’s industrial development. Large quantities of this precious liquid are required for cooling products, machinery and equipment, to feed boilers, meet health needs and provide drinking water to humans. Estimates of water consumption for each country are different and depend on the degree of industrial development thereof. In first world countries like the United States, these intakes are as high as several hundred billion liters per day. These countries have implemented water reuse systems with certain efficiency due to the application of appropriate treatment for purification. Water, a natural electrolyte is an aggressive environment for many metals / alloys, so that they may suffer from corrosion, whose nature is electrochemical.
As raw water or fresh water we mean natural water from direct sources such as rivers, lakes, wells or springs. Water has several unique properties and one of these is its ability to dis‐ solve to some degree the substances found in the earth’s crust and atmosphere allowing the water to contain a certain amount of impurities, which causes problems of scale deposition on the metal surface, e.g. in pipelines, boiler tubes and all kinds of surfaces that are in con‐ tact with water (Valdez, B. et al., 1999, 2010).
Oxygen is the main gas dissolved in water, it is also responsible for the costly replacement of piping and equipment due to its corrosive attack on metals in contact with dissolved oxygen (DO). The origin of all sources of water is the moisture that has evaporated from the land masses and oceans, then precipitated from the atmosphere. Depending on weather conditions, water may fall as rain, snow, dew, or hail. Falling water comes into contact with gas‐ es and particulate matter in the form of dust, smoke and industrial fumes and volcanic emissions present in the atmosphere.
The concentrations of several substances in water in dissolved, colloidal or suspended form are low but vary considerably. A water hardness value greater than 400 parts per million (ppm) of calcium carbonate, for example, is sometimes tolerated in the public supply, but 1 ppm of dissolved iron should be unacceptable. In treated water for high pressure boiler or where radiation effects are important, as in nuclear reactors, impurities are measured in very small amounts such as parts per billion (ppb).
In the case of drinking water the main concern are detailed physicochemical analysis, to find contamination, and biological assays to detect bacterial load. For industrial water supplies it is of interest the analysis of minerals in particular salts. The main constituents of water are classified as follows:
- Dissolved gases: oxygen, nitrogen, carbon dioxide, ammonia and sulfide gases;
- Minerals: calcium, sodium (chloride, sulfate, nitrate, bicarbonate, etc.), Salts of heavy metals and silica;
- Organic matter: plant and animal matter, oil, agricultural waste, household and synthetic detergents;
- Microbiological organisms: include various types of algae, slime forming bacteria and fungi.
The pH of natural waters typically lies within the range of 4.5 to 8.5; at higher pH values, there is the possibility that the corrosion of steel can be suppressed by the metal passivation. For example, Cu is greatly affected by the pH value in acidic water and undergoes a slight corrosion in water releasing small amounts of Cu in the form of ions, so that it’s corroded surface because green stained clothing and sanitary ware. Moreover, deposition of the Cu ions on surfaces of aluminum or galvanized zinc corrosion cells leads to new bimetallic con‐ tact, which cause severe corrosion in metals.
The mineral water saturation produces a greater possibility of fouling on the metal walls, due to the ease with which the insoluble salts (carbonates) can be precipitated. To control this effect it is necessary to know and use the Saturation Indices. Water saturation refers to the solubility product of a compound and is defined as the ratio of the ion activity and the solubility product. For example, water is saturated with calcium carbonate when it is no more possible to dissolve the salt in water and then it begins to precipitate as scale. In fact, it is called supersaturated when carbonate precipitation occurs on standing the solution. The most common parameters that must be known to characterize the water corrosivity, be it raw or treated, for operation in an industrial facility are shown in Table 2.
There six formulas to calculate Saturation Indices and embedding: Langelier index (LSI), Ryznar stability index, Puckorious index of scaling, Larson-Shold index, index of Stiff- Davis and Oddo-Tomson index. There is some controversy and concern for the correlation of these indices with the corrosivity of the waters, particularly regarding the Langelier (LSI).
A LSI saturation index with value “0″ indicates that the water is balanced and will not be fouling, while the positive value indicates that the water may be fouling (Table 3). The negative value of the LSI suggests that water is corrosive and can damage the metal installation, increasing the content of metallic ions in water. While some sectors of the water management industry uses the values of the indices as a measure of the corrosivity of the water. Corrosion specialists are alerted and are very wary of issuing an opinion, or extrapolate the use of indices to measure the corrosivity of the environment.
Sometimes the raw water is contaminated with chemicals such as fertilizers and other chemicals coming from agricultural areas (Figure 5).
In these cases, ionic agents such as nitrites, nitrates, etc., in water causes an accelerated process of localized corrosion to many metals and the consequent failure of equipment.
Raw water contaminants can be quite varied, including both heavy metals and organic chemicals, referred to as toxic pollutants. Among the heavy metals may be mentioned arsenic (As), mercury (Hg), cadmium (Cd), lead (Pb), zinc (Zn) and cadmium (Cd), which are sometimes at trace levels, but they tend to accumulate over time, so that priority pollutants are to be treated.
Pesticides, insecticides and plaguicides comprise a long list of compounds, for which we should be concerned: DDT (insecticide), aldrin (an insecticide), chlordane (pesticide), endo‐ sulfan (insecticide), diazinon (insecticide), among others.
Contaminants, such as polycyclic aromatic organic compounds, include what is known as volatile organic compounds such as naphthalene, anthracene and benzopyrene. There are two main sources of these pollutants: petroleum and combustion products found in munici‐ pal effluents. On the other hand, there are polychlorinated biphenyls or PCBs, which are mainly used in transformers for the electrical industry, heavy machinery and hydraulic equipment. This class of chemicals is extremely persistent in the environment and affects human health.
From the viewpoint of corrosion, these contaminants which are present even at low concentrations or trace in the raw water, favor the corrosivity the metals which are in contact with. The combination of the corrosive effects of these contaminants together with the oxidation by oxygen, minerals and other impurities, leads to consider raw water as a natural means capable of generating corrosion of metals. It is recommended at least, to carry out a process of treating raw water, to reduce significantly the hardness and remove suspended solids, which will help greatly in preventing subsequent problems of corrosion and fouling on metal surfaces, curbing economic losses and maintaining the industrial process in good operating condition.
4.1. Corrosion in potable water systems
Corrosion is a complex phenomenon that arises as a result of the interaction between water and the surface of metallic pipes or the equipment of storage and handling. The process is invariably a combination of oxidation and reduction, as already described in previous chapters. In drinking water, it should be noted that the corrosion products which are partially soluble in water in ionic form are toxic at certain concentrations, e.g. copper and lead. The existence of high concentrations of lead in water carried by copper tubing, indicate that the source of lead may be tin-lead solder at the junctions of the copper pipes. The consumption of domestic water contaminated with toxic metal ions (Pb+2, Cu+2, Zn+2, Cr+3), gives rise to acute chronic health problems. The regulations have set the following limits allowable concentration in drinking water: Cr (0.05 ppm), Cu (0.01 ppm), Pb (0.05 ppm) and Zn (5 ppm). These regulations are made in order to protect the public user and consumer of drinking water and are continuously striving for a reduction in the maximum allowable limits. Some concentrations reach zero as is the case of Pb in the United States due to the concerns Pb about poisoning of children. Still, many sources such as wells and springs are outside the control of law and toxic substances, bacteria and pathogens. Damage caused by corrosion of household plumbing may be accompanied by unpleasant aesthetic problems such as soiled clothing, unpleasant taste, stains and deposits in the toilets, floors of bathrooms, tubs and showers. To prevent corrosion of pipes, we recommend the use of PVC pipes for drinking water, replacing the metal, as a preventive measure.
Corrosion can occur anywhere on the pipes that carry drinking water, mainly at sites of con‐ tact between two dissimilar metals, thus forming a corrosion cell. In general, the metals will corrode to a greater or lesser degree in water, depending on the nature of the metal, on the ionic composition of water and its pH. Waters high in dissolved salts (water hardness), favor the formation of scale, more or less adherent, in different parts of the equipment (Figure 6). These deposits may be hard or brittle, sometimes acting as cement, creating a physical barrier between the metal and water, thereby inhibiting corrosion. Calcium carbonate (Ca‐ CO3) is the most common scale; its origin is associated with the presence of carbon dioxide gas (CO2) in water. Sometimes these deposits are filled with pasty or gelatinous hydrated iron oxides or colonies of bacteria (Valdez, B. et al., 1999, 2010).
Usually, groundwater CaCO3 saturated (calcareous soils), due to the presence of dissolved CO2, whose content depends on its content in the air in contact with the water and on temperature. These waters are often much higher in CO2 content, so they may dissolve substantial amounts of calcium carbonate. These waters are at pressures lower than they had in the ground, so CO2 gas lost with consequent supersaturation of carbonates. If conditions are appropriate, the excess of CaCO3 can precipitate as small agglomerates deposited in muddy or hard layers on solid surfaces, forming deposits. An increase in temperature is an important factor and also leads to supersaturation of carbonates, with the consequent possibility of fouling. To a lesser extent fouling can precipitate more soluble Mg carbonates (MgCO3) and Mn (MnCO3), and also oxides / hydroxides, dark colored and gelatinous. Except in very exceptional cases in sulfated water, it is normal to find deposits of gypsum (CaSO4•½ H2O) because their solubility is high, but decreases with increasing temperature. Hard silica scale (SiO2) may appear with oversaturated waters or appear as different silicates (SiO44-) trapped in the carbonate deposits. Generally, the silica appears trapped in other types of scale and it is not chemical precipitation.
Waters often carry considerable amounts of iron (ferrous ion, Fe+2), which may be often precipitated by oxidation upon contact with air as hydrated iron oxide (ferric, Fe+3) but sometimes can be Fe+2 form black sludge, more or less pasty or gelatinous and sometimes very large. The voluminous precipitate occupies the pores, significantly reducing the permeability of the fouling. Sometimes the Fe ions can come from corrosion of the pipe giving rise to simultaneous corrosion and scaling (Figure 6). Common bacteria of the genera Gallionella, Leptothrix Cremothrix are known as Fe bacteria, can give reddish-yellow voluminous precipitate and sticky ferric compounds from ferrous ion, which drastically reduce the permeability of the deposit, in addition to trap other insoluble particles.
The cost for impairment of domestic water systems and the impact on health, involves several consequences: premature corrosion and failure of the pipes and fittings that carry water in a house or building, a low thermal efficiency (up to 70%) of water heaters (boilers), which can cause their premature failure. High levels of metals or oxides, which usually are not properly, treated in drinking water cause red or blue-green deposits and stains in the toilets sinks. In addition to concerns about the aesthetic appearance, a corrosion process can result in the presence of toxic metals in our drinking water. For evaluating water quality and their tendency corrosive and / or fouling, LSI can be used. This analysis must be accompanied by measurements of water pH and conductivity, and corrosion tests applying international standards.
4.1. Anticorrosive treatment of water Corrosion control is complex and requires a basic knowledge of corrosion of the system and water chemistry. Systems can be installed for water pretreatment, using non-conductive connections, reducing the temperature of hot Cu water pipes employed and copper installing PVC or other plastic materials. It is important to note that the corrosiveness of water can be increased by the use of water softeners, aeration mechanisms, increasing the temperature of hot water, water chlorination, and attachment of various metals in the water conduction system. A proper balance between the treatment systems and water quality, can be obtained with acceptable levels of corrosivity. Thus, the lifetime of the materials that make the water system in buildings, public networks, homes and other systems will be longer.
1. Soil corrosion
A large part of steel structures: aqueducts, pipelines, oil pipelines, communications wire ropes, fuel storage tanks, water pipes, containers of toxic waste, are buried, in aggressive soils. Large amounts of steel reinforced concrete structures are also buried in various soil types. In the presence of soil moisture it is possible to have humid layer on the metal sur‐ face, whose aggressiveness depends on soil type and degree of pollution (decaying organic matter, bacterial flora, etc.). Thus, the soil can form on the metal surface an electrolyte complex with varying degrees of aggressiveness, a necessary element for the development of an underground electrochemical corrosion. The corrosion process of buried structures is extremely variable and can occur in a very fast, but insignificant rate, so that pipes in the soil can have perforations, presenting localized corrosion attack or uniform.
Metal structures are buried depending on their functionality and security. Most often they traverse large tracts of land, being exposed to soils with different degrees of aggressiveness exposed to air under atmospheric conditions (Figure 7).
When pipes or tanks are damaged by corrosion, the formation of macro-and micro-cracks can lead to leaks of contained products or fluids transported, causing problems of environmental pollution, accidents and explosions, which can end in loss of life and property (Guadalajara, Jalisco, Mexico, 1992). In the case of pipes used to carry and distribute water, a leak may cause loss of this vital liquid, so necessary for the development of society in general and especially important in regions where water is scarce, so the leakage through aqueducts pipes should be avoided. An important tool needed to prevent the most serious events, is the knowledge of the specific soil and its influence on the corrosion of metal structures.
5.1. Types of soils and their mineralogy
A natural soil contains various components, such as sand, clay, silt, peat and also organic matter and organisms, gas, mineral particles and moisture. The soils are usually named and classified according to the predominant size range of individual inorganic constituent particles. For example, sandy soil particles (0.02 – 2 mm) are classified as fine sand (0.02 – 0.2 mm) or thick (0.20 -2.00 mm). Silt particles (0.002 to 0.02 mm) and clay, which have an average diameter 0.002 mm, are classified as colloidal matter. A comparison of the sizes of these typical soils is done in Figure 8.
Currently exists in the U.S. and in over 50 countries worldwide, a detailed classification for soils, which includes nine classes with 47 subgroups.
The variation in the proportion of the groups of soil with different sizes, determines many of its properties. Fine-textured soils due to high clay content, have amassed particles, so they have less ability to store and transport gases such as oxygen, that any ground-open e.g. sandy soil. The mineralogy of both clay types and their properties, are closely related to the corrosivity of the soil. Silica (SiO2) is the main chemical constituent of soils type clay, loam and silt, also in the presence of Al2O3. Common species in moist soil are dissolved ions H+, Cl-, 2- -SO4 , HCO3 . The chemical composition and mineralogy of the soil determine its corrosive aggressiveness; poorly drained soils (clay, silt and loam) are the most corrosive, while soils with good drainage (gravel and sand type) are less aggressive to metals. Vertically homogeneous soils do not exist, so it is convenient to consider the non-uniformity of ground, formed of different earth layers. To understand the corrosion behavior of a buried metal is very important to have information about the soil profile (cross section of soil layers). The physicochemical and biological nature of soil, corrosive aggressiveness and dynamic interactions with the environment, distinguishes the ground like a very complex environment and different from many others. Climate changes of solar radiation, air temperature and relative humidity, amount of rainfall and soil moisture are important factors in corrosion. Wind, mechanical action of natural forces, chemical and biological factors, human manipulation can alter soil properties, which directly affects the rate of corrosion of metals buried in the ground. Conditions may vary from atmospheric corrosion, complete immersion of the metal, depending on the degree of compactness of the soil (existence of capillaries and pores) and moisture content. Thus the variation in soil composition and structure can create different corrosion environments, resulting in different behavior of the metal and oxygen concentrations at the metal / soil interface.
Two conditions are necessary to initiate corrosion of metal in soil: water (moisture, ionic conductor) and oxygen content. After startup, a variety of variables can affect the corrosion process, mentioned above, and among them of importance are the relative acidity or alkalinity of the soil (pH), also the content and type of dissolved salts.
Mainly three types of water provide moisture to the soil: groundwater (from several meters to hundreds below the surface), gravitational (rain, snow, flood and irrigation) and capillary (detained in the pores and capillary spaces in the soil particles type clay and silt). The mois‐ ture content in soils can be determined according to the methodology of ASTM D 2216 (“Method for Laboratory Determination of Water (Moisture) Content of Soil and Rock by Mass”), while its permeability and moisture retention can be measured the methods descri‐ bed in ASTM D2434 and D2980. The presence of moisture in soils with a good conductivity (presence of dissolved salts), is an indication for high ion content and possible strong corrosive attack.
The main factors that determine the corrosive aggressiveness of the soil are moisture, rela‐ tive acidity (pH), ionic composition, electrical resistance, microbiological activity.
5.1. Corrosion control of buried metals
Given the electrochemical nature of corrosion of buried metals and specific soils, this can be controlled through the application of electrochemical techniques of control, such as cathodic protection. This method has been universally adopted and is appropriate to protect buried metallic structures. For an effective system of protection and cheaper maintenance, pipelines must be pre-coated, using different types of coatings, such as coal tar, epoxies, etc. This helps reduce the area of bare metal in direct contact with the ground, lowering the demand for protection during the corrosion process. The purpose of indirect inspection is to identify the locations of faulty coatings, cathodic protection and electrical Insufficient shorts (close- interval, on/off Potential surveys, electromagnetic surveys of attenuation current, alternating current voltage gradient surveys, etc..), interference current, geological surveys, and other anomalies along the pipeline.
1. Corrosion under thermal insulation
One of the most common corrosion problems in pipes, ducts, tanks, preheaters, boilers and other metal structures, insulated heat exchange systems, is the wear and corrosion occurring on metal (steel, galvanized steel, Al, SS, etc.), below a deposit or in its immediate neighbor‐ hood. This corrosion is known as corrosion under deposit. The deposit may be formed by metal corrosion products and / or different types of coating applied for protection. For ex‐ ample, in the case of a calcareous deposit, formed in the walls of galvanized steel pipes which carry water with a high degree of hardness (dissolved salts), it might develop corro‐ sion under deposit. These shells may be porous, calcareous deposit and / or partially detach‐ ed from the metal surface, so that direct contact between metal, water and oxygen (the oxidizing agent in the corrosion process) allows the development of metal corrosion. For this reason the pipes could be damaged severely in these locations up to perforation, while in parts of the installation corrosion might occur at a much lower level.
There is a considerable amount of factors in the design, construction and maintenance, which can be controlled to avoid the effects of deterioration of metal by corrosion under de‐ posit. In general, under these conditions the metal is exposed to frequent cycles of moisture, corrosivity of the aqueous medium or failure in the protective coatings (paint, metal, ce‐ ment, fiberglass, etc.). Figure 9 shows a conductor tube steam in a geothermal power plant, where CS corrosion happened beneath the insulation.
Seven factors can be controlled on the ground, to prevent this type of corrosion: design of equipment, operating temperature, selection of the insulation, protective coatings and paints, physical barriers from the elements, climate and maintenance practices of the facility. Any change in any of these factors may provide the necessary conditions for the corrosion process to take place. The management knowledge of these factors help explain the causes of the onset conditions of corrosion under deposits, and it will guide a better inspection of existing equipment and the best design.
6.1. Equipment design
The design of pressure vessels, tanks and pipes, generally includes accessories for support, reinforcement and connection to other equipment. Details about the installation of accessories are the responsibility of the engineers or designers, using building codes to ensure reliability of both insulated and non insulated equipment. The protective barrier against the environment surrounding the metal structure in such designs often breaks donor due to an inappropriate insulation, loss of space for the specified thickness of insulation or simply by improper handling during installation of the equipment. The consequence of a rupture or insulation failure means greater flow water ingress to the space between metal and coating hot-cold cycle, generating over time a buildup of corrosive fluid, increasing the likelihood of corrosive damage. Moreover, wet insulation will be inefficient and also cause economic loss‐ es. The solution of this factor is to meet the thickness specifications and spacing, as indicated in the code or equipment-building specifications and characteristics of the coating used.
The operating temperature is important for two reasons: a high temperature favors the wa‐ ter is in contact with the metal for less time, however, also provides a more corrosive environment, causes fast failures of coatings. Usually a team operating in freezing temperatures is protected against corrosion for a considerable life time. However, some peripheral devices, which are coupled to these cold spots and operating at higher temperatures, are ex‐ posed to moist, air and steam, with cycles of condensation in localized areas, which make them more vulnerable to corrosion. For most operating equipment at freezing conditions, the corrosion occurs in areas outside and below the insulation. The temperature range where this type of corrosion occurs is 60 °C to 80 °C; however, there have been failures in zones at temperatures up to 370 °C. Also, in good water-proof insulation, corrosion is likely to occur at points where small cracks or flaws are present, so that water can reach the hot metal and evaporate quickly. On the other hand, in machines where the temperature reach‐ es extreme values, as in the case of distillation towers, it is very likely to occur severe corro‐ sion problems.
6.2. Selection of insulation
The characteristics of the insulation, which have a greater influence on the corrosion proc‐ esses deposits, are the ability to absorb water and chemical contribution to the aqueous phase. The polyurethane foam insulation is one of the most widely used; however, in cold conditions they promote corrosion due to water absorption present. The coatings of glass fi‐ ber or asbestos can be used in these conditions, always when the capacity of absorbing wa‐ ter do not becomes too high. Corrosion is possible under all these types of coating, such insulation. The selection of insulation requires considering a large group of advantages and disadvantages regarding the installation, operation, cost, and corrosion protection, which is not an easy task. The outside of the insulation is the first protective barrier against the ele‐ ments and this makes it a critical factor, plus it is the only part of the system that can be readily inspected and repaired by a relatively inexpensive process. The durability and ap‐ pearance, melting point fire protection, flame resistance and installation costs are other im‐ portant factors that must be taken into account together with the permeability of the insulation. Usually the maintenance program should include repairs to the range of 2 to 5 years. Obviously the weather is important and corrosion under thermal insulation will more easily in areas where humidity is high. Sometimes conditions of microclimate can be ach‐ ieved through the use of a good design team.
1. Corrosion in the automotive industry
One of the most important elements of our daily life, which has great impact on economic activity, is represented by automotive vehicles. These vehicles are used to transport people, animals, grains, food, machinery, medicines, supplies, materials, etc. They range from com‐ pact cars to light trucks, heavy duty, large capacity and size. All operate mostly through the operation of internal combustion engines, which exploit the heat energy generated by this process and convert it in a mechanical force and provide traction to these vehicles.
The amount and type of materials used in the construction of automotive vehicles are diverse, as the component parts. They are usually constructed of carbon steel, fiberglass, aluminum, magnesium, copper, cast iron, glass, various polymers and metal alloys. Also, for aesthetic and protection against corrosion due to environmental factors, most of the body is covered with paint systems, but different metal parts are protected with metallic or inorganic coatings.
Corrosion in a car is a phenomenon with which we are in some way familiar and is perhaps for this reason that we often take precautions to avoid this deterioration problem.
A small family car, with an average weight of 1000 kg, is constructed of about 360 kg of sheet steel, forged steel 250 kg, 140 kg cast iron mainly for the engine block (now many are made of aluminum), 15 kg of copper wires, 35 kg and of plastic 50 kg of glass that usually do not deteriorate, and 60 kg for rubber tires; which wear and tear. The remaining material is for carpets, water and oil. Obviously, that is an advanced technology in the car industry, with automobiles incorporating many non-metallic materials into their structure. However, the problem of corrosion occurs at parts where the operation of the vehicle is compromised. Corrosion happens in many parts of the car (mostly invisible) it is not only undesirable for the problems it causes, but also reduces the vehicle’s resale value and decreases the strength of the structure. To keep the car in good condition and appearance, its high price, it is neces‐ sary to pay attention to the hidden parts of the vehicle.
The main cause of corrosion of the car body is the accumulation of dust in different closed parts, which stays for a long time by absorbing moisture, so that in these areas metal corrosion proceeds, while in the clean and dry external parts it does not occur (Figure 10).
The corrosion problem that occurs in the metal car body has been a serious problem that usually arises most often in coastal environments, contaminated with chlorides and rural areas with high humidity and specific contaminants. Many countries use salt (NaCl, CaCl2 or MgCl2) to keep the roads free of ice; under these conditions these salts, in combination with the dust blown by the car, provide conditions for accelerated corrosion. Therefore, it is recommended as a preventative measure, after a visit on the coast or being on dirty roads, to wash the car with water, and also the tires and the doors, especially their lower parts. In urban environments, the corrosion problem has been reduced due to the new design and application of protective coatings, introduced by major manufacturers in the early nineties of the twentieth century. The areas most affected are fenders, metal and chrome bumpers views which are used in some luxury vehicles as well as areas where water and mud are easily accumulated e.g. auctions of funds windshield and doors (Figure 11).
In regions with high incidence of solar radiation and the presence of abrasive dust, paint vehicles deteriorate rapidly. The hot, humid weather, combined with high levels of SO2 and NOx emissions that come from burning oil, chlorides salt. In the Gulf of Arabia, the blowing sand from the nearby desert, creates a very aggressive environment; statistics reveals that one in seven cars is damaged and due to corrosion the car life is estimated to an average of 8 months, also the car corrosion resistance decreases in the following order: manufactured in Europe, USA and Japan. White paints generally have shown a significantly better corrosion protection than other colors. Initially, corrosion defects appear as a kind of dots and spots of corrosion products formed under the paint and subsequently emerge from the steel sheet, leaving a free entry for moisture and air (oxygen), accelerating the corrosion process; in these cases reddish metal corrosion products.
7.1. Corrosion in the cooling systemThe cooling system of a car combustion engine consists of several components, constructed of a variety of metals: radiators are made of copper or aluminum, bronze and solder couplings with tin water pumps; motors are made of steel, cast iron or aluminum. Most modern automobiles, with iron block engine and aluminum cylinder head, require inhibitor introduced into the cooling water to prevent corrosion in the cooling system. The inhibitor is not antifreeze, although there are in the market solutions which have the combination of inhibitor-antifreeze. The important thing is to use only the inhibitor recommended in the automobile manual and not a mixture of inhibitors, since these may act in different ways and mechanisms. The circulating water flow should work fine without loss outside the system. If the system is dirty, the water should be drain and filling the system with a cleaning solution. It is not recommended to fill the system with hard water, but with soft water, introducing again the inhibitor in the correct concentration. If there exhaust at the water cooling system, every time water is added the inhibitor concentration should be maintained to prevent.
In small cars, it is common for water pumps; constructed mainly of aluminum, to fail due to corrosion, cavitation, erosion and corrosion, making it necessary to replace the pump (Val‐ dez, B. et al., 1995). Accelerated corrosion in these cases is often due to the use of a strong alkaline solution of antifreeze. On the other hand, in heavy duty diesel trucks, the cooling system is filled with tap water or use filters with rich conditioner chromates that can cause the pistons jackets to suffer localized corrosion. After 12 or 15 months, the steel jackets are perforated and the water passes into the cavity through which the piston runs, forcing tocarry out repair operations (Figure 12).
Corrosion causes great economic losses to the transport industry, since it must stop to repair the truck and abandon to provide the service with all the consequences that this entails. Fur‐ thermore, the use of chemical conditioning is now controlled by environmental regulations, so chromates and phosphates are restricted and novel mixtures of corrosion inhibitors have been produced to control the problem of corrosion in automobile cooling systems.
7.1. Corrosion in exhaust pipes and batteries
Exhaust pipes made of SS (0.6 – 0.8 mm thick) have a better resistance to chemical corrosion at high temperatures, which is why we are now using SS in many popular models. This SS resists corrosion much more than conventional CS and thus their long life covers the higher price. An‐ other alternative is to use conventional CS tube, zinc coated or aluminum (Figure 13). These ex‐ haust pipes are less expensive than stainless steel, but less resistant to corrosion.
The acidic environment which is generated on the surface of accumulators supplying the energy necessary for starting the engine, favors conducting corrosion processes in the lead terminals, where the cables are connected by bronze or steel clamps. Thus, this environment and these contact zones predispose cells to a process galvanic corrosion, which gradually deteriorates the contact wires, generating bulky corrosion products. This phenomenon is called sulfation of the contacts due to the sulfuric acid containing the battery, thus forming white sulfates on the corroded metal surface. These products introduce high resistance to current flow and cause failure to the engine ignition system, and impede the battery charge process. This problem has been eliminated in batteries that have airtight seals, or are manufactured with new technologies as well as bases covered with organic coatings that prevent corrosion.
Some years ago it was common for starters to fail, because the moisture or water penetrated into the gear area preventing it sliding motion and causing burning of the electric motor. Currently, new designs avoid contact with moisture and other foreign agents, preventing the occurrence of corrosion problems in these devices. As a preventive measure is recommended to prevent spillage of battery acid, to periodically clean the battery terminals (with a brush of wire or a special instrument), also coat them with petroleum jelly to prevent corrosion in these contact areas. A fat based composition which contains several components: alkaline salts and oxides of lithium, sodium bicarbonate and magnesium oxide are applied to the terminals and the connector. In general, in wet weather, the contacts of the accumulators have a tendency to more accelerated corrosion, thus requiring greater care to disconnect the terminals when not being used.
7.1. Corrosion prevention
To keep the vehicle for a longer time without the appearance of corrosion, it always requires washing with running water and, the use of very soft brush or cloth-like material, with a special detergent (not household detergents, which are very corrosive) and finally wash the vehicle with plenty of water. The floor carpet should be maintained clean and dry. A car should not be left wet in a hot garage, since under these conditions accelerated corrosion takes place since the water does not dry and can condense on the cold parts of the vehicle. In these cases, it is best not to close the garage door or use a roof space, to protect it from rain, and not allow moisture condensation. However, if the vehicle is left unused for a long time in a closed garage, it should be protected from dust, moisture and contaminants.
1. Corrosion control in thermoelectric plantsElectricity is a key element in ensuring economic growth and social development of a country. Many conventional power plants in recent years are being installed in combined cycle power plants, also called cogeneration. The latter, simultaneously generate electricity and / or mechanical power and useful heat, sometimes using thermal energy sources that are lost in conventional plants.
A power station is a thermoelectric energy conversion system, starting with the chemical energy of fuel that during combustion is converted into heat energy accumulated in the steam. This thermal energy generates mechanical energy from the hot steam, which expands in a turbine, turning on electricity in the generator. In this process of low energy thermal efficiency is lost in the hot gases that escape through the chimney and the cooling steam in the condenser.
Electricity generating plants burn fossil fuels such as coal, fuel oil and natural gas. These fuels containing as minor components sulfur compounds (S), nitrogen (N), vanadium (V) and chloride (Cl-). These are corrosive chemicals attacking the metal infrastructure; and polluting the environment by becoming acid gas emissions, also affecting the health of the population.
The three central equipment of a thermoelectric plant are the boiler, which converts the wa‐ ter into steam, the steam turbine to whom the pressure imparts a rotary motion and the con‐ denser that condenses the vapor released by the turbine and the condensed water is returned to the boiler as feed water. The turbine itself transmits rotary motion to the genera‐ tor of electricity, which will be distributed to industrial, commercial and homes in cities.
Corrosion in steam plant equipment occurs in two parts of the boiler: on the water side and the steam side, with the fire temperature up to 700 ° C, depending on the type, size and ca‐ pacity of the boiler. The boiler feedwater must be treated to eliminate the corrosive components: salts such as chlorides and sulfates dissolved oxygen (DO); silicates and carbonates, producing calcareous scale on the boiler walls, regarded as precursors for the formation of corrosion under deposits. The water is softened by eliminating salts and treated to remove oxygen; the pH is controlled by addition of alkaline phosphate to reach a pH range of 10 to 11, and inhibitors are added to the feedwater to prevent corrosion.
The flue gases and ash solid particles reach temperatures up to 1000 to 1200 °C, impinging on the outer surface of the boiler water tubes and preheater, creating an atmosphere for aggressive chemical corrosion. The damaged tubes lose its thickness generating metal corrosion products; they often are fractured, suffering a stress corrosion due to the combined effects of mechanical stress and corrosion (Figure 14). Since the tubes lose steam and pres‐ sure, the operation of the plant is interrupted and the tubes or its sections should be changed incurring severe economic losses. For example, in the United States has been concluded that the costs of electricity are more affected by corrosion than any other factor, contributing 10% of the cost of energy produced.
A study reveals that in 1991 there were more than 1250 days lost in nuclear plants operating in the United States, due to failure by corrosion, which represented an economic loss of $250.000 per day. Such statistics indicate that the power generation industry needs to obtain a balance between cost and methods for controlling effectively corrosion in their plants. It is sometimes advisable to add additives to the fuel, for example, magnesium oxide which prevent the deposition of the molten salts on the boiler tubes. Corrosion occurs also in the combustion air preheater, by sulphurous gases which react with condense and form sulfuric acid. Metal components of the turbine rotor: disks and blades suffer from corrosion by salts, alkali and solid particles contained in the vapor. In these cases, it is common to observe the phenomena of erosion-corrosion, pitting and stress corrosion fracture; their damage can be ameliorated through a strict quality control of boiler water and steam.
Efficient maintenance and corrosion control in a power plant is based on the following:
- Operation according to mechanical and thermal regime, indicated by the designer and builder of the plant;
- Correct treatment of fuel, water and steam;
- Chemical cleaning of the surfaces in contact with water and steam, using acidic solutions containing corrosion inhibitors, passivating ammoniacal solutions and solutions;
- Mechanical cleaning of surfaces covered with deposits (deposits), using alkaline solutions and water under pressure;
- Perform an optimum selection of the materials of construction for the components of the plant, including those suitable as protective coatings.
- The installation of online monitoring of corrosion in critical plant areas will be one of the most effective actions to control corrosion. In addition, it is recommended same use and document to use corrosion expert system software and materials databases for the analy‐ sis of the materials corrosion behavior.
Corrosion in power plants can be controlled by applying the knowledge, methods, stand‐ ards and materials, based on corrosion engineering and technology.
1. Corrosion in geothermal environments
The development of alternative energy sources represents one of the most attractive challenges for engineering. There are several types of renewable energies already in operation, such as wind, solar and geothermal. Geothermal environments can lead to aggressive environments, e.g. the geothermal field of “Cerro Prieto”, located in Baja California, Mexico.
The physical and chemical properties of the vapor at “Cerro Prieto” make it an aggressive environment for almost any type of material: metal, plastic, wood, fiberglass or concrete. The typical chemical composition of a geothermal brine, is shown in Table 4. Many engineering materials are present as components of the infrastructure and field equipment, required for the steam separation, purification and posterior operations for the generation of electricity. This entire infrastructure is a costly investment and therefore, failure or stoppage of one of them, means economic losses, regardless of how vital it is to maintain constant production of much-needed electricity.
In the process of the geothermal fluid exploitation, corrosion of metal structures occurs from the wells drilling operation, where the drilling mud used, causes corrosion of pumping and piping equipment. Subsequently, when the wells pipes are in contact with the steam, they can also suffer from corrosion-erosion problems, where the corrosive agent is hydrogen sulfide. Steam separators and the pipes are exposed to problems of fouling and localized corrosion due to the presence of aggressive components such as H2S and chloride ions (Cl-), present in the wells fluid. These agents lead to the deterioration of reinforced concrete foundations supporting steel pipes, or other concrete structures used to separate steam from water and to operate steam silencers. The reinforced concrete deterioration due to steel corrosion in this aggressive environment, and the steam pressure mechanical forces lead to concrete damage with formation of cracks and fractures.
In the power plants, the observed corrosion affects components of the steam turbines, condensers and pipelines, and also the cooling towers and concrete structures inside and outside the building that houses the plant. In these cases, the effects of corrosive attack appears in the form of localized corrosion in metal walls and gas piping) or as corrosion fatigue or stress corrosion, caused by cyclic mechanical forces or residual stresses, in turbines and other metal equipment. Table 5 shows a list of equipment and materials used for construction,which are part of the infrastructure of a geothermal power (Valdez, B. et al., 1999, 2008)
The combination of an aerated moist environment with the presence of hydrogen sulfide gas (H2S) dissolved in water provides a very aggressive medium (Figure 16), which promotes the corrosion of metals and alloys, such as CS and SS. The presence of dust, from the geothermal field and condensation cycles favor the failure of protective coatings applied to steel, so that developed corrosion leads to constant repairs and maintenance of metal installations: pipes, machinery, cooling towers, vehicles, tools, fences, warehouses, etc.
Cooling towers constructed of wood, steel and fiberglass in the presence of flowing and stagnant water and air currents (induced to complete cooling fans), suffer a serious deterioration of the steel by corrosion and biodeterioration, involving a variety of microorganisms. The timber is subjected to oxygen delignification under the effect of colonies of fungi and algae, as well as fiberglass reinforced polyester screens, which deteriorate due to colonies of aerobic and anaerobic bacteria e.g. sulfate reducers.
Furthermore, carbon steels corrode in the form of delamination due to sulfate reduction processes which induce the oxidation of iron, while the SS nails and screws undergoes localized corrosion, forming pits (Figure 17)
The deterioration by microorganisms capable of living in these conditions is one of the processes that have provided more information to the study of corrosion induced by microorganisms. In “Cerro Prieto”, for example, have been isolated and studied various bacteria capable of growing even at temperatures of 70 ° C under conditions of low nutrient concen‐ trations, while in the geothermal field of “Azufres” bacteria have been isolated to survive at temperatures of 105 °C and pressures of downhole (Figure 18).
1. Corrosion in the paper industry
Corrosion of the infrastructure used in the pulping and paper industry, is another serious problem for corrosion specialists. The wide experience, gathered from cases of corrosion in the various infrastructure components of the paper industry, has provided an extensive literature on mechanisms, types and control of corrosion in this environment.
In the early 60′s of last century, when the continuous digester process was adopted, the paper industry had limited knowledge about caustic embrittlement. Currently, it is known that the digesters are subjected to caustic levels and temperatures too close to the fracture caustic range where the total relieves of stresses in the material are essential. To elucidate the mechanism of this phenomenon, it was necessary to conduct serious investigations, which subsequently provide solutions to the problem of corrosion and caustic embrittlement. Technology in the paper industry has evolved over the last forty years and in parallel we can talk about the solution of corrosion problems in different parts of its infrastructure. Components with high failure rate due to corrosion are those built of bronze, SS, cast iron. Corrosion occurs in the papermaking machinery, where the white water equipment is subjected to an aggressive environment. The metal surfaces are exposed to immersion in this water; to steam that promotes the formation of cracks, which favor the deposit of pulp and other compounds. CS undergoes rapid uniform corrosion, while the copper alloys and SS (austenitic UNS S30400 L: 18% Cr8% Ni, UNS S31600 L: 16% Cr10% Ni 2% Mo) develop localized pitting corrosion. In the mill bleach plants the pulp equipment has traditionally been made of SS which has good general corrosion resistance and weldability. The use of chlorine gas (Cl2) and oxygen in the bleach plant and pulp bleaching, favors a very aggressive oxidant and SS, as type 317 L (18% Cr14% Ni3.5% Mo). However, in the last 25 years the environment in these plants has become much more corrosive due to the wash systems employed for the paper pulp, which increased the emission of oxidizing and corrosive gas‐ es; so type “317 L” SS is not resistant and has a shorter service life. Many mills in the paper industry have opted for the use of high-alloy SS, nickel (Ni) and titanium (Ti), for better corrosion resistance in these particular environments. In general, SS exposed to corrosive environment of bleach plants are benefited by the share of chromium, nickel and molybdenum as alloying elements, which increase their resistance to the initiation of pitting and crevice corrosion. The addition of nitrogen (N) increases its resistance to pitting corrosion, particularly when it contains molybdenum (Mo). Furthermore, to avoid waste of elements such as carbon (C), where a concentration greater than 0.03%, can cause sensitization at affected by heat areas in the solder, causing the SS to be less resistant to corrosion. Other waste elements, such as phosphorus (P) and sulfur (S) can cause fractures in the hot steel, formed in the metal welding area. The corrosive environment of bleach plants contain residual oxidants such as chlorine (Cl2) and chlorine dioxide (ClO2), these are added to resists the effects of temperature and acidity, maintaining a very aggressive environment.
Corrosion also occurs in the pulping liquor facilities by sulfites, chemical recovery boilers, suction rolls and Kraft pulping liquors. The Kraft process is the method of producing pulp or cellulose paste, to extract the wood fibers, necessary for the manufacture of paper.
The process involves the use of sodium hydroxide (NaOH) and sodium sulfite (Na2SO3) to extract the lignin from wood fibers, using large high pressure digesters. High strength is obtained in the fiber and methods for recovery of chemicals explain the popularity of the Kraft process. The black liquor separated, is concentrated by evaporation and burned in a recovery boiler to generate high pressure steam, which can be used for the plant steam requirements for the production of electricity. The inorganic portion of the liquor is used to regenerate sodium hydroxide and sodium sulfite, necessary for pulping. Corrosion of metals in the facilities used in this process may occur during the acid pickling operation for the removal of carbonate incrustations on the walls and black liquor pipe heaters. It has been found that SS 304 L presents fracture failure and stress corrosion. In the recovery processes of chemical reagents, known as stage re alkalinization, metals can fail due to caustic embrittlement or corrosion-erosion under conditions of turbulent flow. Corrosion also occurs in the equipment used for mechanical pulping, such as stress corrosion cracking, crevice corrosion, cavitation and corrosion-friction.
B. Valdez1, M. Schorr1, R. Zlatev1, M. Carrillo1, M. Stoytcheva1, L. Alvarez1, A. Eliezer2 and N. Rosas3
1 Instituto de Ingeniería, Departamento de Materiales, Minerales y Corrosión, Universidad Autónoma de Baja California, Mexicali, Baja California, México
2 Sami Shamoon College of Engineering Corrosion Research Center, Ber Sheva, Israel 3 Unversidad Politécnica de Baja California, Mexicali, Baja California, México
 Acuña, N., Valdez, B., Schorr, M., Hernández-Duque, G., Effect, of., Marine, Biofilm., on, Fatigue., Resistance, of., an, Austenitic., & Stainless, Steel. Corrosion Reviews, United Kingdom (2004). , 22(2), 101-114.
 Carrillo, M., Valdez, B., Schorr, M., Vargas, L., Álvarez, L., Zlatev, R., Stoytcheva, M., In-vitro, Actinomyces., israelii’s, biofilm., development, on. I. U. D., copper, surfa‐ ces., & Contraception, Vol. (2010). (3), 261-264.
 Carrillo Irene, Valdez Benjamin, Zlatev Roumen, Stoycheva Margarita, Schorr Mi‐ chael, and Carrillo Monica, Corrosion Inhibition of the Galvanic Couple Copper-Car‐ bon Steel in Reverse Osmosis Water, Research Article, Hindawi Publishing Corporation, International Journal of Corrosion, Volume(2011). Article ID 856415
 2010, Garcia, A., Valdez, B., Schorr, M., Zlatev, R., Eliezer, A., Haddad, J., Assess‐ ment, of., marine, , fluvial, corrosion., of, steel., aluminium, Journal., of, Marine., En‐ gineering, , & Technology, Vol. (18), 3-9.
 Garcia Inzunza Ramses, Benjamin Valdez, Margarita Kharshan,Alla Furman, and Mi‐ chael Schorr, ((2012). Interesting behavior of Pachycormus discolor Leaves Ethanol Extract as a Corrosion Inhibitor of Carbon Steel in 1M HCl. A preliminary study. Re‐ search Article, Hindawi Publishing Corporation, International Journal of Corrosion, Article ID 980654, 8 , 2012, 2012.
 Lopez, B. G., Valdez, B., , S., Zlatev, R., , K., Flores, J., , P., Carrillo, M., , B., Schorr, M., & , W. Corrosion of metals at indoor conditions in the electronics manufacturing industry. Anti-Corrosion Methods and MaterialsUnited Kingdom, N0. 6, Noviembre (2007). , 54, 354 EOF-359 EOF.
 Lopez, B. G., Valdez, B., , S., Schorr, M., , W., Rosas, N., , G., Tiznado, H., , V., Soto, G., & , H. Influence of climate factors on copper corrosion in electronic equipment and devices. Anti-Corrosion Methods and MaterialsUnited Kingdom, N0. 3, (2010). , 57, 148 EOF-152 EOF.
 Lopez, Gustavo, Hugo Tiznado, Gerardo Soto Herrera, Wencel De la Cruz, Benjamin Valdez, Miguel Schorr, Zlatev Roumen,(2011). Use of AES in corrosion of copper connectors of electronic devices and equipments in arid and marine environments. Anti-Corrosion Methods and MaterialsIss: 6, , 58, 331-336.
 Lopez, Badilla Gustavo, Benjamin Valdez Salas and Michael Schorr Wiener, Analysis of Corrosion in Steel Cans in the Seafood Industry on the Gulf of California, Materi‐ als Performance, Vol.April (2012). (4), 52-57.
 Navarrete, M., Ballesteros, M., Sánchez, J., Valdez, B., Hernández, G., Biocorrosion, in. a., geothermal, power., plant, Materials., & Performance, April. (1999). USA., 38, 52-56.
 Schorr, M., Valdez, B., Zlatev, R., Stoytcheva, M., Erosion, Corrosion., in, Phosphor‐ ic., Acid, Production., Materials, Performance., & Jan, . (2010). USA, 50(1), 56-59.
 Stoytcheva, M., Valdez, B., Zlatev, R., Schorr, M., Carrillo, M., Velkova, Z., Microbial‐ ly, Induced., Corrosion, in., The, Mineral., Processing, Industry., Advanced, Materi‐ als., & Research, . (2010). Trans. Tech publications, Switzerland, 95, 73-76.
 Raicho Raichev, Lucien Veleva y Benjamín Valdez, Corrosión de metales y degrada‐ ción de materiales.Principios y prácticas de laboratorio. Editorial UABC, 978-6-07775-307-0(2009). pp
 Santillan, S. N., Valdez, S. B., Schorr, W. M., Martinez, R. A., Colton, S. J., Corrosion, of., the, heat., affected, zone., of, stainless., steel, weldments., Anti-Corrosion, Meth‐ ods., Materials, United., & Kingdom, Vol. (2010). (4), 180 EOF-184 EOF.
 Schorr, M., Valdez, B., Zlatev, R., Stoytheva, M., Santillan, N., Phosphate, Ore., Proc‐ essing, For., Phosphoric, Acid., Production, Classical., And, Novel., Technology, Min‐ eral., Processing, , Extractive, Metallurgy., & Vol, . (2010). (3), 125-129.
 Valdez, B., Guillermo Hernandez-Duque, Corrosion control in heavy-duty diesel en‐ gine cooling systems, CORROSION REVIEWS Vol.Nos. 2-4, (1995). , 245-260.
 Valdéz, Salas. B., Miguel, Beltrán., Rioseco, L., Rosas, N., Sampedro, J. A., Hernan‐ dez, G., & Quintero, M. Corrosion control in cooling towers of geothermoelectric power plants. Corrosion Reviews, (1996). England., 14, 237-252.
 Valdez, B., Rosas, N., Sampedro, J., Quintero, M., Vivero, J., Hernández, G., Corro‐ sion, of., reinforced, concrete., of, the., Rio, Colorado., Tijuana, aqueduct., Materials, Performance., & May, . (1999). USA., 38, 80-82.
 Valdez, B., Rosas, N., Sampedro, J., Quintero, M., Vivero, J., Influence, of., elemental, sulphur., on, corrosion., of, carbon., steel, in., geothermal, environments., Corrosion, Reviews., & Vol, . Nos. 3- 4, October (1999). England, 167-180.
 Valdez, S. B., Zlatev, R., , K., Schorr, M., , W., Rosas, N., , G., Ts, Dobrev. M., Monev, I., Krastev, Rapid., method, for., corrosion, protection., determination, of. V. C. I., Films-Corrosion, Anti., Methods, , Materials, United., & Kingdom, Vol. Noviembre (2006). (6), 362-366.
 Valdez, B., Carrillo, M., Zlatev, R., Stoytcheva, M., Schorr, M., Cobo, J., Perez, T., & Bastidas, J. M. Influence of Actinomyces israelii biofilm on the corrosion behaviour of copper IUD, Anti-Corrosion Methods and Materials, United Kingdom, N0. 2, 55-59, (2008). , 55
 Valdez, B., Schorr, M., Quintero, M., Carrillo, M., Zlatev, R., Stoytcheva, M., Ocampo, J., Corrosion, , scaling, at., Cerro, Prieto., Geothermal, Field., Anti-Corrosion, Meth‐ ods., Materials, United., & Kingdom, Vol. N0. 1, (2009). , 28 EOF-34 EOF.
 Valdez, B., Schorr, M., Corrosion, Control., in, The., Desalination, Industry., Ad‐ vanced, Materials., & Research, . (2010). Trans. Tech publications, Switzerland, 95, 29-32.
 Valdez, B., Schorr, M., Quintero, M., García, R., Rosas, N., The, effect., of, climate., change, on., the, durability., of, engineering., materials, in., the, hydraulic., & infra‐ structure, . An overview. Corrosion Engineering Science and Technology(2010). , 45(1), 34-41.
 Valdez, B., Schorr, M., So, A., Eliezer, A., Liquefied, Natural., Gas, Regasification., Plants, Materials., Corrosion, M. A. T. E. R. I. A. L. S. P. E. R. F. O. R. M. A. N. C. E., & Vol, . December (2011). (12), 64-68.
 Vargas, O. L., Valdez, S. B., Veleva, M. L., Zlatev, K. R., Schorr, W. M., Terrazas, G. J., Corrosion, of., silver, at., indoor, conditions., of, assembly., processes, in., the, micro‐ electronics., industry-Corrosion, Anti., Methods, , Materials, United., & Kingdom, Vol. N0. 4, (2009). , 218 EOF-225 EOF.
 Veleva, L., Valdez, B., López, G., Vargas, L., Flores, J., Atmospheric, Corrosion., of- Electronics, Electro., Metals, in., Urban-Desert, Indoor., & Environment, . Corrosion of Electro-Electronics Metals in Urban-Desert Indoor Environment. Corrosion Engineering Science and Technology(2008). , 43(2), 149-155.
This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/3.0), original found here:http://www.intechopen.com/books/environmental-and-industrial-corrosion-practical-and-theoretical-aspects/corrosion-control-in-industry
Advanced Ultrapen features include automatic temperature compensation; highly stable microprocessor-based circuitry; user-intuitive design; and waterproof housing. A true one-handed instrument, the Ultrapens are easy to calibrate and easy to use. To take a measurement, you simply push a button then dip the pen in solution. Results display in seconds.This instrument is designed to be extremely accurate, fast and simple to use in diverse water quality applications.
PoolPro gives you the most reliable, precise, affordable, multiparameter pool testing meter available for testing water quality in any pool or spa.
PoolPro is a comprehensive high performance tool designed to simplify pool and spa water quality control for the pool professional. Both PoolPro models feature innovative user-friendly features and functions that make it easy to manage parameters critical to disinfection, water balance, system maintenance and compliance.
The FCE function reports FAC quickly and accurately by measuring ORP, the chemical characteristic of chlorine that directly reflects its effectivity, cross referenced with pH. Both DPD kits and colorimeters may tell the user the FAC value of the sample in the test tube, but since the chemistry of that sample is quite different from the source water being analyzed, the results are imprecisely related to actual disinfection power. The FCE function measures the real, unaltered chemistry of source water, including moment-to-moment changes in that chemistry. FCE can be used for other types of oxidizing germicides and will track the effect of additives, such as cyanuric acid, that degrade chlorine effectivity without changing the actual concentration of free available chlorine present.
In-Cell Titration Functions
The PS9TKA adds the ability to perform in-cell conductometric titrations that provides a convenient way to determine alkalinity, hardness and LSI in the field. This eliminates the need to collect and transport samples to another location for analysis. User intuitive display prompts guide you through titration procedures from start to finish. All required reagents and equipment are included in the PS9 titration kit.
Water Balance Analysis
The PS9TKA features both an LSI Calculator and an LSI Titration measurement mode. The Calculator allows you to perform what-if scenarios to predict how changes in solution parameters would affect the water balance of a system. The titration measurement function allows you to accurately calculate a saturation index value of a specific solution to determine whether the solution is balanced, scaling or corrosive.
Hardness Unit Conversion
The Hardness and LSI Titrations and LSI Calculator functions allow you to set the hardness unit preference to either grains of hardness or ppm CaCO3 according to your needs.
System Validation & Calibration
Myron L’s PoolPro provides a fast, precise, easy-to-use method of obtaining Oxidation Reduction Potential (ORP or REDOX) mV readings to check the true level of effectiveness of ALL sanitizers in any pool or spa. ORP objectively and precisely measures sanitizer ability to burn up, or oxidize, organic matter in the water. ORP can only be determined by an electronic instrument. PoolPro ORP mV readings serve as a necessary check to ensure automatic ORP control systems are working properly. PoolPro also provides independent readings for recalibration and to detect system failure.
Saltwater Chlorine Generation
PoolPro provides a convenient one-touch test for Mineral/Salt concentration. This is ideal for saltwater systems where manual testing with separate instrumentation is necessary to ensure the proper amount of sodium chloride is present for chlorine generation in quantities specified for microbial disinfection. PoolPro can also be used to recalibrate equipment as part of regular maintenance.
The optional bluDock™ accessory package is an integrated data solution for your record keeping requirements, eliminating the need for additional hardware, wires and hassle. Because the user never touches the data, there is little opportunity for data tampering and human error. bluDock software has an easy to use interface with user intuitive functions for storing, sorting and exporting data.
PoolPro is lightweight, portable, buoyant, waterproof, easy-to-calibrate, and easy-to-use. Simply rinse and fill the cell cup by dipping the PoolPro in the water, then press the button of the parameter you wish to measure. You immediately get a standard, numerical digital readout — eliminating all subjectivity. And you can store up to 100 date-time-stamped readings in PoolPro’s non-volatile memory.
Myron L Meters
PoolMeter™ is a high quality analog instrument that measures TDS/NaCl/ Salt. Myron L meters are so reliable, some have been in continuous use for over 45 years.
Care and maintenance instructions for the Ultrapen PT4 Free Chlorine and Temperature pen.
I. Routine Maintenance
1. ALWAYS rinse the FCE sensor with clean water after each use.
2. ALWAYS replace the soaker cap half filled with Sensor Storage Solution to prevent the
sensor from drying out after each use.
3. Do not drop, throw, or otherwise strike the PT4. This voids the warranty.
4. Do not store the PT4 in a location where the ambient temperatures exceed its specified Operating/Storage Temperature limits.
II. Battery Replacement The PT4 display has a battery indicator that depicts the life
remaining in the battery. When the indicator icon is at 3 bars, the battery is full. When the indicator icon falls to 1 bar, replace the battery with an N type battery.
Align groove in battery housing with guide bump in pen case.
1. In a clean/dry environment,
unscrew the pen cap in a counter-clockwise motion.
2. Slide the cap and battery housing out of the PT4.
3. Remove the depleted battery out of its housing.
4. Insert a new battery into the battery housing oriented with the negative end touching the spring.
5. Align the groove along the battery housing with the guide bump inside the PT4
case and slide the battery housing back in.
6. Screw the PT4 cap back on in a clockwise direction. Do not over tighten.
III. Sensor Cleaning
Cleaning the sensor:
Clean your sensor every two weeks, however this depends on application and frequency of use. Indications of a dirty sensor are slower and/or erroneous readings.
There are three critical components in your PT4 sensor; a very sensitive glass pH sensor bulb, a platinum ORP electrode, and a temperature sensor encapsulated in a small glass noid. Use extreme caution when cleaning your PT4 sensor.
To clean your sensor, select one of the following methods:
• Basic Cleaning: Using a solution made of dish soap mixed with water and a cotton swab, gently clean the inside of the sensor body and platinum electrode, rinse thoroughly with clean water, then recondition the sensor.
• Cleaning the pH Sensor Bulb: If the sensor becomes dirty, clean the sensor surface with an isopropyl soaked cotton swab. Then rinse thoroughly with clean water.
• Deep cleaning the platinum ORP electrode: Using the ORP electrode cleaning paper and water, gently clean the platinum electrode, rinse thoroughly then recondition the sensor.
To recondition the sensor: Rinse the sensor thoroughly with clean water, then allow it to soak in Storage Solution for a minimum of 1 hour (for best results allow the sensor to soak in Storage Solution overnight).
A. Calibration preparation
For maximum accuracy, fill 2 clean containers with each pH Buffer and/or ORP Standard Solution. Arrange them in such a way that you can clearly remember which is the rinse solution and which is the calibration standard/buffer. If you don’t have enough standard/ buffer, you can use 1 container of each standard/buffer for calibration and 1 container of clean water for all rinsing. Always rinse the FCE sensor between standard/buffer solutions. Ensure the FCE sensor is clean and free of debris.
B. pH Calibration using pH 7, 4, and 10 Buffer Solutions.
NOTE: You should always calibrate with pH 7 first.
1. Thoroughly rinse the PT4 by submerging the sensor in pH 7 Buffer rinse solution and swirling it around.
2. Push and release the push button to turn the PT4 on.
3. Push and hold the push button. The display will alternate between “CAL”, “FAC CAL”, “ºCºF TEMP”, “ModE SEL”, “PAr SEL”, “SOL ck”, and “ESC”.
4. Release the button when “CAL” displays.
5. The display will alternate between “PUSHnHLD” and “CAL.
6. Push and hold the button, The display will alternate between “PH” and “ORP”.
7. Release the button when “PH” is displayed.
8. The display will indicate “CAL” and the LED will flash rapidly.
9. While the LED flashes rapidly, dip the PT4 in pH 7 Buffer Calibration Solution so that the sensor is completely submerged.
10. While the LED flashes slowly, the pH calibration point will display along with “CAL”.
Swirl the PT4 around to remove bubbles, keeping the sensor submerged.
11. If the pH 7 calibration is successful, the display will indicate “SAVEd”, then “PUSHCONT” will be displayed (“PUSHCONT” will NOT be displayed if only calibrated with pH 4 or 10).
12. Push and release to continue or let the unit time out to exit after a 1-point or 2-point calibration.
13. Repeat steps 9 through 12 with pH 4 and 10 Buffer Solutions. After the 3rd calibration point is successfully saved, the display will indicate “SAVEd” and power off.
14. Verify calibration by retesting the calibration solution in solution check mode “SOL ck”, see section V below.
C. ORP Calibration using 80mV Quinhydrone, 260mV Quinhydrone, or 470mV MLC Light’s ORp Standard Solution.
NOTE: The PT4 has automatic temperature compensation in ORP calibration mode (from 15ºC to 30ºC).
1. Follow pH calibration steps 1 through 6, using ORP Solutions.
2. Release the button when “ORP” is displayed.
3. The display will indicate “CAL” and the LED will flash rapidly.
4. While the LED flashes rapidly, dip the PT4 in ORP Standard Solution so that the
sensor is completelysubmerged.
5. While the LED flashes slowly, the ORP calibration point will display along with “CAL”.
Swirl the PT4 around to remove any air bubbles, keeping the sensor submerged.
6. If the ORP calibration is successful, the display will indicate “CAL SAVEd”, then time out.
7. Verify calibration by retesting the calibration solution in solution check mode.
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